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3篇 您的检索式:作者名="Z.V.P.Murthy"
    题名 作者 年代 出处 被引量
1Application of nanofiltration to treat rare earth element(neodymium) containing water显示文摘The scope of present work was to study the feasibility of a commercial nanofiltration(NF) membrane to reject Nd(III) ions fromsynthetic aqueous solution.The permeates were analyzed using inductively coupled plasma-atomic emission spectrometry(ICP-AES) to findNd(III) concentration.Experimental results indicated that the Nd(III) rejection increased with increase in applied pressure and feed flow rate;and decreased with increase in feed concentration.Rejection of Nd(III) ions using NF membrane were widely influenced by solution pH dueto the charged nature of the membrane which changed with the variation in pH.The use of a surfactant(sodium dodecyl sulphate) in aqueoussolution resulted in its adsorption on the membrane surface,thereby changing membrane characteristics,and in turn influencing the rejection.The complexation step induced had also increased the rejection to a greater extent by forming [Nd-EDTA]-complex thereby increasing itsmolecular weight and thus increasing rejection.Z.V.P.Murthy Anshul Choudhary 2011Journal of Rare Earths2011,29,10:2
2Synthesis,characterization and application of PVA/ionic liquid mixed matrix membranes for pervaporation dehydration of isopropanol显示文摘In this study,polyvinyl alcohol(PVA)–ionic liquid(IL) membranes were prepared for the separation of isopropyl alcohol(IPA)–water azeotropic mixtures by pervaporation.PVA-IL composite membranes were prepared by simple solvent evaporation method using four ILs,viz.,1-n-butyl-3-methylimidazolium chloride(BMIMCl),1-hexyl-3-methylimidazolium chloride(HMIMCl),1-hexyl-3-methylimidazolium tetra fluoroborate(HMIMBF4) and 1-octyl-3-methylimidazolium chloride(OMIMCl).Three ILs were used to study the effect of alkyl chain on the pervaporation performance.The study had focused on the effect feed water concentration from 10%–40%and effect of feed temperature from 50–80°C.Physiochemical properties of all the membranes were studied using Fourier transform infrared spectroscopy(FTIR),scanning electron microscopy(SEM) and contact angle measurement.The Arrhenius activation energies for permeation were estimated to be in the range 4–12 kJ·mol-1 from the temperature dependent permeation values.Ganesh B.Thorat Smita Gupta Z.V.P.Murthy 2017Chinese Journal of Chemical Engineering2017,25,10:1
3Vanadium-Doped Magnesium Oxide Nanoparticles Formation in Presence of Ionic Liquids and Their Use in Photocatalytic Degradation of Methylene Blue显示文摘Magnesium oxide(MgO) is one of the metal oxides having unique properties with numerous potential industrial applications.In this study,MgO and vanadium-doped MgO nanoparticles were synthesized by sol–gel method in 1-butyl-3-methylimidazolium tetrafluoroborate [BMIM][BF_4] and 1-octyl-3-methylimidazolium tetrafluoroborate [OMIM][BF_4] ionic liquids.Vanadium-doped MgO nanoparticles exhibited nanosphere and nanorod morphologies with 40–80 nm in particle size,primarily due to the influence of ionic liquids as demonstrated by high-resolution scanning electron microscopy and transmission electron microscopy.Characteristics of nanoparticles were also studied by thermal gravimetric analysis,X-ray diffraction and energy-dispersive X-ray spectroscopy.Photodegradation ability of synthesized nanoparticles was evaluated for methylene blue(MB) in specially designed UV reactor.Photodegradation is found to be dependent on doping,and particle characteristics change due to the influence of ionic liquid.The ionic liquid-assisted vanadium-doped MgO nanoparticles showed good reusability under UV irradiation and MB degradation ability under visible light.Harshad R.Patil Z.V.P.Murthy 2016Acta Metallurgica Sinica(English Letters)2016,29,3:0
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