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| 1 | Microscopic structures of ionic liquids 1-ethyl-3-methylimidazolium tetrafluoroborate in water probed by the relative chemical shift显示文摘The relative chemical shifts (△δ) △δwere put forward to investigate the microscopic structure of 1-ethyl-3-methyl-imidazolium tetrafluoroborate (EmimBF4) during the dilution process with water.The concentration-dependent △δ(C2)H-(C4)H,△δ(C2)H-(C5)H and △δ(C4)H-(C5)H were analyzed.The results reveal that the variations of the microscopic structures of three aromatic protons are inconsistent.The strength of the H-bond between water and three aromatic protons follows the order:(C2)H···O > (C4)H···O > (C5)H···O.The concentration-dependent △δ(C6)H-(C7)H and △δ(C6)H-(C8)H indicate the formation of the H-bonds of (Calkyl)H···O is impossible,and more water is located around (C6)H than around (C7)H or (C8)H.The concentration-dependent △δ(C2)H-(C4)H and △δ(C2)H-(C5)H both increase rapidly when xwater > 0.9 or so,suggesting the ionic pairs of EmimBF4 are dissociated rapidly.The turning points of concentration-dependent △δ(C2)H-(C4)H and △δ(C2)H-(C5)H indicate that some physical properties of the EmimBF4/water mixtures also change at the corresponding concentration point.The microscopic structures of EmimBF4 in water could be clearly detected by the relative chemical shifts. | XU YingJie GAO Yan ZHANG LiQun YAO Jia WANG CongMin LI HaoRan | 2010 | Science China Chemistry2010，53，7： | 8 |
| 2 | Overview of Biomass Conversion to Electricity and Hydrogen and Recent Developments in Low-Temperature Electrochemical Approaches显示文摘Biomass is plant or animal material that stores both chemical and solar energies,and that is widely used for heat production and various industrial processes.Biomass contains a large amount of the element hydrogen,so it is an excellent source for hydrogen production.Therefore,biomass is a sustainable source for electricity or hydrogen production.Although biomass power plants and reforming plants have been commercialized,it remains a difficult challenge to develop more effective and economic technologies to further improve the conversion efficiency and reduce the environmental impacts in the conversion process.The use of biomass-based flow fuel cell technology to directly convert biomass to electricity and the use of electrolysis technology to convert biomass into hydrogen at a low temperature are two new research areas that have recently attracted interest.This paper first briefly introduces traditional technologies related to the conversion of biomass to electricity and hydrogen,and then reviews the new developments in flow biomass fuel cells(FBFCs)and biomass electrolysis for hydrogen production(BEHP)in detail.Further challenges in these areas are discussed. | Wei Liu Congmin Liu Parikshit Gogoi Yulin Deng | 2020 | Engineering2020，6，12： | 7 |
| 3 | A Review of Technical Advances,Barriers,and Solutions in the Power to Hydrogen(P2H)Roadmap显示文摘Power to hydrogen(P2H)provides a promising solution to the geographic mismatch between sources of renewable energy and the market,due to its technological maturity,flexibility,and the availability of technical and economic data from a range of active demonstration projects.In this review,we aim to provide an overview of the status of P2H,analyze its technical barriers and solutions,and propose potential opportunities for future research and industrial demonstrations.We specifically focus on the transport of hydrogen via natural gas pipeline networks and end-user purification.Strong evidence shows that an addition of about 10%hydrogen into natural gas pipelines has negligible effects on the pipelines and utilization appliances,and may therefore extend the asset value of the pipelines after natural gas is depleted.To obtain pure hydrogen from hydrogen-enriched natural gas(HENG)mixtures,end-user separation is inevitable,and can be achieved through membranes,adsorption,and other promising separation technologies.However,novel materials with high selectivity and capacity will be the key to the development of industrial processes,and an integrated membrane-adsorption process may be considered in order to produce high-purity hydrogen from HENG.It is also worth investigating the feasibility of electrochemical separation(hydrogen pumping)at a large scale and its energy analysis.Cryogenics may only be feasible when liquefied natural gas(LNG)is one of the major products.A range of other technological and operational barriers and opportunities,such as water availability,byproduct(oxygen)utilization,and environmental impacts,are also discussed.This review will advance readers’understanding of P2H and foster the development of the hydrogen economy. | Guoping Hu Chao Chen Hiep Thuan Lu Yue Wu Congmin Liu Lefu Tao Yuhan Men Guangli He Kevin Gang Li | 2020 | Engineering2020，6，12： | 7 |
