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| 1 | Advanced transition metal/nitrogen/carbon-based electrocatalysts for fuel cell applications显示文摘The development of advanced transition metal/nitrogen/carbon-based(M/N/C)catalysts with high activity and extended durability for oxygen reduction reaction(ORR)is critical for platinum-group-metal(PGM)free fuel cells but still remains great challenging.In this review,we summarize the recent progress in two typical M/N/C catalysts(atomically dispersed metal-nitrogen-carbon(M-N-C)catalysts and carbon-supported metal nanoparticles with N-doped carbon shells(M@NC))with an emphasis on their potential applications in fuel cells.Starting with understanding the active sites in these two types of catalysts,the representative innovative strategies for enhancing their intrinsic activity and increasing the density of these sites are systematically introduced.The synergistic effects of M-N-C and M@NC are subsequently discussed for those M/N/C catalysts combining both of them.To translate the material-level catalyst performance into high-performance devices,we also include the recent progress in engineering the porous structure and durability of M/N/C catalysts towards efficient performance in fuel cell devices.From the viewpoint of industrial applications,the scale-up cost-effective synthesis of M/N/C catalysts has been lastly briefed.With this knowledge,the challenges and perspectives in designing advanced M/N/C catalysts for potential PGM-free fuel cells are proposed. | Tang Tang Liang Ding Zhe Jiang Jin-Song Hu Li-Jun Wan | 2020 | Science China Chemistry2020,63,11: | 5 |
| 2 | Trimetallic Au@PdPb nanowires for oxygen reduction reaction显示文摘The development of highly efficient and stable Pd-based catalysts is crucial to improve their sluggish oxygen reduction reaction(ORR)kinetics in acid media.To improve ORR activity and utilization efficiency of Pd,an ideal catalyst should have ORR-favorable chemical environment,optimized geometric structure,and long periods of operation.In this work,we first synthesize a novel trimetallic Au@PdPb core–shell catalyst consisting of PdPb alloy nano-layers grown on the surface of ultrathin Au nanowires(NWs)by a two-step water-bath method.The Au@PdPb NWs have the merits of anisotropic one-dimensional nanostructure,high utilization efficiency of Pd atoms and doping of Pb atoms.Because of the structural and multiple compositional advantages,Au@PdPb NWs exhibit remarkably enhanced ORR activity with a high haIf-wave potential(0.827 V),much better than those of commercial Pd black(0.788 V)and bimetallic Au@Pd NWs(0.803 V).Moreover,Au@PdPb NWs display better electrocatalytic stability for the ORR than those of Pd black and Au@Pd NWs.This study demonstrates the validity of our approach for deriving highly ORR-active Pd-based catalysts by modifying their structure and composition. | Xian Jiang Yuexin Xiong Ruopeng Zhao Jiancheng Zhou Jong-Min Lee Yawen Tang | 2020 | Nano Research2020,13,10: | 3 |
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