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| 1 | Lithium nitrate regulated carbonate electrolytes for practical Li-metal batteries: Mechanisms, principles and strategies显示文摘Li-metal batteries(LMBs)regain research prominence owing to the ever-increasing high-energy requirements.Commercially available carbonate electrolytes exhibit unfavourable parasitic reactions with Limetal anode(LMA),leading to the formation of unstable solid electrolyte interphase(SEI)and the breed of Li dendrites/dead Li.Significantly,lithium nitrate(LiNO_(3)),an excellent film-forming additive,proves crucial to construct a robust Li_(3)N/Li_(2)O/Li_(x)NO_(y)-rich SEI after combining with ether-based electrolytes.Thus,the given challenge leads to natural ideas which suggest the incorporation of LiNO_(3) into commercial carbonate for practical LMBs.Regrettably,LiNO_(3) demonstrates limited solubility(~800 ppm)in commercial carbonate electrolytes.Thence,developing stable SEI and dendrite-free LMA with the incorporation of LiNO_(3) into carbonate electrolytes is an efficacious strategy to realize robust LMBs via a scalable and cost-effective route.Therefore,this review unravels the grievances between LMA,LiNO_(3)and carbonate electrolytes,and enables a comprehensive analysis of LMA stabilizing mechanism with LiNO_(3),dissolution principle of LiNO_(3) in carbonate electrolytes,and LiNO_(3) introduction strategies.This review converges attention on a point that the LiNO_(3)-introduction into commercial carbonate electrolytes is an imperious choice to realize practical LMBs with commercial 4 V layered cathode. | Kun Wang Wenbing Ni Liguang Wang Lu Gan Jing Zhao Zhengwei Wan Wei Jiang Waqar Ahmad Miaomiao Tian Min Ling Jun Chen Chengdu Liang | 2023 | Journal of Energy Chemistry2023，，2： | 1 |
| 2 | Surface glycosylation of polymeric membranes显示文摘Surface glycosylation of polymeric membranes has been inspired by the structure of natural biomem-branes. It refers to that glycosyl groups are introduced onto the membrane surface by various strate-gies, which combine the separation function of the membrane with the biological function of the sac-charides in one system. In this review, progress in the surface glycosylation of polymeric membranes is highlighted in two aspects, i.e. the glycosylation methods and the potential applications of the sur-face-glycosylated membranes. | DAI ZhengWei WAN LingShu XU ZhiKang | 2008 | Science China Chemistry2008，51，10： | 1 |
| 3 | Reduced irreversible capacities of graphene oxide-based anodes used for lithium ion batteries via alkali treatment显示文摘The large irreversible capacities of graphene oxide-based anodes hinder commercial applications of GO materials although the high specific capacity of it has been universally accepted. In this paper, GO was treated under alkaline condition and the composite consisting of the modified GO and graphite was used as anode for lithium ion batteries (LIBs), resulting in an improved initial coulombic efficiency. Electrochemical tests also showed that the modified GO/graphite electrode possessed 86.0% of initial coulombic efficiency, which was 15% higher than that of pristine GO/graphite electrode. The species and the content of functional groups were investigated via XPS, FTIR characterizations in detail, which certified that the ring-opening reaction of epoxides under alkaline condition could greatly reduce the irreversible capacity of GO/graphite anode, in addition, the reversible capacity was guaranteed at the same time. This modified GO/graphite electrodes in the LIBs exhibit superior rate capability and long cycle life. The uniqueness of this electrode lied in its chemical stability, which benefits from the transition of epoxide group and unstable functional groups removal. | Danhua Jiao Zhengwei Xie Qi Wan Meizhen Qu | 2019 | Journal of Energy Chemistry2019，28，10： | 0 |
| 4 | AD-16 Protects Against Hypoxic-Ischemic Brain Injury by Inhibiting Neuroinflammation显示文摘Neuroinflammation is a key contributor to the pathogenic cascades induced by hypoxic-ischemic(HI)insult in the neonatal brain.AD-16 is a novel anti-inflammatory compound,recently found to exert potent inhibition of the lipopolysaccharide-induced production of pro-inflammatory and neurotoxic mediators.In this study,we evaluated the effect of AD-16 on primary astrocytes and neurons under oxygen-glucose deprivation(OGD)in vitro and in mice with neonatal HI brain injury in vivo.We demonstrated that AD-16 protected against OGD-induced astrocytic and neuronal cell injury.Single dose post-treatment with AD-16(1 mg/kg)improved the neurobehavioral outcome and reduced the infarct volume with a therapeutic window of up to 6 h.Chronic administration reduced the mortality rate and preserved whole-brain morphology following neonatal HI.The in vitro and in vivo effects suggest that AD-16 offers promising therapeutic efficacy in attenuating the progression of HI brain injury and protecting against the associated mortality and morbidity. | Zhihua Huang Zhengwei Luo Andrea Ovcjak Jiangfan Wan Nai-hong Chen Wenhui Hu Hong-Shuo Sun Zhong-Ping Feng | 2022 | Neuroscience Bulletin2022，38，8： | 0 |
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