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1Synthesis of Diethyl Oxalate by a Coupling-Regeneration Reaction of Carbon Monoxide显示文摘This article describes a process for the synthesis of diethyl oxalate by a coupling reaction ofcarbon monoxide, catalyzed by palladium in the presence of ethyl nitrite. The kinetics and mechanism ofthe coupling and regeneration reaction are also discussed. This paper presents the results of a scale-uptest of the catalyst and the process based on an a priori computer simulation.Fandong Meng,Genhui Xu,Baowei Wang,Xinbin Ma1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China 2. Luoyang Petrochemical Engineering Corporation, Luoyang 471003, China revised Apr 2002Journal of Natural Gas Chemistry2002,11,1:2
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