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| 1 | The role of magmatism in the thinning and breakup of the South China Sea continental margin显示文摘INTRODUCTION Magmatism plays a key role in the process of continental margin breakup and ocean formation.Even in the extremely magma-poor Iberia and Newfoundland margin,studies of field outcrops have shown that syn-rift magmatism had participated in rifting from a very early stage and contributed directly to the rifting process.The final transition from exhumed continental mantle to the ocean formation is also triggered by the accumulation and eruption of magma[1]. | Zhen Sun Jian Lin Ning Qiu Zhimin Jian PinXian Wang Xiong Pang Jinyun Zheng Benduo Zhu | 2019 | National Science Review2019，6，5： | 34 |
| 2 | Global monsoon in a geological perspective显示文摘季风现在仅仅被看作一个全球系统而非地区性的现象。为超过 300 年,季风被看作了巨大的陆地海微风,但是现在,卫星和常规观察支持因此把季风看作热带集中地区(ITCZ ) 并且,的季节的移植的表明的一个其他的假设,全球规模的一个气候系统。作为一个低纬度的气候系统,季风在所有大陆上存在但是南极洲,并且通过所有地质的历史至少自从 Phenorozoic。时间为在空间和时间的季风变化的系统的研究是成熟的。是由地质的记录证实了,全球季风被威尔森周期在构造时间规模上控制(10 6 10 8 一) 。一“大大陆”生产“大季风”,并且它的故障导致季风紧张变弱。在 10 4-105 的时间规模上一,全球季风显示 ∼20 ka 的岁差的周期和 100-ka, 和 400-ka 的怪癖周期,即轨道的周期。在 10 3 的时间规模上一 and 在下面,全球季风紧张被太阳的周期和另外的因素调制。全球季风的 cyclicity 象为人的社会的环境变化一样在地球表面系统代表为变化负责的基本因素之一。 400-ka 全球季风的长怪癖周期被把到地球系统的“心跳”,并且全球季风的领前周期以前为在 ∼4000 年的几种亚洲、非洲的古老的文化的倒塌负责,而太阳的周期 大约1000 年以前导致了幻境文明的遗赠。因此, paleoclimatology 应该在冰帽子变化集中的高纬度的过程集中于不仅,而且在象季风那样的低纬度的过程上,因为后者与冻结成冰相比的地质的历史上是更普通的。 | WANG PinXian | 2009 | Chinese Science Bulletin2009，54，7： | 25 |
| 3 | The South China Sea is not a mini-Atlantic: plate-edge rifting vs intra-plate rifting显示文摘The South China Sea,as‘a non-volcanic passive margin basin’in the Pacific,has often been considered as a small-scale analogue of the Atlantic.The recent ocean drilling in the northern South China Sea margin found,however,that the Iberian model of non-volcanic rifted margin from the Atlantic does not apply to the South China Sea.In this paper,we review a variety of rifted basins and propose to discriminate two types of rifting basins:plate-edge type such as the South China Sea and intra-plate type like the Atlantic.They not only differ from each other in structure,formation process,lifespan and geographic size,but also occur at different stages of the Wilson cycle.The intra-plate rifting occurred in the Mesozoic and gave rise to large oceans,whereas the plate-edge rifting took place mainly in the mid-Cenozoic,with three-quarters of the basins concentrated in the Western Pacific.As a member of the Western Pacific system of marginal seas,the South China Sea should be studied not in isolation on its origin and evolution,but in a systematic context to include also its neighboring counterparts. | Pinxian Wang Chi-Yue Huang Jian Lin Zhimin Jian Zhen Sun Minghui Zhao | 2019 | National Science Review2019，6，5： | 24 |
| 4 | Long-term cycles in the carbon reservoir of the Quaternary ocean: a perspective from the South China Sea显示文摘In recent years,long-term,high-resolution records from the deep sea and ice-cores have ofered new research opportunities for Quaternary science.Paleoclimate studies are no longer restricted to individual glacial cycles,but extend to long-term(≥105 yr)processes across those cycles.Ocean Drilling Program Leg 184 of the South China Sea in 1999 uncovered well-preserved sediment sections,in which three long-term cycles in Pleistocene carbon isotope(δ13C)sequence have been found and demonstrated to be common in the global ocean.Subsequent discoveries conirm the existence of long-term processes of 105yr in both the hydrologic(ice-sheet changes)and carbon(biogeochemical changes)cycles,posing the question whether the two processes are related.he present review shows that the long-eccentricity cycles prevail throughout theδ13C and other biogeochemical records in geologic history,and 400-kyr cycles in the oceanicδ13C sequence before the Quaternary can be hypothetically explained by changes in ratio between particulate and dissolved organic carbon(POC/DOC)in the ocean,depending on the monsoon-controlled