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| 1 | High power and stable P-doped yolk-shell structured Si@C anode simultaneously enhancing conductivity and Li^(+)diffusion kinetics显示文摘Silicon is a low price and high capacity ancxje material for lithium-ion batteries.The yolk-shell structure can effectively accommodate Si expansion to improve stability.However,the limited rate performance of Si anodes can't meet people's growing demand for high power density.Herein,the phosphorus-doped yolk-shell Si@C materials(P-doped Si@C)were prepared through carbon coating on P-doped Si/SiO_(x)matrix to obtain high power and stable devices.Therefore,the as-prepared P-doped Si@C electrodes delivered a rapid increase in Coulombic efficiency from 74.4%to 99.6%after only 6 cycles,high capacity retention of-95%over 800 cycles at 4 A·g^(-1),and great rate capability(510 mAh·g^(-1)at 35 A·g^(-1)).As a result,P-doped Si@C anodes paired with commercial activated carbon and LiFePO_(4)cathode to assemble lithium-ion capacitor(high power density of〜61,080 W·kg^(-1)at 20 A·g^(-1))and lithium-ion full cell(good rate performance with 68.3 mAh·g^(-1)at 5 C),respectively.This work can provide an effective way tofurther improve power density and stability for energy storage devices. | Ming Chen Qinnan Zhou Jiantao Zai Asma Iqbal TsegayeTadesse Tsega Boxu Dong Xuejiao Liu Yuchi Zhang Changyu Yan Liang Zhao Ali Nazakat SharelPeisan E CheeTongJohn Low Xuefeng Qian | 2021 | Nano Research2021，14，4： | 5 |
| 2 | Effects of calcination temperature and Li^+ ions doping on structure and upconversion luminescence properties of TiO_2:Ho^(3+)-Yb^(3+) nanocrystals显示文摘Ho^(3+)-Yb^(3+) co-doped and Ho^(3+)-Yb^(3+)-Li^+ tri-doped TiO_2 nanocrystals were prepared using the sol-gel method. Effects of the calcination temperature and Li^+ ions doping on the structure and upconversion luminescence properties of Ho^(3+)-Yb^(3+) co-doped TiO_2 nanocrystals were investigated. The upconversion luminescence of nanocrystals was enhanced with the reduction of the crystal lattice symmetry and the crystallinity improvement of the matrix, which were facilitated by the calcination temperature change and Li^+ ions doping. The lowest lattice symmetry and the best crystallinity of the matrix resulted in the maximum luminescence intensity. | Kaishun Zou Guangzong Dong Juncheng Liu Boxu Xu Danping Wang | 2019 | Journal of Materials Science & Technology2019，35，4： | 1 |
| 3 | Electric field control by permittivity functionally graded and superficially non-linear conductivity materials for DC-GIS spacer显示文摘This paper offers a simulation study on the application of a novel approach to control the electric field around a basin-type spacer by combining permittivity functionally graded materials(ε-FGM)and superficially non-linear conductivity materials(SNCM),namely multi-dimensional functional materials(MDFM).The permittivity distribution of theε-FGM spacer is designed by the iteration optimization algorithm,and the epoxy/SiC composites with 30 and 60 phr doping contents are assigned as the coating materials of two SNCM spacers,namely SNCM30 and SNCM60.The MDFM spacer combinesε-FGM in its bulk and SNCM60 on its surface.The electric field regulation effect of each functional spacer is investigated under variable conditions,that is,DC steady state(DC-steady),DC turn-on state(DC-on),DC polarity reversal(DC-PR),and DC superimposed with switching impulse voltage(DC-SI).Results show that the applicability ofε-FGM and SNCM is limited to transient and stationary conditions,respectively.The MDFM spacer combines the advantages ofε-FGM and SNCM for adaptively relaxing the electric field under all the above conditions.It is hoped that this research will be beneficial to the development and application of spacers for the direct current gas-insulated switchgear(DC-GIS). | Boxue Du Jianan Dong Hucheng Liang | 2022 | High Voltage2022，7，5： | 1 |
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