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| 1 | Versatile zero- to three-dimensional carbon for electrochemical energy storage显示文摘Secondary batteries have been widely developed and used in various fields,such as large-scale energy storage,portable electronics,and electric vehicles.Carbon-based materials have attracted considerable attention due to their abundance,environmental friendliness,tunable structure,and excellent chemical stability.Beyond the commercial carbon for batteries and supercapacitors,many studies focused on advanced and multifunctional carbon with various structures for electrochemical energy storage.This review summarizes the zero-to three-dimensional carbon-based materials and reviews their various electrochemical applications based on their structural characteristics.The importance of carbon structures and the relationship between materials'structures and electrochemical performance are discussed.Then,the prospects and potential challenges of using advanced carbon to formulate designs and develop novel carbonaceous materials with high electrochemical performance are further discussed. | Yuyue Zhao Yunlu Zhang Ying Wang Daxian Cao Xiao Sun Hongli Zhu | 2021 | Carbon Energy2021,3,6: | 3 |
| 2 | Carbon-based flexible self-supporting cathode for lithium-sulfur batteries:Progress and perspective显示文摘The flexible self-supporting electrode can maintain good mechanical and electrical properties while retaining high specific capacity,which meets the requirements of flexible batteries.Lithium-sulfur batteries(LSBs),as a new generation of energy storage system,hold much higher theoretical energy density than traditional batteries,and they have attracted extensive attention from both the academic and industrial communities.Selection of a proper substrate material is important for the flexible self-supporting electrode.Carbon materials,with the advantages of light weight,high conductivity,strong structural plasticity,and low cost,provide the electrode with a large loading space for the active material and a conductive network.This makes the carbon materials meet the mechanical and electrochemical requirements of flexible electrodes.In this paper,the commonly used fabrication methods and recent research progresses of the flexible self-supporting cathode with a carbon material as the substrate are introduced.Various sulfur loading methods are summarized,which provides useful information for the structural design of the cathode.As the first review article of the carbon-based flexible self-supporting LSB cathodes,it provides valuable guidance for the researchers working in the field of LSB. | Qinghuiqiang Xiao Jinlin Yang Xiaodong Wang Yirui Deng Peng Han Ning Yuan Lei Zhang Ming Feng Chang‐an Wang Ruiping Liu | 2021 | Carbon Energy2021,3,2: | 3 |
| 3 | Metal-organic framework derived porous cathode materials for hybrid zinc ion capacitor显示文摘Aqueous zinc ion hybrid capacitor(AZHC)is an emerging energy storage device.It combines the merits of secondary battery and supercapacitor.Nonetheless,the low energy density and cycling capability need to be further enhanced.Therefore,it is crucial to construct a viable electrode material for improving the electrochemical performance of AZHC.In this work,we prepare mesoporous VO/C microcubes by a high-temperature carbonization strategy. | Ying Liu Ahmad Umar Xiang Wu | 2022 | Rare Metals2022,41,9: | 2 |
| 4 | Rational modulation of emerging MXene materials for zinc-ion storage显示文摘Currently,emerging battery technologies are being studied intensively.The lack of ideal electrode materials remains a key hindrance to further development of new batteries.The novel MXene material,due to its unique structural characteristics and physicochemical properties,shows the ability to enhance the electrochemical performance of the electrode.In addition to the adjustable layer spacing,because of excellent electrical conductivity,rich chemical composition,and controllable surface chemistry,MXene has the potential for use in diverse applications as an ideal electrode material in various battery systems.This review covers the recent progress achieved in research of the zinc-ion energy storage of MXenes,including MXene-based cathodes,MXenederived cathodes,MXene-modified zinc anodes,and electrolyte additives.Moreover,further structural design and reaction mechanisms of MXenes in zinc-ion storage are explored. | Penggao Liu Weifang Liu Kaiyu Liu | 2022 | Carbon Energy2022,4,1: | 2 |