nutrient supply.his is a‘DOC hypothesis’.However,ocean restructuring at 1.6 Ma marked by the isolation of a sluggish abyss under the Southern Ocean has obscured the long-eccentricity 400-kyr signal in oceanicδ13C.he last million-year period has experienced two major changes in the climate regime,namely the mid-Pleistocene transition(MPT)centered at 0.9 Ma and the mid-Brunhes event(MBE)around 0.4 Ma.he MPT and MBE were preluded byδ13C maxima-III(δ13Cmax-III)~1.0 Ma andδ13Cmax-II~0.5 Ma,respectively.Together with similar hydroclimatic phenomena over corresponding glacial cycles,the two groups of hydrologic and biogeochemical events appear to have been driven largely by oceanographic changes in the Southern Ocean.herefore,we interpret that the long-term biogeochemical processes originating from the Southern Ocean must have played a crucial role in Quaternary ice-sheet waxing and waning. | PinXian Wang QianYu Li Jun Tian ZhiMin Jian ChuanLian Liu Li Li WenTao Ma | 2014 | National Science Review2014，1，1： | 23 |
| 5 | Shifts of the Kuroshio axis over the last 20 000 years显示文摘Core 255 from the southern Okinawa Trough was selected to monitor the shift of the Kuroshio axis over the last 20 000 years. During the last glacial maximum the Kuroshio axis had ever shifted outside the Okinawa Trough. It entered the Okinawa Trough again at about 6 500 a BP, leading to abrupt increase of sedimentation rate, distinctly coarser sediment and remarkably increased abundance of foraminiferal indicators of the Kuroshio in the core. But, during about 4 000-3 000 a BP the abundance of the Kuroshio indicator Pulleniatina obliquiloculata sharply decreased again, indicating that the Kuroshio axis had ever shifted easterly for a short period or the Kuroshio was weakened and that moment. | Jian Zhimin Y. Saito Wang Pinxian Li Baohua Chen Ronghua | 1998 | Chinese Science Bulletin1998，43，12： | 20 |
| 6 | Tracing the life history of a marginal sea——On “The South China Sea Deep” Research Program显示文摘The Major Research Program 'Deep Sea Processes and Evolution of the South China Sea', or 'The South China Sea Deep', launched in January 2011 by the National Natural Science Foundation of China, is the first large-scale basic-research program in ocean science in the country aiming to reconstruct the life history of a marginal sea. The overall scientific objective of the program is to dissect this typical marginal sea by studying its history of evolution and its modern processes, including the following three major components:(1) Development of the deep basin:utilizing new techniques to re-measure magnetic anomaly lineations, to explore the deep tectonic features, to drill the oceanic crust, and to study volcanic seamount chains; (2) deep-water sediments: observing the modern processes to reveal the patterns of deep-water circulations and sedimentation, analyzing deep-sea sediments to recognize paleoceanographic response to basin evolution, and subsequently to bridge the modern and paleo-studies of the deep-sea processes; and (3) biogeochemical processes:using a variety of techniques including deploying submarine observation and deep-water diving device to investigate the distribution patterns and environmental impacts of deepwater seepages and sub-bottom circulation, and to reveal the role of microbes in deep-sea carbon cycling. As compared with the open ocean and other marginal seas, the South China Sea enjoys many more advantages as a marine basin for reconstructing the life history. Meanwhile, the South China Sea Deep Program provides unique opportunities in studying the evolution and variations of the sea-land interactions between the Pacific and Asia. | WANG PinXian | 2012 | Chinese Science Bulletin2012，57，24： | 18 |
