维普中文期刊产品整合服务
2篇 您的检索式:作者名="Tim Senden"
    题名 作者 年代 出处 被引量
1Quenching of the red Mn^(4+) luminescence in Mn^(4+)-doped fluoride LED phosphors显示文摘Red-emitting Mn^(4+)-doped fluorides are a promising class of materials to improve the color rendering and luminous efficacy of white light-emitting diodes(w-LEDs).For w-LEDs,the luminescence quenching temperature is very important,but surprisingly no systematic research has been conducted to understand the mechanism for thermal quenching in Mn^(4+)-doped fluorides.Furthermore,concentration quenching of the Mn^(4+) luminescence can be an issue but detailed investigations are lacking.In this work,we study thermal quenching and concentration quenching in Mn^(4+)-doped fluorides by measuring luminescence spectra and decay curves of K2TiF6:Mn^(4+) between 4 and 600 K and for Mn^(4+) concentrations from 0.01%to 15.7%.Temperature-dependent measurements on K2TiF6:Mn^(4+) and other Mn^(4+)-doped phosphors show that quenching occurs through thermally activated crossover between the ^(4)T_(2) excited state and ^(4)A_(2) ground state.The quenching temperature can be optimized by designing host lattices in which Mn^(4+) has a high 4T2 state energy.Concentration-dependent studies reveal that concentration quenching effects are limited in K_(2)TiF_(6):Mn^(4+)up to 5%Mn^(4+).This is important,as high Mn^(4+)concentrations are required for sufficient absorption of blue LED light in the parity-forbidden Mn^(4+)d–d transitions.At even higher Mn^(4+) concentrations(>10%),the quantum efficiency decreases,mostly due to direct energy transfer to quenching sites(defects and impurity ions).Optimization of the synthesis to reduce quenchers is crucial for developing more efficient highly absorbing Mn^(4+) phosphors.The present systematic study provides detailed insights into temperature and concentration quenching of Mn^(4+) emission and can be used to realize superior narrow-band red Mn^(4+) phosphors for w-LEDs.Tim Senden Relinde J.A.van Dijk-Moes Andries Meijerink 2018Light(Science & Applications)2018,7,1:13
2Probing the archie’s exponent under variable saturation conditions显示文摘Munish Kumar Tim J Senden Adrian P Sheppard 2011Petrophysics2011,52,2:1
返回顶部 每页显示:
共1页 首页 上一页 第1页 下一页 末页 /1 跳转

网站首页 | 关于我们 | 联系我们 | 产品服务 | 客服中心 | 广告服务 | 版权声明 | 网站联盟 | 友情链接 | 售卡网点

版权所有© 渝B2-20050021-1 渝公网安备 50019002500403号 违法和不良信息举报中心

互联网出版许可证 新出网证(渝)字10号 全国400电话 - 免长途话费