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| 1 | Supporting IrO2 and IrRuOx nanoparticles on TiO2 and Nb-doped TiO2 nanotubes as electrocatalysts for the oxygen evolution reaction显示文摘IrO2 and IrRuOx(Ir:Ru 60:40 at%),supported by 50 wt%onto titania nanotubes(TNTs)and(3 at%Nb)Nb-doped titania nanotubes(Nb-TNTs),as electrocatalysts for the oxygen evolution reaction(OER),were synthesized and characterized by means of structural,surface analytical and electrochemical techniques.Nb doping of titania significantly increased the surface area of the support from 145(TNTs)to 260 m2g-1(Nb-TNTs),which was significantly higher than those of the Nb-doped titania supports previously reported in the literature.The surface analytical techniques showed good dispersion of the catalysts onto the supports.The X-ray photoelectron spectroscopy analyses showed that Nb was mainly in the form of Nb(IV)species,the suitable form to behave as a donor introducing free electrons to the conduction band of titania.The redox transitions of the cyclic voltammograms,in agreement with the XPS results,were found to be reversible.Despite the supported materials presented bigger crystallite sizes than the unsupported ones,the total number of active sites of the former was also higher due to their better catalyst dispersion.Considering the outer and the total charges of the cyclic voltammograms in the range 0.1–1.4 V,stability and electrode potentials at given current densities,the preferred catalyst was Ir O2 supported on the Nb-TNTs.The electrode potentials corresponding to given current densities were between the smallest ones given in the literature despite the small oxide loading used in this work and its Nb doping,thus making the Nb-TNTs-supported IrO2 catalyst a promising candidate for the OER.The good dispersion of IrO2,high specific surface area of the Nb-doped supports,accessibility of the electroactive centers,increased stability due to Nb doping and electron donor properties of the Nb(IV)oxide species were considered the main reasons for its good performance. | Radostina V.Genova-Koleva Francisco Alcaide Garbine Alvarez Pere L.Cabot Hans-Jürgen Grande María V.Martínez-Huerta Oscar Miguel | 2019 | Journal of Energy Chemistry2019，28，7： | 2 |
| 2 | Cigarette smoking as a risk factor for tuberculosis in young adults: a ease-control stud- y显示文摘 | Alcaide J Altet MN Plans P Parron I Foguera L Salto E Dominguez A Pardell H Salleras L | 1996 | Tuber LungDis1996，77，2： | 1 |
| 3 | Aplidin induces the mitochondrial apoptotic pathway via oxidative stress-mediated JNK and p38 activation and protein kinase C delta 显示文摘 | Garcia-Fernández LF Losada A Alcaide V | 2002 | Oncogene2002，21，： | 1 |
| 4 | The mycobacterium xenopi GyrA protein splicing element: characterization of a minimal intein 显示文摘 | Telenti A Southworth M Alcaide F | 1997 | J Bacteriol1997，179，20： | 1 |
| 5 | An Approach to Solve the Minimum Expected Makespan Flow Shop Problem Subject to Breakdowns 显示文摘 | Alcaide D Rodriguez G A Sicilia A | 2002 | European Journal of Operation Research (S0377-221)2002，140，2： | 1 |
| 6 | A network flow-based method to solve performance cost and makespan open-shop scheduling problems with time-windows显示文摘 | Sede(n)o-Noda A Alcaide López de Pablo D González-Martín C | | 0，，01： | 1 |
| 7 | Comparative study of the clinical efficacy of two coumarin dosages in the management of arm lymphedema after treatment for breast cancer显示文摘 | Burgos A Alcaide A Alcoba C | 1999 | Lymphology1999，32，1： | 1 |
| 8 | Abrogation of func- tional seletin-ligand expression reduces migration of pathogenic CD8+ T cell into heart显示文摘 | Cai Y H Alvarez A Alcaide P | 2006 | J Immunol2006，176，11： | 1 |
| 9 | Bayesian rational exchange 显示文摘 | Estevez-Tapiador M J Alcaide A | 2008 | International Journal of Information Security2008，7，1： | 1 |
| 10 | An approachto solve the minimum expected makespan flow-shopproblem subject to breakdowns 显示文摘 | Alcaide D Rodriguez-Gonzalez A Sicilia J | 2002 | European J ofOperational Research2002，140，2： | 1 |
| 11 | Flexible uretemrenoscopy(URS) : technique and results显示文摘 | Cansino Alcaide JR Reinoso Elbers J Lopez Sanchez D Perez Gonzalez S Rodriguez Aguilera Bazan A Rando Tous A Hidalgo Togores L De La Pena Barthel J | 2010 | Arch Esp Urol2010，63，10： | 1 |
| 12 | An approach to solve the minimum expected makespan flowshop problem subject to breakdowns显示文摘 | ALCAIDE D RODRIGUEZ-GONZALEZ A SICILIA A | 2002 | European Journal of Operation Research2002，140，2： | 1 |
| 13 | The use of a geographical information system to assess the effect of traffic pollution显示文摘 | Moragues A Alcaide T 1996 | 1996 | Sci Total Environ1996，190，： | 1 |
| 14 | Apolipoprotein C m induces expression of vascular cell adhesion molecule-1 in vascular endothelial cells and increases ad- hesion of monocytic ceils 显示文摘 | Kawakami A Aikawa M Alcaide P | 2006 | Circulation2006，114，： | 1 |
| 15 | Apolipoprotein C Ⅲ induces expres- sion of vascular cell adhesion molecule-1 in vascular endothelial cells and in- creases adhesion of monocytic cells显示文摘 | Kawakami A Aikawa M Alcaide P | 2006 | Circulation2006，114，7： | 1 |
| 16 | Simultaneous a nalysis of multiple PCR amplicons enhances capillary SS CP discrimination of M HC alleles显示文摘 | Alcaide M Lbpez L Tanferna A | 2010 | Eleetrophoresis2010，31，8： | 1 |
| 17 | Comparativestudy of the clinical efficacy of two different coumarin dosa-ges in the management of arm lymphedema after treatmentfor breast cancer显示文摘 | BURGOS A ALCAIDE A ALCOBA C | 1999 | Lymphology1999，32，1： | 1 |
| 18 | Role of embB in natural and ac- quired resistance to ethambutol in Mycobacteria显示文摘 | Alcaide F Pfyffer G E Telenti A | 1997 | Antimicrob A- gents Chemother1997，41，10： | 1 |
| 19 | Recycling of olive oil by-products:possibilities of utilization in animal nutri- tion显示文摘 | Molina Alcaide E Nefzaoui A | 1996 | International Biodeterioration & Biodegrada- tion1996，38，3： | 1 |
| 20 | Interaction of an ordered mesoporous bioactive glass with osteoblasts,fibroblasts and lymphocytes,demonstrating its biocompatibility as a potential bone graft material显示文摘 | Alcaide M Portolés P López-Noriega A | 2010 | Acta Biomaterialia2010，6，3： | 1 |
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