| 7 | Exploring cyclic changes of the ocean carbon reservoir显示文摘A 5-Ma record from ODP Site 1143 has re-vealed the long-term cycles of 400—500 ka in the carbon isotope variations. The periodicity is correlatable all over the global ocean and hence indicative of low-frequency changes in the ocean carbon reservoir. As the same periodicity is also found in carbonate and eolian dust records in the tropical ocean, it may have been caused by such low-latitude proc-esses like monsoon. According to the Quaternary records from Site 1143 and elsewhere, major ice-sheet expansion and major transition in glacial cyclicity (such as the Mid-Brunhes Event and the Mid-Pleistocene Revolution ) were all pre-ceded by reorganization in the ocean carbon reservoir ex-pressed as an episode of carbon isotope maximum (d 13Cmax), implying the role of carbon cycling in modulating the glacial periodicity. The Quaternary glacial cycles, therefore, should no more be ascribed to the physical response to insolation changes at the Northern Hemisphere high latitudes alone; rather, they have been driven by the 揹ouble forcing? a combination of processes at both high and low latitudes, and of processes in both physical (ice-sheet) and biogeochemical (carbon cycling) realms. As the Earth is now passing through a new carbon isotope maximum, it is of vital impor-tance to understand the cyclic variations in the ocean carbon reservoir and its climate impact. The Pre-Quaternary varia-tions in carbon and oxygen isotopes are characterized by their co-variations at the 400-ka eccentricity band, but the response of d 13C and d 18O to orbital forcing in the Quater-nary became diverged with the growth of the Arctic ice-sheet. The present paper is the second summary report of ODP Leg 184 to the South China Sea. | WANG Pinxian, TIAN Jun, CHENG Xinrong, LIU Quanlian & XU Jian Key Laboratory of Marine Geology, Ministry of Education, Tongji Uni-versity, Shanghai 200092, China | 2003 | Chinese Science Bulletin2003，48，23： | 17 |
| 8 | Sea surface temperature and terrestrial biomarker records of the last 260 ka of core MD05-2904 from the northern South China Sea显示文摘This paper reports high-resolution biomarker records of the last 260 ka for core MD05-2904 from the northern South China Sea (SCS). The sea surface temperature (SST) record using the U k3’7 index re-veals a minimum of 21.5℃ (MIS 2) and a maximum of 28.3℃ (MIS 5.5), for a temperature difference of almost 7℃, and provides the longest high-resolution U k3’7 SST record in northern SCS. The content of odd-number long chain n-alkanes and several n-alkanes indexes such as the CPI, ACL and the C31/C27 ratio, all reveal generally higher values during the glacials and lower values during the interglacials. Terrestrial input as indicated by n-alkane content was mostly controlled by sea-level changes: During the glacials, lower sea-level exposed the continental shelf to enable rivers to transport more terrestrial materials to the slope; and the situation reverses during the interglacials. The n-alkane indexes changes reveal more n-alkanes from contemporary vegetation during glacials as a result of the prox-imity of the core site to the source region, while the increases in ACL and C31/C27 ratio during glacials indicate a change to more grassy vegetation. However, the highest values for CPI, ACL and the C31/C27 ratio all occurred during late MIS 3, and it was suggested that this period was characterized by a strong summer monsoon-dominated humid climate which resulted in a denser vegetation for the exposed continental shelf region. | HE Juan ZHAO MeiXun LI Li WANG PinXian GE HuangMin | 2008 | Chinese Science Bulletin2008，53，15： | 17 |
| 9 | Potential role of strike-slip faults in opening up the South China Sea显示文摘Radiometric dates of key rock units indicate that a remnant Late Mesozoic ocean of the Huatung Basin is still preserved today east of the South China Sea(SCS).We integrate regional geology with a Cretaceous oceanic basement in the vicinity of the Huatung Basin to reconstruct the Huatung Plate east of the Eurasian continent.Results of geophysical investigations,four expeditions of deep-sea drilling and a renaissance of regional geology allow us to propose a hypothesis that the mechanism responsible for the SCS opening was raised from strike-slip fault