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One-dimensional ZnSe@N-doped carbon nanofibers with simple electrospinning route for superior Na/K-ion storage

查看全文 作  者:Di [1]Huang;Daxiong [2]Wu;Jixing [1]Zhu;Jinyu [1]Xie;Jipeng [1,2]Wu;Jiaojiao [1]Liang 高影响力作者 机构地区:[1]Hunan University of Technology,Zhuzhou 412008,China;[2]School of Physics and Electronics,Hunan University,Changsha 410082,China高影响力机构 出  处:《Chinese Chemical Letters》索引2023年第34卷第2期,共4页高影响力期刊 基  金:supported by the Natural Science Foundation of Hunan Province (Nos. 2020JJ5135 and 2021JJ40168);the Education Department of Hunan Province (Nos. 21B0534 and 20C0602)。 摘  要:One-dimensional carbon nanofibers are widely applied as anode material in the energy storage field due to its unique structure and high conductivity. In this work, one-dimensional ZnSe@N-doped carbon nanofibers(ZnSe@NC NFs) are successfully synthesized by electrospinning and annealed without extra troublesome conditions. ZnSe nanocrystals are enfolded in the N-doped carbon nanofibers, which can act as a protective layer to avoid the volume expansion of active material and promote ion transport during the cycling process. More importantly, the as-synthesized ZnSe@NC NFs are served as the anode material and display the admirable storage properties for Na/K-ion batteries. The one-dimensional Zn Se@NC NFs material shows the high capacity of 237 mAh/g for Na-ion batteries at a current density of 1 A/g for 2000cycles. Meanwhile, it also delivers a high discharge capacity of 337 mAh/g for K-ion batteries at 0.2 A/g for 300 cycles. Additionally, it is confirmed that the pseudocapacitive contribution of the nano-structure material is up to 54.5% at a scan rate of 0.6 m V/s through the cyclic voltammetry(CV) measurement in K-ion batteries. 关 键 词:ZNSE NANOFIBERS ELECTROSPINNING Na-ion batteries K-ion batteries PSEUDOCAPACITIVE
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