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| 1 | Systematic study of H2 production from catalytic photoreforming of cellulose over Pt catalysts supported on TiO2显示文摘Hydrogen(H2)production from photocatalytic reforming of cellulose is a promising way for sustainable H2 to be generated.Herein,we report a systematic study of the photocatalytic reforming of cellulose over Pt/m-TiO2(i.e.mixed TiO2,80%of anatase and 20%of rutile)catalysts in water.The optimum operation condition was established by studying the effect of Pt loading,catalyst concentration,cellulose concentration and reaction temperature on the gas production rate of H2(r(H2))and CO2(r(CO2)),suggesting an optimum operation condition at 40°C with 1.0 g·L^-1of cellulose and 0.75 g·L^-1of 0.16-Pt/m-TiO2 catalyst(with 0.16 wt%Pt loadting)to achieve a relatively sound photocatalytic performance with rH2=9.95μmol·h^-1.It is also shown that although the photoreforming of cellulose was operated at a relatively mild condition(i.e.with an UV-A lamp irradiation at40°C in the aqueous system),a low loading of Pt at^0.16 wt%on m-TiO2 could promote the H2 production effectively.Additionally,by comparing the reaction order expressed from both r(H2)(a1)and r(CO2)(a2)with respect to cellulose and water,the possible mechanism of H2 production was proposed. | Lan Lan Yan Shao Yilai Jiao Rongxin Zhang Christopher Hardacre Xiaolei Fan | 2020 | Chinese Journal of Chemical Engineering2020，28，8： | 3 |
| 2 | Recent advances in non-thermal plasma(NTP)catalysis towards C1 chemistry显示文摘C1 chemistrymainly involves the catalytic transformation of C1molecules(i.e.,CO,CO2,CH4 and CH3OH),which usually encounters thermodynamic and/or kinetic limitations.To address these limitations,non-thermal plasma(NTP)activated heterogeneous catalysis offers a number of advantages,such as relatively mild reaction conditions and energy efficiency,in comparison to the conventional thermal catalysis.This review presents the state-of-the-art for the application of NTP-catalysis towards C1 chemistry,including the CO2 hydrogenation,reforming of CH4 and CH3OH,and water-gas shift(WGS)reaction.In the hybrid NTP-catalyst system,the plasma-catalyst interactions aremultifaceted.Accordingly,this reviewalso includes a brief discussion on the fundamental research into themechanisms of NTP activated catalytic C1 chemistry,such as the advanced characterisation methods(e.g.,in situ diffuse reflectance infrared Fourier transform spectroscopy,DRIFTS),temperatureprogrammed plasma surface reaction(TPPSR),kinetic studies.Finally,prospects for the future research on the development of tailor-made catalysts for NTP-catalysis systems(which will enable the further understanding of its mechanism)and the translation of the hybrid technique to practical applications of catalytic C1 chemistry are discussed. | Huanhao Chen Yibing Mu Shanshan Xu Shaojun Xu Christopher Hardacre Xiaolei Fan | 2020 | Chinese Journal of Chemical Engineering2020，28，8： | 2 |
| 3 | 显示文摘 | Russell G Evans Oleksiy V Klymenko Christopher Hardacre | 2003 | Journal of Electroanalytical Chemistry2003，556，： | 1 |
| 4 | Determination of ammonia based on the electro-oxidation of hydroquinone in dimethylformamide or in the room temperature ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide显示文摘 | Debora Giovanelli Marisa C Buzzeo Nathan S Lawrence Christopher Hardacre Kenneth R Seddon Richard G Compton | 2003 | Talanta2003，，： | 1 |
| 5 | Influence of surface structures,subsurface carbon and hydrogen,and surface alloying on the activity and selectivity of acetylene hydrogenation on Pd surface:a density functional theory study显示文摘 | Bo Yang Robbie Burch Christopher Hardacre | 2013 | Journal of Catalysis2013，305，： | 1 |
| 6 | Catalysis in ionic liquids显示文摘 | P^rvulescu Vasile I Hardacre Christopher | 2007 | Chemical Reviews2007，107，： | 1 |
| 7 | Microwave-assisted catalyst-free hydrolysis of fibrous cellulose for deriving sugars and biochemicals显示文摘Microwave(MW)assisted catalyst-free hydrolysis of fibrous cellulose(FC,cellulolysis)at 200℃promoted a cellulose conversion o f ca.37.2%and quantitative production o f valuable C5/C6 sugars(e.g.,glucose)and the according platform biochemicals(e.g.,5-hydroxymethylfurfliral),corresponding to an overall selectivity o f 96.5%.Conversely,conventional hydrothermal cellulolysis under similar conditions was not effective,even after 24 h,carbonising the FC.Based on the systematic study of MW-assisted cellulolysis,the specific interaction between water molecules and macroscopic FC under the MW irradiation was proposed,accounting for the interpretation o f the experimental observation.The kinetic energy o f water molecules under the MW irradiation facilitated the C-C(in the non-hindered surface-CH2OH groups)and C-O-C bond breaking(inside the cellulose cavities)in FC,producing primary cellulolysis products of xylose,glucose and cellobiose. | Songshan Jiang Helen Daly Huan Xiang Ying Yan Huiping Zhang Christopher Hardacre Xiaolei Fan | 2019 | Frontiers of Chemical Science and Engineering2019，13，4： | 1 |
| 8 | Kinetics of the oxidation of methyl tertbutyl ether (MTBE)by potassium permanganate显示文摘 | Jochen H Damm Christopher Hardacre Robert MKalin | 2002 | Water Research2002，36，： | 1 |
| 9 | Alternating copolymerisation of styrene and carbon monoxide in ionic liquids 显示文摘 | Christopher Hardacre John D Holbrey Suhas P Katdarea | 2002 | Green Chemistry2002，4，： | 1 |
| 10 | Regeneration mechanism of a Lean NO x Trap (LNT) catalyst in the presence of NO investigated using isotope labelling techniques显示文摘 | Be?at Pereda-Ayo Juan R. González-Velasco Robbie Burch Christopher Hardacre Sarayute Chansai | 2011 | Journal of Catalysis2011，，1： | 1 |
| 11 | Use of room temperature ionic liquids in gas sensor design 显示文摘 | Buzzeo Marisa C Hardacre Christopher Compton Richard G | 2004 | Analytical Chemietry2004，76，15： | 1 |
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