| 5 | Photo-rechargeable batteries and supercapacitors:Critical roles of carbon-based functional materials显示文摘As a clean and renewable energy source,solar energy is a competitive alternative to replace conventional fossil fuels.Nevertheless,its serious fluctuating nature usually leads to a poor alignment with the actual energy demand.To solve this problem,the direct solar-to-electrochemical energy conversion and storage have been regarded as a feasible strategy.In this context,the development of high-performance integrated devices based on solar energy conversion parts(i.e.,solar cells or photoelectrodes)and electrochemical energy storage units(i.e.,rechargeable batteries or supercapacitors[SCs])has become increasingly necessary and urgent,in which carbon and carbon-based functional materials play a fundamental role in determining their energy conversion/storage performances.Herein,we summarize the latest progress on these integrated devices for solar electricity energy conversion and storage,with special emphasis on the critical role of carbon-based functional materials.First,principles of integrated devices are introduced,especially roles of carbon-based materials in these hybrid energy devices.Then,two major types of important integrated devices,including photovoltaic and photoelectrochemicalrechargeable batteries or SCs,are discussed in detail.Finally,key challenges and opportunities in the future development are also discussed.By this review,we hope to pave an avenue toward the development of stable and efficient devices for solar energy conversion and storage. | Liqun Wang Lei Wen Yueyu Tong Sihui Wang Xinggang Hou Xiaodong An Shi Xue Dou Ji Liang | 2021 | Carbon Energy2021,3,2: | 0 |
| 6 | Structural energy storage composites based on modified carbon fiber electrode with metal-organic frame enhancing layered double hydroxide显示文摘Structural energy storage composites present advantages in simultaneously achieving structural strength and electrochemical properties.Adoption of carbon fiber electrodes and resin structural electrolytes in energy storage composite poses challenges in maintaining good mechanical and electrochemical properties at reasonable cost and effort.Here,we report a simple method to fabricate structural supercapacitor using carbon fiber electrodes(modified by Ni-layered double hydroxide(Ni-LDH)and in-situ growth of Co-metal-organic framework(Co-MOF)in a two-step process denoted as Co-MOF/Ni-LDH@CF)and bicontinuous-phase epoxy resin-based structural electrolyte.Co-MOF/Ni-LDH@CF as electrode material exhibits improved specific capacity(42.45 F·g^(-1))and cycle performance(93.3%capacity retention after 1000 cycles)in a three-electrode system.The bicontinuous-phase epoxy resin-based structural electrolyte exhibits an ionic conductivity of 3.27×10^(-4) S·cm^(-1).The fabricated Co-MOF/Ni-LDH@CF/SPE-50 structural supercapacitor has an energy density of 3.21 Wh·kg^(-1) at a power density of 42.25 W·kg^(-1),whilst maintaining tensile strength and modulus of 334.6 MPa and 25.2 GPa.These results show practical potential of employing modified commercial carbon fiber electrodes and epoxy resin-based structural electrolytes in structural energy storage applications. | Jinrui Ye Zhongbao Wang Qin Lei Lei Sun Jinfeng Gu | 2024 | Nano Research2024,17,3: | 0 |
| 7 | 基于卟啉-⁃金属有机框架材料的光动力疗法研究进展显示文摘卟啉‐金属有机框架(MOFs)材料是由金属节点和卟啉有机配体构成的一类新型多孔材料,MOFs骨架上的卟啉配体在光激发下,可以发挥光动力学治疗(PDT)作用。这类多孔结构的PDT材料在疾病治疗中,可以发挥载药、多功能修饰等功能,某些金属位点独特的MOFs还具有纳米酶功能。近年来,这类卟啉‐MOFs已经成为PDT领域的重要研究方向。目前,在推向临床前,这类材料还需要解决氧气浓度、能量传递效率等问题,研究者也给出了诸多解决方案,根据实际应用过程中所面对的不同环境,采取不同手段来增强PDT的效果,包括提高氧气浓度、改进能量传递过程、消耗功能分子、产生信号分子以及协同策略等。本文综述了近年来的代表性工作,包括卟啉‐MOFs材料以及PDT产生的机制,卟啉‐MOFs材料PDT的应用和最新进展,并针对卟啉‐MOFs材料的PDT在生物医学领域未来发展趋势进行了展望。 | 孔庆超 孙文悦 林金莹 王林 董彪 | 2023 | 发光学报2023,44,8: | 0 |
| 8 | MOF衍生物/生物质碳基钠电池电极材料的研究进展显示文摘钠(Na)电池具有原料成本低、储量大、能量密度较大等特点,是极具发展前景的下一代电池材料之一。生物质具有可持续发展、环境友好、结构多样和高反应活性等优点。由金属-有机骨架(MOF)衍生物和生物质材料制备的多孔碳基材料能够提供主体框架,利用孔结构增大碳的层间间距,保证足够的层间空间用于Na^(+)插入,促进电子转移,从而提高电池的电化学性能。综述了常见的生物质碳基材料、MOF及其衍生物、MOF/生物质复合材料钠电池负极材料的相关研究进展,以期为开发高性能MOF衍生物/生物质碳基复合钠电池电极材料提供理论依据。 | 何玉琼 张玉婷 王娅欣 杜官本 徐开蒙 | 2023 | 林产工业2023,60,9: | 0 |