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    题名 作者 年代 出处 被引量
1Focus on polymer chemistry papers in Science China Chemistry of the year 2010显示文摘The journal Science China Chemistry published 63 papers in polymer fields in 2010,leading to a percentage increase of 473%compared to the year 2008 and 70%to the year 2009,respectively(Figure 1).In this year,three polymer Special Topics were designed and published:Biomedical Polymer(Number 3)[1],Advances in Principles of Polymerization(Number 8)[2]and HighlyTIAN Ying ZHU XiaoWen CAO Yong 2011Science China Chemistry2011,54,2:2
2Development of Science China Chemistry during 2008-2012:From the perspective of Special Issues/Topics显示文摘1 Introduction Science China Press Co.,Ltd.(SCP) is a science and technology(ST) journal publishing company of the Chinese Academy of Sciences(CAS).SCP publishes 16 kinds of academic journals,Science China Series and Chinese Science Bulletin,of which 8 journals are in English and 8SONG GuanQun ZHU XiaoWen 2012Science China Chemistry2012,55,12:2
3Polymers with complicated architectures constructed from the versatile, functional monomer 1-ethoxyethyl glycidyl ether显示文摘Because glycidyl(Gly) contains an epoxy and an active hydroxyl group, the Gly unit is difficult to introduce into certain polymeric chains in a controlled manner and usually yields hyperbranched polyglycidyl. Alternatively, the monomer 1-ethoxyethyl glycidyl ether(EEGE), derived from Gly and ethyl vinyl ether, has shown potential for application in polymer chemistry, and homopolymerization of this monomer directly produces linear poly(1-ethoxyethyl glycidyl ether) and further yields linear polyglycidyl. In this review, the initiation system of the EEGE monomer is first discussed in terms of chain transfer to monomers in ring-opening polymerization of epoxides with substituent groups. Then, random copolymerization of EEGE with other epoxides is considered. In addition, because the EEGE units on polymers can be transferred to Gly units and further used to construct copolymers with complicated architectures, the applications of EEGE monomers to block, graft, and hyperbranched copolymers are reviewed. Finally, the synthesis of main chain and terminal functional polyethers by transforming the hydroxyl groups at the polymer end or on the main chain into certain functional groups are also discussed. Chemistry based on EEGE has been proved to be an efficient, versatile route to constructing copolymers containing Gly units and ultimately yielding the target properties and applications.Jiaxing Zhang Guowei Wang 2015Science China Chemistry2015,58,11:0
4温敏性环状聚合物的制备及表征显示文摘以溴化亚铜(CuBr)/三(2-二甲氨基乙基)胺(Me_(6)TREN)为催化体系,2-氯丙酸炔丙酯(PCP)为引发剂,应用原子转移自由基聚合(ATRP)方法,引发保护炔基基团的甲基丙烯酸丙炔基酯与N-异丙基丙烯酰胺(NIPAM)共聚,得到末端带有炔基基团的线型聚合物,将线型聚合物叠氮化,使其两端分别带有炔基基团和叠氮基团,通过点击反应得到环状聚合物。当外界温度低于低临界溶解温度(LCST)时,环状聚合物溶液是澄清的;当外界温度高于LCST时,环状聚合物溶液是浑浊的,因此表现出良好的温敏性。南婷婷 高正国 林润雄 2022现代塑料加工应用2022,34,2:0
5基于大环聚乙二醇的接枝聚合物的研究显示文摘大环结构的聚合物因其特殊的无端基结构,它的设计与合成在高分子领域一直备受关注。聚乙二醇由于其优良的生物相容性,在体内能溶于组织液中且无任何毒副作用,是一种理想的可用于药物载体的聚合物,广泛应用于化学、生物、医学等领域。本文正是对基于大环聚乙二醇的特殊结构的接枝聚合物的合成研究工作进行了总结。许秋菊 2016化学工程与装备2016,,12:0
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