on the east.The hypothesis suggests that the SCS opening could highly relate to the strike-slip faults inherited from Late Mesozoic structures onshore–offshore the SE Cathaysia Block to develop rhombic-shaped extensional basins en echelon on the thinned Eurasian continental crust in the Early Cenozoic.It was followed by sinistral strike-slip movements along the boundary between the Eurasian Plate and the Huatung Plate driven by oblique subduction of the Huatung Plate to the northwest coupled with slab-pull force by southward subduction of the Proto-SCS to open up the triangle-shaped oceanic East Sub-basin in the Early Oligocene(33/34 Ma).The spreading ridge then propagated southwestward in the step-over segment between the Zhongnan-Lile and the Red River strike-slip fault systems to open the triangle-shaped oceanic Southwest Sub-basin by 23 Ma.The plate boundary fault was subsequently converted into the Manila Trench when the Eocene Sierra Madre arc of the Huatung Plate had moved from the south to its present latitude by the Middle Miocene. | Chi-Yue Huang Pinxian Wang Mengming Yu Chen-Feng You Char-Shine Liu Xixi Zhao Lei Shao Guangfa Zhong Graciano P.Yumul Jr | 2019 | National Science Review2019，6，5： | 16 |
| 10 | Sediment mass and distribution in the South China Sea since the Oligocene显示文摘The sediment macro-distribution patterns and their evolutionary characteristics in the South China Sea (SCS) are discussed based on a quantification of the sediment mass from the beginning of seafloor spreading in the Oligocene to the Present. Above the pre-Oligocene base, the total sediment mass for the whole SCS is estimated to be 1.44×1016 t, with the highest average accumulation rate of ~22 g·cm-2·ka-1 in the Oligocene. Having no large abyssal fans but fast accumulation in sedimentary basins on the continental shelf and slope, the SCS shows quite different sedimentary characters not only from the open ocean but also from small backarc basins along the marginal West Pacific, apparently controlled by the coupling between local tectonics and global climate changes. | HUANG Wei WANG Pinxian | 2006 | Science China Earth Sciences2006，49，11： | 11 |
| 11 | Paleoproductivity records for the past 30 ka in the southern Nansha area, the South China Sea显示文摘This note presents productivity variations for the past 30 ka in the southern Nansha area, the South China Sea, from the gravity core 17962 (7°11 ′N, 112°5′E, core length: 8 m, water depth: 1 968 m). Estimated surface productivity demonstrates that at the last glacial maximum the productivity was about 1.6 times as much as that in the Holocene, and the change may be ascribed to an increase of terrestrial nutrients as sea level lowered in the glacial time. | Dianyong Fang Zhimin Jian Pinxian Wang | 2000 | Chinese Science Bulletin2000，45，13： | 10 |
| 12 | Changes in sea surface temperature in western South China Sea over the past 450 ka显示文摘Sea surface temperature over the past 450 ka was obtained by the unsaturation of molecular fossil-long chain alkenone with a resolution of about 1 ka from the western South China Sea. This is the longest temperature profile in the South China Sea at such high resolution. The U3k7′-SST results revealed similar glacial-interglacial cycles as the δ18O profile of planktonic foraminifera, with SST variability of 23―25.5℃ for glacial and 25―28℃ for interglacial periods. The highest SST (28.4℃) was recorded at MIS5.5 and lowest SST (22.6℃) during MIS2. The SST record preceded the planktonic foraminiferal δ18O on five glacial-interglacial transitions. Comparison of temperature records from the Southern and Northern Hemispheres indicated a more Southern Hemisphere-like pattern for the temperature variation in the SCS. Strong precession and semiprecession signals in the spectra of our SST record manifest the tropical phenomena. | LI Li WANG Hui LI JianRu ZHAO MeiXun WANG PinXian | 2009 | Chinese Science Bulletin2009，54，18： | 8 |
