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| 1 | Status of study on biological and toxicological effects of nanoscale materials显示文摘Because the physical and chemical properties of nanosized materials mostly differ from the existing microsized materials, their potential impacts on human health and the envi-ronment will be topics under the serious discussions in press and in a number of international scientific journals. We analyze and summarize the existing data of the experimental study on the biological activities and adverse effects of nanoscale materials/particles including single wall carbon nanotubes, multi wall carbon nanotubes, titanium oxide and iron powders. Though some biological behaviors of nanoscale materials observed cannot be understood on the basis of the current knowledge, as the existing data are mostly preliminary, it is too early to make some ex-clusive conclusions on biological activities (or the toxicity) of any of nanoscale materials. The experimental techniques, the current topics, and the future research directions for this new re-search field are also discussed. | WANG Bing1, FENG Weiyue1, ZHAO Yuliang1, XING Gengmei1, CHAI Zhifang1, WANG Haifang2 & JIA Guang3 1. Laboratory for Bio-Environmental Health Sciences of Nanoscale Materials (Nanosafety Lab), Institute of High Energy Physics, Chi-nese Academy of Sciences, Beijing 100049, China 2. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China 3. Department of Occupational and Environmental Health Sciences, School of Public Health, Peking University, Beijing 100083, China | 2005 | Science China Chemistry2005，48，5： | 9 |
| 2 | Study on Thermal Simulation of Solidification in Heavy Section Ductile Iron显示文摘Using an artificial intelligent instrument and a computer feedback control method, a new thermal simulation systemis studied. Based on numerical simulation of casting solidification, a sample in the new system successfully simulatedthe solidification of heavy section ductile iron. The results show that the new thermal simulation system is accurateand reliable. Not only cooling curve but also graphite in the center of the thermal sample and the heavy sectionductile iron is identical. Realization of accurate thermal simulation of solidification in heavy section ductile iron willbe helpful for studying formation mechanism and controlling graphite degeneration in heavy section ductile iron. | Zhenhua LI Yanxiang LI Huiyuan GENG Jianjun CHEN Chunyan ZHOU Junfa CHEN | 2003 | Journal of Materials Science & Technology2003，19，z1： | 5 |
| 3 | Transition metal coordination polymers with polycarboxylic acid as bridging ligands:Synthesis and structure characterization of[Fe(μ_(4)-bta)_(0.5)(phen)(OH)]_(n)显示文摘A new 2D (two-dimensional) coordination polymer, [Fe(μ4-bta)0.5(phen)(OH)]n (1), has been hydrothermally synthesized with FeCl3·6H2O, Na4bta (H4bta = 1,2,4,5-benzentetra- carboxylic acid), 1,10-phen (1,10-phenanthroline) and H2O as raw materials. The crystals of the compound belong to monoclinic P21/n space group, a = 1.0129(2) nm, b = 0.9265(2) nm, c = 1.5696(3) nm,β = 91.37(3) o, V = 1.4721(5) nm3, Z = 3, final R1 = 0.0292, Wr2 = 0.0798 for 2572 [I > 2σ (I )] observed reflections. The result of structure determination shows that in the compound each bta ligand is connected with four FeIII, forming a new μ4-coordination mode. Four deprotonated carboxylic groups of bta link to FeIII ions alternatively through monodentate and bidentate coordination fashion, constructing 2D layer network. The measurement of variable temperature magnetic susceptibility indicates that there exist antiferromagnetic interactions between FeIII ions in the compound. The TGA spectrum displays relatively fine thermal stability of the compound. In addition, IR and UV-Vis spectra of compound 1 have also been measured. | XU Jiqing, CHU Deqing, YU Jiehui, WANG Tiegang & TANG AoqingCollege of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China Institute of Theoretical Chemistry, Jilin University, Changchun 130023, China | 2004 | Science China Chemistry2004，47，1： | 2 |
| 4 | QUANTUM-CHEMICAL MODIFICATIONS OF SURFACE:NEW METHODS FOR PROTECTING MATERIALS FROM CORROSION显示文摘A new method of corrosion-resistant coating of technical iron is presented. Processing by vibrationally excited hydrogen molecules of the iron surface covered with oxide film of α-Fe2 03 results in modification of surface by creating a film of amorphous iron on it. The presence of iron films with crystalline and amorphous phases, having the different Fermi levels, leads to formation of potential differences between them. This potential difference is opposite to the external electric field, resulting in decrease of anode current and increase of corrosion resistance. | R. T. Malkhasyan (Scientific Production Enterprise 'Atom' , Ministry of Industry and Trade, 3/1 Tevosyan, Yerevan, 375076, Armenia) | 2001 | Acta Metallurgica Sinica(English Letters)2001，14，6： | 1 |
| 5 | Electrolytic surface hardening of steel, cast iron and aluminium-bronze显示文摘Electrolytic hardening process was developed in USSR in the 1950s. The process was developed but was not commercially exploited. There is no evidence of work done on this process in India. The author has done this original work applied to different materials like steel, cast iron and aluminum-bronze. This paper gives details of microstructural transformations along with hardness value achieved. There is vital scope for this process to become viable for surface hardening and selective hardening of small components. | Suhas Keshav Paknikar | 2006 | China Foundry2006，3，3： | 1 |
| 6 | Numerical Simulation of Microstructure Formation and Forecast of Mechanical Properties for Spheroidal Graphite Iron显示文摘The numerical simulation can overcome the hardship of mathematical analysis and experimental research, explicate the mechanism of microstructure shaping, predict mechanical properties and operating life of castings and then optimize technology and control microstructure formation to obtain the qualified castings. The finite difference method (FDM) is applied to the simulation of temperature field based on all kinds of nucleation and growth models on all stages of solidification of spheroidal graphite cast iron. Visual C++ is used to program the numerical simulation software, QTstructure-1 to simulate the solidification process of spheroidal graphite cast iron and the formation of all phases in solidification process. Finally, the result of simulation is well agreed with the experimental result. | Weimin ZHAO Shuping HOU Haipeng LI Aiwen HU | 2003 | Journal of Materials Science & Technology2003，19，z1： | 0 |
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