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| 1 | CuZnAl Shape Memory Alloy Refined with Composite Rare Earths La+Ce显示文摘The effects of composite rare earths La+Ce on properties of CuZnAl shape memory alloys were studied bymetallograph examination, tensile and bending tests, electric resistivity measurements, EDS and SEM. The test resultsshow that the grain size of CuZnAl shape memory alloys could be diminished effectively and the mechanical propertiesimproved obviously by the addition of composite rare earths La+Ce (La: Ce=1: 1). Meanwhile, the excellent shapememory properties remained unchanged. The results of microanalyses indicate that the composite rare earths were segregated at grain boundaries and impeded the grain growth, leading to the improvement of the mechanical properties ofCuZnAl alloys. If the amount of composite rare earths La+Ce was greater than 0. 10%, the shape memorial propertiesbecame poor. | 司乃潮 | 1999 | Journal of Rare Earths1999，17，4： | 16 |
| 2 | Selective laser melting of NiTi alloy with superior tensile property and shape memory effect显示文摘It is a challenge to develop complex-shaped Ni Ti shape memory alloy parts by traditional processing methods, due to the poor machinability of Ni Ti alloy. It is reported that selective laser melting(SLM) of additive manufacturing could overcome this problem. However, the reported SLM-produced Ni Ti exhibits poor tensile ductility due to the inner defects and adverse unidirectional columnar grains from SLM process. In this work, the defect-less SLM-Ni Ti with nondirective columnar grains was fabricated by optimizing the intraformational laser scanning length and interformational laser scanning direction. The obtained lath-shaped SLM-Ni Ti sample exhibits tensile strain of 15.6%, more than twice of the reported maximum result(7%). Besides, the SLM-Ni Ti part with complex geometry displays a shape memory recovery of 99% under compressive deformation of 50%. | Zhiwei Xiong Zhonghan Li Zhen Sun Shijie Hao Ying Yang Meng Li Changhui Song Ping Qiu Lishan Cui | 2019 | Journal of Materials Science & Technology2019，35，10： | 15 |
| 3 | ORDER STATE AND STABILITY OF MARTENSITE IN AN AIR-QUENCHED Cu-Zn-Al ALLOY显示文摘ORDERSTATEANDSTABILITYOFMARTENSITEINANAIR-QUENCHEDCu-Zn-AlALLOY￥WangMingpu;JinZhanpeng;YinZhimin;XuGenyin(DepartmentofMateria... | Wang Mingpu Jin Zhanpeng Yin Zhimin Xu Genyin(Department of Materials Science and Engineering,Central South University of Technology, Changsha 410083 Anhui Institute of Technology, Hefei 230069) | 1996 | 中国有色金属学会会刊:英文版1996，6，3： | 8 |
| 4 | Design optimization of cast Cu-Al-Be-B alloys for high damping capacity显示文摘This paper investigated high-damping Cu-Al-Be-B cast alloys using metallographic analysis, X-ray diffraction (XRD) and electrical resistance measurements for transformation temperatures. The results showed that beryllium can stabilize β phase, resulting in a thermo-elastic martensite microstructure leading to high-damping capacity in cast Cu-Al-Be-B alloys. Trace additions of boron to Cu-Al-Be alloys can significantly refine the grains, providing high strength and ductility to the alloys. A factorial design of experiment method was used to optimize the composition and properties of cast Cu-Al-Be-B alloys. The optimal microstructure for thermo-elastic martensite can be obtained by adjusting the amounts of aluminum and beryllium to eutectoid or pseudo-eutectoid compositions. An optimized cast Cu-Al-Be-B alloy was developed to provide excellent mechanical properties, tensile strength σ_b=767MPa, elongation δ=7.62%, and damping capacity S. D. C=18.70%. | ~*S. Lu~(1,2), W. H. Miao~1, J. Chen~1, P. H. Lin~2 (1. Department of Materials Engineering, East China Ship Building Institute of Technology, Zhenjiang 212003, Jiangsu, P. R. Chine 2. Department of Mechanical Engineering, Southeast University, Nonjing 210096, Jiangsu, P. R. Chine) | 2004 | China Foundry2004，1，S1： | 8 |
| 5 | Martensitic transformation involved mechanical behaviors and wide hysteresis of NiTiNb shape memory alloys | Minjuan Wang Mingyang Jiang Guangyue Liao Shun Guo Xinqing Zhao | 2012 | Progress in Natural Science:Materials International2012，22，2： | 7 |
