维普中文期刊产品整合服务
共被期刊论文引用了2次 您的检索式:您选中1篇文献正在查看引证文献汇总
    题名 作者 年代 出处 被引量
1Modulating metal-organic frameworks for catalyzing acidic oxygen evolution for proton exchangemembrane water electrolysis显示文摘Proton exchangemembrane(PEM)water electrolysis represents one of the most promising technologies to achieve green hydrogen production,but currently its practical viability is largely affected by the slow reaction kinetics of the anodic oxygen evolution reaction(OER)in an acidic environment.While noble metal-based catalysts containing iridium or ruthenium are excellent catalysts for the acidic OER,their practical use in PEM electrolyzers is hindered due to their low abundance and high cost.Most recently,metal-organic frameworks(MOFs)have been demonstrated as a perfect platform to facilitate the design of acidic OER catalysts with both high efficiency and cost-effectiveness.Here,we pro-vide a timely and comprehensive overview of the recent progress on MOF-based acidic OER catalysts.The fundamental mechanisms of the acidic OER are first introduced,followed by a summary of the development of pristine MOFs and MOF derivatives as acidic OER catalysts.Importantly,a number of catalyst design strategies are discussed aiming at improving the acidic OER catalytic per-formance of MOF-based candidates.The integration of MOF-based catalysts into real PEM water electrolyzers is also included.Finally,future research directions are provided to achieve better MOF-based catalysts operational in acidic envi-ronments and PEM devices.Xiaomin Xu Hainan Sun San Ping Jiang Zongping Shao 2021SusMat2021,1,4:1
2用于酸性析氧反应研究的原位表征技术显示文摘质子交换膜(PEM)水电解的阳极催化剂需要耐受强酸性环境以及析氧反应(OER)条件下的高氧化电位。为了加深对酸性介质中OER过程的理解以开发具有更好稳定性与更高活性的电催化剂,研究和发展原位表征技术显得尤为重要。该综述介绍了几种用于酸性OER研究的原位表征技术,包括:原位X射线光电子能谱技术、原位X射线吸收谱技术、原位X射线衍射/散射技术、原位电化学红外技术、原位电化学拉曼技术、原位电感耦合等离子体-质谱技术、微分电化学质谱/在线电化学质谱技术、电化学石英微晶天平技术。重点讨论了这些技术的原位装置设计以及它们在酸性OER研究领域的具体应用。最后总结了这些技术的特征,并指出用于酸性OER的原位表征技术的发展之有待解决的问题,即新技术的研发与原位技术间的联用、原位装置的改进及时空分辨率的提高。杨家豪 施兆平 王意波 葛君杰 刘长鹏 邢巍 2021储能科学与技术2021,10,6:0
返回顶部 每页显示:
共1页 首页 上一页 第1页 下一页 末页 /1 跳转

网站首页 | 关于我们 | 联系我们 | 产品服务 | 客服中心 | 广告服务 | 版权声明 | 网站联盟 | 友情链接 | 售卡网点

版权所有© 渝B2-20050021-1 渝公网安备 50019002500403号 违法和不良信息举报中心

互联网出版许可证 新出网证(渝)字10号 全国400电话 - 免长途话费