| 13 | Responses of foraminiferal isotopic variations at ODP Site 1143 in the southern South China Sea to orbital forcing显示文摘The foraminiferal δ18O and δ13C records for the past 5 Ma at ODP Site 1143 reveal the linear responses of the Plio-Pleistocene climatic changes in the southern South China Sea to orbital forcing at the obliquity and precession bands. The phase of the δ18O variations with the orbital forcing is opposite to that of the δ13C, which may be caused by the frequent El Nino events from the equatorial Pacific. The amplification of the Northern Hemisphere Ice Sheet at ~3.3 Ma probably affected the development of the 100-ka climatic cycles. Its further spreading may spur the 100-ka climatic cycle to become the dominant cycle in the late Pleistocene. The 'MidPleistocene Transition' event has localized influence on the isotopic variations in the southern South China Sea. The foraminiferal δ13C records for the past 5 Ma at Site 1143 are highly coherent with the orbital forcing at the long eccentricity band, and lead the δ18O records at the shorter eccentricity band, highlighting the importance of the carbon cycle in the global climate change. | TIAN Jun WANG Pinxian CHENG Xinrong | 2004 | Science China Earth Sciences2004，47，10： | 6 |
| 14 | Late Quaternary upper-water column structure in upwelling areas of the South China Sea显示文摘Based on a quantitative analysis of planktonic foraminifera in two gravity cores (17928 and 17954), the history of the upper-water structure of the eastern and western slopes of the South China Sea (SCS) over the last 220 Ka was reconstructed using the transfer function technique. Our results show that lower sea surface temperature (SST) and shallower depth of thermocline (DOT) exist at Core 17928, off Luzon, in the glacial periods; on the contrary, the same situation turned up in the interglacial at Core 17954, off Vietnam. These changes of the upper-water column structure in the two areas are induced by coastal up-welling, which in turn is driven by monsoons, namely, winter monsoon leads to upwelling at the eastern slope, and summer monsoon gives birth to upwelling on the western slope. Moreover, the intensity of upwellings is also closely related to the evolution of the East Asian monsoon. Therefore, we assume that the changes of the upwelling in the two sites indicate strengthenning of winter and | Huang Baoqi Jian Zhimin Cheng Xinrong Wang Pinxian | 2001 | Chinese Science Bulletin2001，46，20： | 6 |
| 15 | Coral reef ecosystems in the South China Sea as a source of atmospheric CO_2 in summer显示文摘由空至海的 CO2 的领域大小在华南海的三个珊瑚礁石区域交换(即 Nansha 岛的 Yongshu 礁石环礁,南部的华南海(SCS ) ;Xisha 岛的 Yongxing 岛,北方中央的 SCS;并且在海南岛的 Sanya 的 Luhuitou Fringing 礁石,北 SCS ) 在 2008 和 2009 的夏天期间揭示了那 CO2 (pCO2 ) 的部分压力显示出的空气和表面海水常规日报周期。最小的价值在早上发生在晚上和最大的价值。在每三个学习区域的空气 pCO2 出现了小日报变化,当时大日报变化在海水 pCO2 被观察。日报海水 pCO2 的变化振幅是 70 摩尔摩尔? 1 在 Yongshu 礁石泻湖, 420619 摩尔摩尔? 1 在 Yongxing 岛礁石公寓,和 264579 摩尔摩尔上? 1 在 Luhuitou Fringing 礁石的礁石公寓上,并且 324492 摩尔摩尔? 1 在就在这 fringing 礁石外面的一个邻近的区域。关于空间关系,在越过华南海的由空至海的 CO2 流动有大差别(例如 0.4 mmol CO2 m ? 2 d ? 1 在 Yongshu 礁石, 4.7 mmol CO2 m ? 2 d ? 1 在 Yongxing 岛,并且 9.8 mmol CO2 m ? 2 d ? 1 在 Luhuitou Fringing 礁石)。然而,这些积极的值建议 SCS 的珊瑚礁石生态系统可以是到空气的 CO2 的网络来源。另外的分析显示了那日报在浅水礁石公寓的表面海水 pCO2 的变化主要被生物新陈代谢的过程控制,当那些被两个生物新陈代谢和水动力学因素更深的水泻湖和外部礁石区域调整时。不同于开的海洋,无机的新陈代谢在在珊瑚礁石生态系统影响海水 pCO2 变化起一个重要作用。 | YAN HongQiang YU KeFu SHI Qi TAN YeHui ZHANG HuiLing ZHAO MeiXia LI Shu CHEN TianRan HUANG LingYing WANG PinXian | 2011 | Chinese Science Bulletin2011，56，7： | 6 |
| 16 | Exploring the deep South China Sea: Retrospects and prospects显示文摘Rapid developments of deep-sea researches in China over the past 20 years have promoted the South China Sea(SCS) into the international deep-sea frontiers. The 'three deep technologies', namely scientific drilling, long-term seafloor observation and deep submersible vehicles implemented successively in SCS studies helped to achieve a number of scientific breakthroughs. Over the 20 years, five international ocean drilling expeditions to the SCS recovered nearly 10 km of sediment cores from sites at 3–4 km water depths, and drilling into the