| 6 | Recent progress in 4D printing of stimuli-responsive polymeric materials显示文摘4D printing is proposed based on the additive manufacturing of stimuli-responsive materials and structures,which can realize shape changing upon external stimuli.This article reviews the 4D printing methods and actuating performances of 4D printing structures based on shape memory polymers,hydrogels,liquid crystal elastomers,and electroactive polymers.This article shows that the shape morphing properties of single materials are limited,while 4D printing of composites can integrate the various driving modes of different smart materials.In the end,challenges facing 4D printing such as broadening the scope of smart materials,improving printing processes,the compatibility of printing different materials have been discussed. | MA SuQian ZHANG YunPeng WANG Meng LIANG YunHong REN Lei REN LuQuan | 2020 | Science China(Technological Sciences)2020，63，4： | 7 |
| 7 | Nonlinear hysteresis identification and compensation based on the discrete Preisach model of an aircraft morphing wing device manipulated by an SMA actuator显示文摘The conception of aircraft morphing wings thrives in aeronautics since the appearance of shape memory alloys(SMAs). An aircraft morphing wing device, manipulated by an SMA actuator, inherits the intrinsic nonlinear hysteresis from the SMA actuator, ending up with control disadvantages. Conventionally, systems with SMA actuators are constrained to bi-stable states to bypass the hysteresis region. Rather than retreating a morphing wing device to bi-stable states, this paper is dedicated to transcend the morphing wing device beyond the customary limit. A methodology of discrete Preisach modeling, which identifies the hysteresis of the morphing wing device, is proposed herein. An array of discrete equal-distance points is applied to the Preisach plane in order to derive the Preisach density over the partitioned unit of the Preisach plane. Discrete Preisach modeling is fulfilled by the discrete first-order reversible curve(DFORC). By utilizing the discrete Preisach model, the aircraft morphing wing device is simulated; the validity and accuracy of discrete Preisach modeling are demonstrated by contrasting the simulated outcome with experimental data of the major hysteretic loop and the wingspan-wise displacement over time; a comparison between simulation and experimental results exhibits consistency. Afterwards, a hysteresis compensation strategy put forward in this paper is implemented for quasi-linear control of the aircraft morphing wing device, which manifests a compensated shrinking hysteresis loop and attains the initiative of extending the morphing range to the intrinsic hysteretic region. | Yuchen CHEN Xing SHEN Jiefeng LI Jinjin CHEN | 2019 | Chinese Journal of Aeronautics2019，32，4： | 7 |
| 8 | Martensitic transformation,shape memory effect and superelasticity of Ti-xZr-(30-x)Nb-4Ta alloys显示文摘Martensitic transformations,mechanical properties,shape memory effect and superelasticity of Ti-xZr-(30-x)Nb-4Ta(x=15,16,17 and 18;at%) alloys were investigated.X-ray diffraction(XRD),optical microscopy(OM) and transmission electron microscopy(TEM) results indicated that the Ti-16Zr-14Nb-4Ta,Ti-17Zr-13Nb-4Ta and Ti-18Zr-12Nb4Ta alloys were mainly composed of α″-martensite,while the Ti-15Zr-15Nb-4Ta alloy was characterized by predominant p phase.The reverse martensitic transformation temperatures increased when Nb was replaced by Zr,indicating stronger p-stabilizing effect for the former.The Ti-15Zr-15Nb-4Ta alloy displayed superelasticity during tensile deformation with a recovery strain of 3.51%.For the other three alloys with higher Zr content,the martensitic reorientation occurred during tensile deformation,resulting in shape memory recovery upon subsequent heating.The maximum shape memory effect was 3.46% in the Ti-18Zr-12Nb-4Ta alloy. | Wen-Tao Qu Hao Gong Jun Wang Yong-Sheng Nie Yan Li | 2019 | Rare Metals2019，38，10： | 7 |
