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1篇 您的检索式:作者名="Alex Abelson"
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1In situ TEM observation of neck formation during oriented attachment of PbSe nanocrystals显示文摘Oriented attachment of nanocrystals is an important route to constructing epitaxially-connected nanocrystal superlattices for various applications.During oriented attach me nt of semic on ductor nano crystals,neck can be formed betwee n nan ocrystals and it strongly influe nces the properties of the resulting superlattice.However,the neck formation mechanism is poorly understood.Here,we use in situ liquid cell transmission electro n microscopy(TEM)to directly observe the initiatio n and growth of homoepitaxial n ecks betwee n PbSe nano crystals with atomic details.We find that neck initiatio n occurs slowly(~10 s)whe n two nano crystals approach to each other within an edge-to-edge dista nee of 0.6 nm.During neck initiation,Pb and Se atoms defuse from other facets into the gap,forming'dynamic reversible'filaments.Once the filament(n eck)width is larger than a critical size of 0.9 nm,it gradually(15 s)widens into a 3-nm-wide n eck.The atomic structure of the neck is further obtained using ex situ aberration-corrected seanning TEM imaging.Neck initiation and growth mechanisms are elucidated with density functional theory calculati ons.Our direct unveiling of the atomic pathways of neck formatio n duri ng oriented attach me nt shed light into the fabrication of nanocrystal superlattices with improved structural order and electronic properties.Yu Wang Xinxing Peng Alex Abelson Bing-Kai Zhang Caroline Qian Peter Ercius Lin-Wang Wang Matt Law Haimei Zheng 2019Nano Research2019,12,10:1
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