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2篇 您的检索式:作者名="XinQinGAO"
    题名 作者 年代 出处 被引量
1Novel Heptamethine 3H-Indocyanines and their Spectral Properties显示文摘Novel heptamethine 3H-indocyanine dyes are synthesized and embedded into a matrix of silica gel derived from tetraethoxysilicane. The photophysical properties of these near infrared dyes in various solvents and in SiO2 sol gel were investigated. The results show that the dyes containing cyclohexenylene bridge and N-(p-carboxy)benzyl groups have better photostability and longer absorption wavelength than those containing linear heptamethine bridge and/or N-(5- carboxy)pentanyl groups. The absorption maxima of these dyes are in reverse proportion to the polarity of the solvents. The microenvironment of the dyes in SiO2 sol-gel characters medium polarity (between methanol and DMF) according to the absorption maxima.LiQiuWANG XiaoJunPENG ErHuLU JingNanCUI XinQinGAO 2005Chinese Chemical Letters2005,16,4:1
2Synthesis and Spectral Properties of Novel Water-soluble Near-infrared Fluorescent Indocyanines显示文摘Two fluorescent pentamethine and a squarylium indocyanines containing at least one p-carboxybenzyl group on N atoms in the heterocyclic rings were synthesized. They had good water solubility and photostability. Their maximum absorption and maximum emission were 600-700 nm in water. When it was anchored onto nanostructured TiO2 electrode, compared with in water, the squaraine showed double absorption peaks (one blue shifted and another red shifted) and absorption intensity of the red shift peak increased with the increase of the time of irradiation. The intensity of the blue one decreased simultaneously. We proposed that the presence of two electronic charge forms of squaraine anchored on the TiO2 film might be the reason.LiQiuWANG XiaoJunPENG WeiBingZHANG FeiYIN JingNanCUI XinQinGAO 2005Chinese Chemical Letters2005,16,3:1
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