| 9 | Structure design of high-performance Cu-based shape memory alloys显示文摘The effects of various structure factors on the properties(superelasticity mainly) of Cu-based shape memory alloys(SMAs) were systematically evaluated in this review article through literatures combining with our work. It is concluded that besides the decisive role of grain orientation, the grain boundary(GB) characteristics also play important roles in the superelasticity, which include GB area, GB type, GB morphology and GB direction in descending order of the effect significance. According to the above results, the prior principles of structure design are proposed for high-performance Cu-based SMAs from most to least important:(1) obtaining grain orientation with high phase transformation strain;(2) increasing grain size or reducing GB area;(3) obtaining straight low-energy GBs, especially low-angle GBs;(4) trying to make GB direction parallel to external stress. Consistent with the main or all principles, the bamboo-like-grained and columnar-grained(CG) Cu-based SMAs show excellent comprehensive properties. | Jian-Xin Xie Ji-Li Liu Hai-You Huang | 2015 | Rare Metals2015，34，9： | 7 |
| 10 | Improvement of Artificial Foldable Wing Models by Mimicking the Unfolding/Folding Mechanism of a Beetle Hind Wing显示文摘In an attempt to realize a flapping wing micro-air vehicle with morphing wings, we report on improvements to our previousfoldable artificial hind wing.Multiple hinges, which were implemented to mimic the bending zone of a beetle hind wing, weremade of small composite hinge plates and tiny aluminum rivets.The buck-tails of rivets were flared after the hinge plates wereassembled with the rivets so that the folding/unfolding motions could be completed in less time, and the straight shape of theartificial hind wing could be maintained after fabrication.Folding and unfolding actions were triggered by electrically-activatedShape Memory Alloy (SMA) wires.For wing folding, the actuation characteristics of the SMA wire actuator were modifiedthrough heat treatment.Through a series of flapping tests, we confirmed that the artificial wings did not fold back and arbitrarilyfluctuate during the flapping motion. | Azhar Muhammad Quoc Viet Nguyen Hoon Cheol Park Do Y.Hwang Doyoung Byun Nam Seo Goo | 2010 | Journal of Bionic Engineering2010，7，2： | 6 |
| 11 | A macro-mechanical constitutive model of shape memory alloys显示文摘It is of practical interest to establish a precise constitutive model which includes the equations describing the phase transformation behaviors and thermo-mechanical processes of shape memory alloy (SMA). The microscopic mechanism of super elasticity and shape memory effect of SMA is explained based on the concept of shape memory factor defined by the author of this paper. The conventional super elasticity and shape memory effect of SMA are further unified as shape memory effect. Shape memory factor is redefined in order to make clear its physical meaning. A new shape memory evolution equation is developed to predict the phase transformation behaviors of SMA based on the differential relationship between martensitic volume fraction and phase transformation free energy and the results of DSC test. It overcomes the limitations that the previous shape memory evolution equations or phase transformation equations fail to express the influences of the phase transformation peak temperatures on the phase transformation behaviors and the transformation from twinned martensite to detwinned martensite occurring in SMA. A new macro-mechanical constitutive equation is established to predict the thermo-mechanical processes realizing the shape memory effect of SMA from the expression of Gibbs free energy. It is expanded from one-dimension to three-dimension with assuming SMA as isotropic material. All material constants in the new constitutive equation can be determined from macroscopic experiments, which makes it more easily used in practical applications. | ZHOU Bo LIU YanJu LENG JinSong ZOU GuangPing | 2009 | Science China(Physics,Mechanics & Astronomy)2009，52，9： | 6 |