| 4 | Conversion of PtNi alloy from disordered to ordered for enhanced activity and durability in methanol-tolerant oxygen reduction reactions显示文摘划算的氧减小反应(ORR ) 的发展有高甲醇忍耐和提高的耐久性的催化剂为直接甲醇燃料房间是高度合乎需要的。这个工作从混乱稳固的溶液集中于 PtNi nanoparticles 的变换到订的金属间化合的混合物。这里,在 ORR 活动,耐久性,和甲醇忍耐的这变换的效果被描绘。X 光检查衍射和传播电子显微镜学结果与高分散和大约 7.6 nm 的一种吝啬的粒子尺寸证实订的 PtNi 金属间化合的 nanoparticles 的形成。展出的 PtNi 金属间化合的 nanoparticles 在纯、包含甲醇的电解质向甲醇容忍的 ORR 提高了集体、特定的活动。在 PtNi 金属间化合的 nanoparticles 上的 0.85 V 的 ORR 的特定的活动比在商业 Pt/C 和比在混乱 PtNi 合金上大的 3 次上大几乎 6 倍。在 5,000 潜力骑车以后,耐久性测试为 PtNi 金属间化合的 nanoparticles 显示了 ORR 活动的最小的损失,而 ORR 活动为混乱 PtNi 合金在 28% 减少了。提高的 methanoltolerant ORR 活动和耐久性可以被归因于相对混乱 PtNi 合金的稳定性比较的订的 PtNi 金属间化合的 nanoparticles 的结构、组合的稳定性,强烈建议 PtNi 金属间化合的 nanoparticles 可以为实际应用用作高度活跃、持久的甲醇容忍的 ORR electrocatalysts。 | Liangliang Zou Jing Fan Yi Zhou Congmin Wang Jun Li Zhiqing Zou Hui Yang | 2015 | Nano Research2015，8，8： | 6 |
| 5 | ZrOCl_2·8H_2O: An Efficient and Cheap Catalyst for Esterification of Free Fatty Acids to Methyl Esters显示文摘The esterification of lauric acid with methanol could be efficiently catalyzed by ZrOCl2·8H2O, and this reaction was studied to develop a green method for biodiesel production. The influencing factors, such as amount of catalyst, reaction time and molar ratio of acid to methanol, were investigated. The results indicated that the ZrOCl2·8H2O catalyst showed high catalytic activity, and gave a 97.0% methyl laurate conversion rate under the following optimized conditions, viz.: a lauric acid/methanol molar ratio of 1:10, a catalyst dosage of 4%, and a reaction duration of 2 h at methanol refluxing temperature. The catalyst could be easily recovered while its activity could be well retained after three cycles. The ZrOCl2·8H2O catalyst also exhibited excellent catalytic activity for the esterification of different free long-chain fatty acids(including nonedible oils with high acid value) with different short carbon chain alcohols. Therefore, the ZrOCl2·8H2O catalyst has good potential for the synthesis of biodiesel from low-cost feedstocks such as waste vegetable oils and non-edible oils. | Cai Jie Zhang Qiuyun Huang Congmin Zhou Kaizhi Ma Peihua | 2014 | China Petroleum Processing & Petrochemical Technology2014，16，1： | 4 |
| 6 | A multicenter retrospective cohort study of ketogenic diet therapy in 481 children with infantile spasms显示文摘Background:Ketogenic diet(KD)therapy is one of the main treatments for drug-resistant epilepsy.However,the KD therapy has been applied in only a small number of infantile spasm cases.In this large multicenter study,we investigated the efficacy of KD therapy in the treatment of infantile spasms.Methods:In this retrospective,multicenter cohort study,clinical data from main epilepsy centers were analyzed.Patients were classified into different groups according to age,type of drug and whether glucocorticoid was used before initiation of KD.Results:From October 2014 to March 2020,481 patients(308 males and 173 females)with infantile spasms were treated with the KD therapy.The age of the patients ranged from 2 months to 20 years,with a mean age of 1 year and 10 months.The number of anti-seizure medications(ASMs)used before KD initiation ranged 0-6,with a median of 3.In different time from initiation(1,3,6,and 12 months),the rates of seizure freedom after KD were 6.9,11.6;16.0 and 16.8%,respectively(x^(2)=27.1772,P<0.0001).There was a significant difference in the rate of seizure freedom between 3 months and 1 month(x^(2)=6.5498,P=0.0105)groups,and 6 months and 3 months(x^(2)=3.8478,P=0.0498)groups,but not between 12 months and 6 months(x^(2)=0.1212,P=0.7278)groups.The rates of effectiveness were 44.7;62.8,49.1 and 32.0%(x^(2)=93.2674,P<0.0001),respectively.The retention rates were 94.0,82.5,55.7 and 33.1%(x^(2)=483.7551,P<0.0001),correspondingly.The rate of effectiveness