| 1 | Time-sensitivity mechanism of rock stress memory properties under tensile stress显示文摘In deep underground engineering,understanding of time-related stress memory properties is critical to evaluate the in situ stress conditions of a rock mass.In this study,the time-sensitivity mechanism of the rock stress memory properties under tensile stress was investigated.It was found that the material property(Poisson’s ratio)and crack angle were the controlling factors of the Kaiser effect(KE)under tensile stress.In particular,the time-sensitivity of the stress memory properties was closely related to the crack growth path.When the failure of the rock specimen was dominated by tensile microcracks and the crack development direction was deflected by up to 30°in the successive loading process,the stress memory capacity was likely to be time-independent for a sandstone specimen.The distribution of the Felicity ratio in a Brazilian test was more discrete than that in a three-point bending test It also showed that the changes in the crack path,rather than the time interval between successive loading cycles,led to inaccuracy of the detected KE.This study provides insights into stress memory-related issues under uniaxial or more complex stress conditions and thus facilitates development of methods for testing in situ mechanical behaviors of rocks with acoustic emission(AE)technology. | Yuxin Ban Xiang Fu Qiang Xie Jun Duan | 2020 | Journal of Rock Mechanics and Geotechnical Engineering2020，12，3： | 1 |
| 2 | A new insight into the promoting effects of transition metal phosphides in methanol electrooxidation显示文摘The construction of highly active catalysts for methanol oxidation reaction(MOR)is central to direct methanol fuel cells.Tremendous progress has been made in transition metal phosphides(TMPs)based catalysts.However,TMPs would be partially damaged and transformed into new substances(e.g.,Pt-M-P composite,where M represents a second transition metal)during Pt deposition process.This would pose a large obstacle to the cognition of the real promoting effects of TMPs in MOR.Herein,Co_(2)P co-catalysts(Pt-P/Co_(2)P@NPC,where NPC stands for N and P co-doped carbon)and Pt-Co-P composite catalysts(Pt-CoP/NPC)were controllably synthesized.Electrocatalysis tests show that the Pt-Co-P/NPC exhibits superior MOR activity as high as 1016 m A/mg_(Pt),significantly exceeding that of Pt-P/Co_(2)P@NPC(345 m A/mg_(Pt)).This result indicates that the promoting effect is ascribed primarily to the resultant Pt-Co-P composite,in sharply contrast to previous viewpoint that Co_(2)P itself improves the activity.Further mechanistic studies reveal that Pt-Co-P/NPC exhibits much stronger electron interaction and thus manifesting a remarkably weaker CO absorption than Pt-P/Co_(2)P@NPC and Pt/C.Moreover,Pt-Co-P is also more capable of producing oxygen-containing adsorbate and thus accelerating the removal of surface-bonded CO^(*),ultimately boosting the MOR performance. | Junjie Ding Shaojie Jing Changqing Yin Chaogang Ban Kaiwen Wang Xue Liu Youyu Duan Yuxin Zhang Guang Han Liyong Gan Jinsong Rao | 2023 | Chinese Chemical Letters2023，34，6： | 0 |
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