| 12 | A macroscopic multi-mechanism based constitutive model for the thermo-mechanical cyclic degeneration of shape memory effect of NiTi shape memory alloy显示文摘A macroscopic based multi-mechanism constitutive model is constructed in the framework of irreversible thermodynamics to describe the degeneration of shape memory effect occurring in the thermo-mechanical cyclic deformation of NiTi shape memory alloys(SMAs). Three phases,austenite A, twinned martensite Mtand detwinned martensite M^d, as well as the phase transitions occurring between each pair of phases( A → M^t, M^t→ A, A → M^d,M^d→ A, and M^t→ M^d) are considered in the proposed model. Meanwhile, two kinds of inelastic deformation mechanisms, martensite transformation-induced plasticity and reorientation-induced plasticity, are used to explain the degeneration of shape memory effects of NiTi SMAs. The evolution equations of internal variables are proposed by attributing the degeneration of shape memory effect to the interaction between the three phases(A, M^t, and M^d) and plastic deformation. Finally, the capability of the proposed model is verified by comparing the predictions with the experimental results of NiTi SMAs. It is shown that the degeneration of shape memory effect and its dependence on the loading level can be reasonably described by the proposed model. | Chao Yu Guozheng Kang Qianhua Kan | 2017 | Acta Mechanica Sinica2017，33，3： | 6 |
| 13 | STABILIZATION OF MARTENSITE IN Cu-Zn-Al ALLOY AND ITS REVERSE SHAPE MEMORY EFFECT显示文摘INTRODUCTIONThestabilizationofmartensitereferstothephenomenonthatthereversetransformationstartandfinishtemperatures(AsandAf)i... | Cheng Yan and Wang Mingpu Department of Materials Science and Engineering, Central South University of Technology, Changsha 410083, P. R. China | 1998 | 中国有色金属学会会刊:英文版1998，8，4： | 5 |
| 14 | EFFECT OF MICROSTRUCTURE ON THE HARDENING AND SOFTENING BEHAVIORS OF POLYCRYSTALLINE SHAPE MEMORY ALLOYS PART Ⅰ:MICROMECHANICS CONSTITUTIVE MODELING显示文摘The effects of microstructure and its evolution on the macroscopicsuperelastic stress-strain response of polycrystalline Shape Memory Alloy(SMA)arestudied by a microstructure-based constitutive model developed in this paper.Themodel is established on the following basis:(1)the transformation conditions of theunconstrained single crystal SMA microdomain(to be distinguished from the bulksingle crystal),which serve as the local criterion for the derivation of overall transfor-mation yield conditions of the polycrystal;(2)the micro-to macro-transition schemeby which the connection between the polycrystal aggregates and the single crystalmicrodomain is established and the macroscopic transformation conditions of thepolycrystal SMA are derived;(3)the quantitative incorporation of three microstruc-ture factors(i.e.,nucleation,growth and orientation distribution of martensite)intothe modeling.These microstructural factors are intrinsic of specific polycrystal SMAsystems and the role of each factor in the macroscopic constitutive response is quan-titatively modeled.It is demonstrated that the interplay of these factors will resultin different macroscopic transformation kinematics and kinetics which are responsiblefor the observed macroscopic stress-strain hardening or softening response,the latterwill lead to the localization and propagation of transformation bands in TiNi SMA. | 宋固全 孙庆平 黄克智 | 2000 | Acta Mechanica Sinica2000，16，4： | 5 |
| 15 | Formation of Poly(ε-caprolactone) Networks via Supramolecular Hydrogen Bonding Interactions显示文摘In this contribution, we reported a novel approach to crosslink poly(ε-caprolactone)(PCL) via supramolecular hydrogen bonding interactions. First, a series of octa-armed poly(ε-caprolactone) stars with polyhedral oligomeric silsesquioxane(POSS) cores were synthesized via the ring-opening polymerizations. Thereafter, the arm ends of organic-inorganic star-shaped PCLs were reacted with 2-(6-isocyanatohexylaminocarbonylamino)-6-methyl-4[1 H]-pyrimidinone to obtain 2-ureido-4[1 H]-pyrimidone(UPy)-terminated PCL stars.Notably, the UPy-terminated PCL stars were physically crosslinked, which was evidenced by means of dynamic mechanical thermal analysis(DMTA) and rheological analysis. Owing to the formation of the physically-crosslinked networks, the organic-inorganic PCL stars displayed significant shape memory properties with about 100% of shape recovery, which was in marked contrast to the PCL stars without UPy termini. | Sen Xu Pengfei Chang Bingjie Zhao Muhammad Adeel Sixun Zheng | 2019 | Chinese Journal of Polymer Science2019，37，3： | 5 |