magmatic basement at 6 sites shed light on the genesis of the SCS basin. Coupled with other deep-sea short core sediments from the SCS, these records demonstrate evidence that water and carbon cycling in the low latitude regions can directly respond to the orbital forcing, and subsequently nurture a new concept of lowlatitude forcing of climate changes, which challenges the classical wisdom of the overwhelming role played by the Arctic icesheet in climate changes. The exploration in the continent-ocean transition zone also reveals a number of specific features that characterize the SCS as a marginal basin formed at the subduction zone in the Western Pacific. The features include active magmatism and rapid rupture of lithosphere through the basin formation process, and imply that 'the SCS is not a mini-Atlantic'as they can be distinguished as 'plate-edge rifting' and 'inner-plate rifting' respectively, thus challenging the universality of the Atlantic model for passive margins. Many more discoveries can be assembled from long-term mooring observations and deep diving cruises in the deep SCS, such as the cyclonic nature of the deep-water circulation, deep-water sediment transport by contour currents and turbidites, manganese nodules, extinct hydrothermal vents, and cold-water coral forests. In addition,prominent progress achieved in microbiology and biogeochemistry includes the microbial carbon pump and the coupling of carbon and nitrogen cycles. Clearly, most achievements of the deep-sea explorations in the SCS over the last 20 years have always been of international scale and impact. However, the contributions from Chinese scientists are most prominent, particularly with the research activities undertaken from the major program 'Deep Sea Processes and Evolution of the South China Sea(2011–2018)' supported by the National Natural Science Foundation of China. | Pinxian WANG Zhimin JIAN | 2019 | Science China Earth Sciences2019，62，10： | 5 |
| 17 | Calcium carbonate pump during Quaternary glacial cycles in the South China Sea显示文摘The preservation and dissolution of calcium carbonate (namely calcium carbonate pump) controls the pH of seawater in global oceans by its buffer effect, and in turn plays a significant role in global changes in atmospheric CO2 concentration. The results from measured carbonate con-tents over the past 2 Ma at ODP Site 1143 in the South China Sea provide high-resolution records to explore the process of the calcium carbonate pump during Quaternary glacial cy-cles. The results indicate statistically that the highest car-bonate accumulation rate leads the lightest d 18O by about 3.6 ka at transitions from glacials to interglacials, and that the strongest carbonate dissolution lags the lightest d 18O by about 5.6 ka at transitions from interglacials to glacials. The calcium carbonate pump releases CO2 to the atmosphere at the glacial-interglacial transitions, but transports atmos-pheric CO2 to deep sea at the interglacial-glacial transitions. The adjustable function of the calcium carbonate pump for the deep-sea 23CO- concentration directly controls parts of global changes in atmospheric CO2, and contributes the global carbon cycle system during the Quaternary. | LIU Zhifei, XU Jian, TIAN Jun & WANG Pinxian Laboratory of Marine Geology, Tongji University, Shanghai 200092, China | 2003 | Chinese Science Bulletin2003，48，17： | 5 |
| 18 | Bimetallic Nickel Cobalt Sulfide as E cient Electrocatalyst for Zn–Air Battery and Water Splitting显示文摘The development of e cient earth-abundant electrocatalysts for oxygen reduction, oxygen evolution, and hydrogen evolution reactions(ORR, OER, and HER) is important for future energy conversion and energy storage devices, for which both rechargeable Zn–air batteries and water splitting have raised great expectations. Herein, we report a single-phase bimetallic nickel cobalt sulfide((Ni,Co)S_2) as an e cient electrocatalyst for both OER and ORR. Owing to the synergistic combination of Ni and Co, the(Ni,Co)S_2 exhibits superior