| 1 | Understanding the improved performance of sulfur-doped interconnected carbon microspheres for Na-ion storage显示文摘As one of the low-cost energy storage systems,Na-ion batteries(NIBs)have received tremendous attention.However,the performance of current anode materials still cannot meet the requirements of NIBs.In our work,we obtain sulfur-doped interconnected carbon microspheres(S-CSs)via a simple hydrothermal method and subsequent sulfurizing treatment.Our S-CSs exhibit an ultrahigh reversible capacity of 520 mAh g^(-1) at 100 mA g^(-1) after 50 cycles and an excellent rate capability of 257 mAh g^(-1),even at a high current density of 2 A g^(-1).The density functional theory calculations demonstrate that sulfur doping in carbon favors the adsorption of Na atom during the sodiation process,which is accountable for the performance enhancement.Furthermore,we also utilize operando Raman spectroscopy to analyze the electrochemical reaction of our S-CSs,which further highlights the sulfur doping in improving Na-ion storage performance. | Xinran Yuan Siming Chen Jinliang Li Junpeng Xie Genghua Yan Botian Liu Xibo Li Rui Li Likun Pan Wenjie Mai | 2021 | Carbon Energy2021，3，4： | 3 |
| 4 | A multistimuli-responsive fluorescent hydrogel based on a fluorescence response to macromolecular segmental motion显示文摘Fluorescent hydrogels with fast and reversible responses have attracted extensive attention, and it remains a challenge to designmultistimuli-responsive fluorescent hydrogel through a facile and versatile method. Meanwhile, the segmental motion inhydrogels is of significance for the various functions of hydrogels such as chemical reactivity, self-healing, and mechanicalstrength, etc., however, it is difficult and complicated to in situ investigate the segmental motion under different conditions. In thiswork, a multistimuli-responsive fluorescent hydrogel was designed and fabricated by introducing a tetraphenylethylene (TPE)derivative as a nonaggregated crosslinker in the gel network. Since the intermolecular rotation of TPE at the crosslinking pointwas directly integrated with the dynamic conformational transition of the macromolecular network, the mobility of macromolecularsegments can be monitored by the fluorescence intensity of the hydrogel. The prepared hydrogel has promising fluorescenceresponses to temperature, pH, metal ions, and hydrogen bonding agents, and characterization of the fluorescence and the chainsegmental motion showed that the weaker the mobility of the network macromolecular chain is, the stronger the fluorescenceintensity is. Furthermore, due to the multistimuli-responsive fluorescence of the hydrogel, such fluorescent hydrogels can bedesigned as reversible patterning displays and biomimetic color/shape adjustable actuators, with various potential applications. | Botian Li Bo Yan Jian Wang Yichi Zhang Ziyan Qiu Jundang Liang Qiong Zhou | 2023 | Nano Research2023，16，10： | 0 |
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