and the retention rate of KD were significantly different among the 1,3,6 and 12 months.KD treatment was the first choice in 25 patients(5.2%),55 patients(11.4%)started KD after the failure of the first ASM,158 patients(32.8%)started KD after the failure of the second ASM,157 patients(32.6%)started KD after the failure of the third drug,and 86 patients(17.9%)started KD after the failure of the fourth and more.The KD effect was not related to the number of ASMs used before KD startup(P>0.05).Two hundred and eighteen patients(45.3%)failed to respond to corticotropin or glucocorticoid before initiation.There was no significant difference in the effectiveness rate at different time points between the group of KD therapy after glucocorticoid failure and the group after non-hormone failure (x^(2)=0.8613,P=0.8348).The rate of adverse events of KD in 1,3,6,and 12 months after KD initiation were 22.3,21.7,16.8 and 6.9%,respectively.The adverse events mainly occurred during the first 3 months of KD,and the main adverse events were gastrointestinal disturbance and constipation.Conclusions:The efficacy of the KD treatment for infantile spasms was not affected by age,medication,and glucocorticoid use before initiation.KD is one of the effective treatments for infantile spasms. | Yuanzhen Ye Dan Sun Hua Li Jianmin Zhong Rong Luo Baomin Li Dengna Zhu Dan Li Shaoping Huang Yuwu Jiang Nong Xiao Yucai Chen Yuqin Zhang Mei Yu Xiaoyun Shen Li Gao Guo Zheng Congmin Zhao Baoqiang Yuan Jianxiang Liao Jiong Qin CAAE KD group | 2022 | Acta Epileptologica2022，5，1： | 2 |
| 7 | Synthesis of Biphasic Defective TiO2-x/Reduced Graphene Oxide Nanocomposites with Highly Enhanced Photocatalytic Activity显示文摘 | GAO Guiqi ZHU Qing CHONG Hanbao ZHENG Jun FAN Congmin LI Guang | 2018 | Chemical Research in Chinese Universities2018，34，2： | 2 |
| 8 | 硫酸钙晶须改性PA66研究显示文摘以硫酸钙晶须(CSW)改性PA66材料,并测试CSW改性PA66复合材料的摩擦系数、拉伸强度和冲击强度.结果表明:随着CSW用量的增加,PA66复合材料的摩擦系数先减小后增大;拉伸强度和冲击强度都呈现出先增大后减小的趋势.改性PA66复合材料性能得到了提高. | 郑志武 卢建飞 刘任晖 魏佳平 ZHENG Congmin | 2017 | 绵阳师范学院学报2017，36，5： | 2 |
| 9 | Pitting corrosion behavior of 316L stainless steel in the media of sulphate reducing and iron-oxidizing bacteria显示文摘 | Xu Congmin Zhang Yaoheng Cheng Guangxu | 2008 | Materials Characterization2008，59，3： | 1 |
| 10 | Survivin-an attractive target for RNAi in non-Hodgkin' s lymphoma Daudi cell line as a model 显示文摘 | Congmin G Mu Z Yihui M | 2006 | Leuk Lymphoma2006，47，9： | 1 |
| 11 | Novel quaternary ammonium ionic liquids and their use as dual solvent-catalysts in the hydrolytic reaction 显示文摘 | Weng Jianyang Wang Congmin Li Haoran | 2006 | Green Chem2006，8，1： | 1 |
| 12 | Ionic liquids as catalytic green solvents for cracking reaction显示文摘 | Wang yong Li haoran Wang congmin | 2004 | Journal of royal society of chemistry2004，4，1： | 1 |
| 13 | Ionic liquids as catalytic green solvents for cracking reaction显示文摘 | Wang yong Li haoran Wang congmin | 2004 | Journal of royal society of chemistry2004，4，1： | 1 |
| 14 | Carbon dioxide capture by superbase derived protic ionic liquids显示文摘 | Wang Congmin Luo Huimin Jiang De-en | 2010 | General & Introductory Chemistry:Angewandte Chemic International Edition2010，122，34： | 1 |
| 15 | Survivin-an attractive target for RNAi in non Hodgkin's lymphoma, Daudi cell line as a model显示文摘 | Congmin G Mu Z Yihui M | 2006 | Leuk Lymphoma2006，47，9： | 1 |
| 16 | Tuning the basicity of ionic liquids for equimolar CO2 capture显示文摘 | Wang Congmin Luo Xiaoyan Luo Huimin | 2011 | General & Introductory Chemistry:Angewandte Chemie International Edition2011，50，21： | 1 |
| 17 | Principles of methane adsorption and natural gas storage显示文摘 | Yan Sun Congmin Liu Wei Su Yaping Zhou Li Zhou | 2009 | Adsorption2009，，2： | 1 |
| 18 | Novel CeO2 yolk-shell structures loaded with tiny Au nanoparti- cles for superior catalytic reduction of p-nitrophenol 显示文摘 | Fan Congmin Zhang Linfei Wang Shasha | 2012 | Nanoscale2012，4，21： | 1 |
| 19 | AN ANALYSIS OF CHARACTERISTICS OF VARIATION OF THE TAIWAN WARM CURRENT DEEP WATER显示文摘 | Weng Xuechuan and Wang Congmin (Institute of Oceanology Academia Sinica Qingdao) | 1985 | Chinese Journal of Oceanology and Limnology1985，，01： | 1 |
| 20 | On the Taiwan Warm Current Water显示文摘 | Weng Xuechuan Wang Congmin | 1988 | Chinese Journal of Oceanology and Limnology1988，，4： | 1 |
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