electrocatalytic performance for ORR, OER, and HER in an alkaline electrolyte, and the first principle calculation results indicate that the reaction of an adsorbed O atom with a H_2O molecule to form a *OOH is the potential limiting step in the OER. Importantly, it could be utilized as an advanced air electrode material in Zn–air batteries, which shows an enhanced charge–discharge performance(charging voltage of 1.71 V and discharge voltage of 1.26 V at 2 mA cm^(-2)), large specific capacity(842 mAh g_(Zn)^(-1) at 5 mA cm^(-2)), and excellent cycling stability(480 h). Interestingly, the(Ni,Co)S_2-based Zn–air battery can e ciently power an electrochemical water-splitting unit with(Ni,Co)S_2 serving as both the electrodes. This reveals that the prepared(Ni,Co)S_2 has promising applications in future energy conversion and energy storage devices. | Jingyan Zhang Xiaowan Bai Tongtong Wang Wen Xiao Pinxian Xi Jinlan Wang Daqiang Gao John Wang | 2019 | Nano-Micro Letters2019，11，1： | 4 |
| 19 | Transition-metal-doped NiSe2 nanosheets towards efficient hydrogen evolution reactions显示文摘Transition metal diselenides are promising electrocatalysts for hydrogenevolution and therefore different approaches have been proposed to enhancetheir catalytic activity. Herein, we describe systematic studies of the dependenceof transition-metal doping on the catalytic activity of NiSe2 by first principlescalculations, where Fe is demonstrated to be the best candidate element to tunethe electrocatalytic activity of NiSe2 with lower AGH. values and increasedelectrical conductivity. To provide further experimental evidence, Fe-dopedNiSe2 porous nanosheets grown on carbon cloth are successfully developed.These nanosheets show significantly improved efficiency for hydrogen evolutionreactions compared to their un-doped counterpart. The optimized Ni0.sFe0.2Se2electrocatalyst gives rise to a current density of 10 mA.cm-2 at a very lowoverpotential of 64 mV with outstanding long-term stability. The present strategyof doping NiSe2-based electrocatalysts with transition metals paves a newpathway for the design and synthesis of electrocatalysts for large-scale electro-chemical energy applications. | Tongtong Wang Daqiang Gao Wen Xiao Pinxian Xi Desheng Xue John Wang | 2018 | Nano Research2018，11，11： | 4 |
| 20 | Benthic foraminiferal fauna turnover at 2.1 Ma in the northern South China Sea显示文摘Quantitative analysis of benthic foraminifera from ODP Site 1146 in the northern South China Sea (SCS) shows that abundance of Bulimina alazanensis, sometimes up to about 90%, decreased gradually since 3.2 Ma, especially at 2.1 Ma. Abundance of other benthic foraminiferal species, Globobulimina sub-globosa and Cibicidoides wuellerstorfi, increased after 2.1 Ma. Comparison with changes in oxygen and carbon isotopes of planktonic and benthic foraminifera shows that high abundance values of B. alazanensis corresponded with lower values of oxygen isotope, but for carbon isotope, high values of the species were consistent with heavier carbon isotope of benthic foraminifera and lighter carbon isotope of planktonic foraminifera, respectively, and vice versa. Considering factors such as uplift of Bashi Strait, expansion of the North Hemisphere Glaciation, strengthening of East Asian winter mon-soon and variations in oxygen and carbon isotope of foraminifera, changes of B. alazanensis in ODP Site 1146 suggest that the source of deep water masses of the northern South China Sea changed from the warm Pacific deep water with high oxygen content to Pacific Intermediate water with low oxygen content at 2.1 Ma. In addition, the strengthened East Asian winter monsoon resulted in increased pri-mary productivity, high nutrient and suboxic bottom water. Variations in species of B. alazanensis seemed to be unable to tolerate environmental stress induced by deep water masses and productivity changes. | HUANG BaoQi JIAN ZhiMin WANG PinXian | 2007 | Chinese Science Bulletin2007，52，6： | 4 |
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