| 16 | Variable-model SMA-driven spherical robot显示文摘In this paper, we introduce a bionic spherical robot. This research has been inspired by the muscular organs and modularity of organisms such as starfish and octopuses. The robot that we fabricated uses five soft feet to crawl like a starfish, and the robotic feet are driven by the shape memory alloy springs. The robotic spherical structure and the soft feet were fabricated by 3 D printing. The robotic feet were made of silicone gel;these feet could bend upward and downward to help the robot to crawl on the ground and roll down a slope. The shell separation module installed inside the robot could divide the robot into two identical modules, and this smart structure could enhance the robotic flexibility in a small space. We performed force analysis and robotic simulation, and the results verified the feasibility of the model. The robot can switch between rigidity and softness by using human control. Three types of gaits have been proposed for controlling robotic movement and improving robotic flexibility in movement;these include rolling, crawling, and avoiding obstacles. The results of this study indicate that the variable-model design of the robot is an effective way to enhance the flexibility of soft robots. | PAN Jie SHI ZhenYun WANG TianMiao | 2019 | Science China(Technological Sciences)2019，62，8： | 5 |
| 17 | 生物医用钛基无镍记忆合金研究进展显示文摘综述近年来国内外关于Ti基无Ni记忆合金的研究进展,主要介绍Ti-Nb和Ti-Mo基二元及三元合金的记忆性能和超弹性行为,重点评述合金的微观结构、相变以及力学性能等特点,并提出一些值得关注的问题。 | 崔琰 李岩 罗坤 徐惠彬 | 2010 | 稀有金属材料与工程2010，39，9： | 4 |
| 18 | TiNiCu形状记忆合金薄带研究进展显示文摘TiNiCu形状记忆合金薄带凭借其窄相变滞后、优异的形状记忆效应与超弹性、良好的热循环稳定性成为一种很有前途的微驱动器材料。本文全面阐述了国内外在TiNiCu薄带研究方面的最新进展,主要包括晶化行为、显微组织、马氏体相变行为、形状记忆效应与超弹性,重点介绍了热处理工艺-显微组织-性能之间的内在联系,探讨了TiNiCu薄带今后的研究重点。 | 佟运祥 陈枫 王本力 李莉 郑玉峰 | 2010 | 稀有金属材料与工程2010，39，12： | 4 |
| 19 | 4D printed shape memory polymers and their structures for biomedical applications显示文摘Shape memory polymers are smart materials that produce shape changes under external stimulus conditions.Four-dimensional(4D)printing is a comprehensive technology originate from deformable materials and three-dimensional(3D)printing technology.At present,4D printed shape memory polymers and shape-changing structures have been applied in various fields,especially in the field of biomedical science.4D printing technology has made a breakthrough of personalized customization in the traditional medical field,providing a new direction for the further development of the biomedical field.In this review,the recent research and development of shape memory polymer,3D printing technology,4D printed shape memory polymers and shape-changing structures in biomedical area are present.The examples and applications of 4D printed shape memory polymers and their structures in the area of biomedical are also introduced.Based on 4D printing,stimulated by different conditions,3D printed objects can be fabricated into various biomedical applications such as cell scaffolds,vascular stents,bone scaffolds,tracheal stents and cardiac stents by different 3D printing techniques.Finally,the application prospects,existing technical restriction and future development directions of 4D printed shape memory polymers and their structures in the biomedical field are summarized. | LI YueJia ZHANG FengHua LIU YanJu LENG JinSong | 2020 | Science China(Technological Sciences)2020，63，4： | 4 |
| 20 | Nanocrystalline Ti49.2Ni50.8 shape memory alloy as orthopaedic implant material with better performance显示文摘Ti Ni alloys, with their unique shape memory effects and super elastic properties, occupy an indispensable place in the family of metallic biomaterials. In the past years, surface treatment is the main technique to improve the bioinert nature of microcrystalline Ti Ni alloys and inhibit on the release of toxic nickel ions to obtain excellent osteogenesis and osseointegration function. In the present study, nanocrystalline Ti49.2Ni50.8 alloy has been fabricated via equal channel angular pressing(ECAP), and the in vitro and in vivo studies revealed that it had enhanced cell viability, adhesion, proliferation, ALP(Alkaline phosphatase)activity and mineralization, and increased periphery thickness of new bone, in comparison to the commercial coarse-grained counterpart. These findings indicate that the reduction of grain size is beneficial to increasing the biocompatibility of Ti49.2Ni50.8 shape memory alloy. | H.F.Li F.L.Nie Y.F.Zheng Y.Cheng S.C.Wei R.Z.Valiev | 2019 | Journal of Materials Science & Technology2019，35，10： | 4 |
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