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| 1 | A review on synthesis of graphene,h-BN and MoS2 for energy storage applications:Recent progress and perspectives显示文摘The significance of graphene and its two-dimensional(2D)analogous inorganic layered materials especially as hexagonal boron nitride(h-BN)and molybdenum disulphide(MoS2)for“clean energy”applications became apparent over the last few years due to their extraordinary properties.In this review article we study the current progress and selected challenges in the syntheses of graphene,h-BN and MoS2 including energy storage applications as supercapacitors and batteries.Various substrates/catalysts(metals/insulator/semiconducting)have been used to obtain graphene,h-BN and MoS2 using different kinds of precursors.The most widespread methods for synthesis of graphene,h-BN and MoS2 layers are chemical vapor deposition(CVD),plasma-enhanced CVD,hydro/solvothermal methods,liquid phase exfoliation,physical methods etc.Current research has shown that graphene,h-BN and MoS2 layered materials modified with metal oxide can have an insightful influence on the performance of energy storage devices as supercapacitors and batteries.This review article also contains the discussion on the opportunities and perspectives of these materials(graphene,h-BN and MoS2)in the energy storage fields.We expect that this witen review article including recent research on energy storage will help in generating new insights for further development and practical applications of graphene,h-BN and MoS2 layers based materials. | Rajesh Kumar Sumanta Sahoo Ednan Joanni Rajesh Kumar Singh Ram Manohar Yadav Rajiv Kumar Verma Dinesh Pratap Singh Wai Kian Tan Angel Perez del Pino Stanislav A.Moshkalev Atsunori Matsuda | 2019 | Nano Research2019,12,11: | 12 |
| 2 | Mn3O4-石墨烯气凝胶的高效制备及其储锂性能显示文摘以改进的Hummers法制备的Mn^2+/氧化石墨烯悬浊液为原料无需添加锰源,采用水热法得到Mn3O4含量可调的Mn3O4-石墨烯气凝胶(Mn3O4-GA)。得益于石墨烯气凝胶相互连通的三维导电网络以及Mn3O4纳米粒子和其间的强烈的耦合作用Mn3O4-GA表现出了比Mn3O4-石墨烯粉末复合物(Mn3O4-G)更加优异的储锂性能其中Mn3O4-GA-70(Mn3O4含量为70%)在100 mA·g^-1的电流密度下其可逆比容量达到1073 mA·h·g^-1,在800 mA·g^-1的电流密度下循环200次后其比容量为565 mA·h·g^-1,保持率为85%。该方法为环境友好制备锰基石墨烯气凝胶提供新思路。 | 高峰 覃仕辉 臧云浩 顾建峰 曲江英 | 2020 | 新型炭材料2020,35,2: | 6 |
| 3 | 富氧空位的钴掺杂NiMoO4纳米片用于高能量密度和循环稳定性的水系镍锌电池显示文摘提高能量密度和循环稳定性对推广水系可充电镍锌电池的广泛应用至关重要.我们采用一种简易的合成方法构建了Co掺杂NiMoO4纳米片,并将其作为正极材料用于高性能镍锌电池.得益于导电性和氧空位浓度的大幅度提升,钴掺杂量为15%的电极材料(CNMO-15)表现出突出的比容量及循环稳定性,在3 A g-1的电流密度下其容量高达361.4 mA h g-1.此外,以CNMO-15为正极组装的镍锌电池(CNMO-15//Zn)也展现了优异的比容量(在2 A g-1的电流密度下高达270.9 mA h g-1),以及高能量密度(在3.5 kW kg-1的功率密度下高达474.1 W h kg-1)和功率密度(在118.8 W h kg-1的能量密度下高达10.3 kW kg-1).值得注意的是,该电池在循环5000圈后容量没有损失,保留了初始容量的119.8%,表现出优异的循环稳定性.本研究可以为未来构建高能量密度和优异循环稳定性的镍锌电池提供非常有价值的参考. | 沈越年 张可 杨方 李志豪 崔哲 邹儒佳 刘倩 胡俊青 徐开兵 | 2020 | Science China Materials2020,63,7: | 3 |
| 4 | 免黏结剂V2O5和Fe2O3柔性电极的构建及在超级电容器中的应用显示文摘近年来,越来越多的研究致力于开发新型、超高能量密度、高法拉第反应活性的电极材料,尤其将其应用于新一代超级电容器储能系统。通过水热法直接在柔性基质碳布上生长海胆状V2O5纳米球和十四面体Fe2O3纳米盒子。V2O5微观结构和储能性能可通过改变水热时间进行调控。海胆状V2O5纳米球正极材料具有最高比容量535 F·g^−1。以十四面体Fe2O3纳米盒子作为负极材料组装的新型结构V2O5-CC//Fe2O3-CC柔性超级电容器,在功率密度为699.49 W·kg^−1时,能量密度可达46.06 W·h·kg^−1。而且具有良好的机械柔韧性,在180°弯曲循环测试5000次,比容量保持率仍高达83.4%。研究为开发下一代超高能量密度、柔性电子器件提供了一种通用而有效的策略。 | 胡兵兵 杨束 李彦 徐川岚 陈鹏 于晶晶 余丹梅 陈昌国 | 2020 | 化工学报2020,71,10: | 2 |
| 5 | Low Li ion diffusion barrier on low-crystalline FeOOH nanosheets and high performance of energy storage显示文摘To obtain symmetric supercapacitors(SCs)with high energy density,it is critical to fabricate an electrode with wide potential window and excellent capacitive performance.Herein,by using the strong double hydrolysis reaction between anions and cations,the FeOOH nanosheets on the surface of activated carbon cloth(FeOOH@AC)are prepared through a simple hydrothermal process.The FeOOH@AC electrode exhibits maximum capacitance of 4,090 mF·cm^−2 at wider potential window-1–0 V and 3,250 mF·cm^−2 at 0–1 V versus SCE in 2 M LiNO3 electrolyte.With two pieces of FeOOH@AC electrodes the obtained symmetric SC can operate at the voltage window of 2 V.This FeOOH symmetric SC shows high energy density of 13.261 mWh·cm^−3 at a power density of 14.824 mW·cm^−3 and maintains 4.175 mWh·cm^−3 at a maximum power density of 118.564 mW·cm^−3,as well as excellent charge storage capacity and cyclic stability.Li ion adsorption and diffusion mechanism on the(200)facets of FeOOH are explained by the density functional theory(DFT)calculations.The simple synthesis process and excellent capacitance performance of the FeOOH@AC composite make it a very promising candidate for high performance symmetric SC electrodes. | Jien Li Shuang Luo Congcong Wang Qian Tang Yanwei Wang Xiangyu Han Hao Ran Jing Wan Xiao Gu Xue Wang Chenguo Hu | 2020 | Nano Research2020,13,3: | 1 |