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| 1 | 汽车尾气中NO_X再燃烧过程的动力学显示文摘为了阐明汽车尾气中 NOX再燃烧的动力学进程 ,以甲醛和 NO2 作为探针分子 ,通过 FT-IR跟踪研究了反应体系中所产生的 HCO自由基与 NO2 反应的动力学。结果表明 ,反应的主要产物中包括 CO、CO2 、NO、HONO和 H2 O等分子 ,经长时间的反应 ,当体系中的 NO2 基本耗尽时 ,才有少量的 N2 O生成。这些产物分子分别是在几个不同途径的连串反应中形成的。从体系中 CO和 CO2 的生成量 ,测定了主反应的歧化反应速率比 ,并对相应的动力学机理进行了讨论。 | 陈平 郑小明 Meyer S Temps F | 2000 | 环境污染与防治2000，22，4： | 2 |
| 2 | FTIR研究HCO自由基与NO_2反应的动力学显示文摘In this work,mixtures of HCHO-NO2-Ar were photolyzed under stationary conditions using a high-pressure Hg lamp atλ =300~ 340 nm and HCHO as a probe molecule.The HCO radicals were generated in the reaction system,and the kinetics of the reaction between HCO radicals and NO2 was investigated at room temperature in Ar gas at 5.7× 104 Pa pressure by FTIR spectroscopy.The main reaction products including CO,CO2,NO,HONO and H2O were detected.A small amount of N2O was found only at longer reaction times when NO2 consumption was complete.These product molecules were formed in consecutive reactions from several reaction channels.From the yields of CO and CO2,branching ratios were determined and their kinetic mec hanism was discussed. | 陈平 郑小明 Meyer S Temps F | 2000 | 物理化学学报2000，16，11： | 1 |
| 3 | A fungal metabolite mediates degradation of non-phenolic lignin structures and syn- thetic lignin by laccase显示文摘 | EGGERT C TEMP U DEAN J F D | 1996 | FEBS Letters1996，391，12： | 1 |
| 4 | Enhanced photoswitching and ultrafast dynamics in structurally modified pho- tochromic fulgides显示文摘 | Renth F Siewertsen R Temp F | 2013 | International Reviews in Physical Chemistry2013，32，1： | 1 |
| 5 | A direct study of the reaction of ethylene radicals with hydrogen and deuterium atoms显示文摘 | Bonehead T Temps F Wagner H G | 1987 | J Phys Chem1987，91，： | 1 |
| 6 | A fungal metabolite mediates degradation of non-phenolic lignin structures and synthetic lignin by laccase显示文摘 | Eggert C Temp U Dean J F D | 1996 | FEBS Letter1996，391，： | 1 |
| 7 | Base sequence and higher-order structure induce the complex excited-state dynamics in DNA显示文摘 | Schwalb N K Temps F | | 0，，5899： | 1 |
| 8 | Base sequence and higher-order strueture induce the complex excited-state dynamics in DNA显示文摘 | Sehwalb NK Temps F | 2008 | Science2008，322，： | 1 |
| 9 | Laccase-mediated formation of the phenoxazinone derivative, einnabarinic acid显示文摘 | EGGERT C TEMP U DEAN J F D | 1995 | FEBS Letters1995，376，3： | 1 |
| 10 | Rotational spectrum, structure and internal dynamics of the pyrrole ammonia complex显示文摘 | Rensing C Milder H Temps F | 2008 | J Mol Spectrosc2008，251，： | 1 |
| 11 | A fungal metabolite mediates degradation of non-phenolic lignin structures and synthetic lignin by lacease 显示文摘 | EGGERT C TEMP U DEAN J F D | 1996 | FEBS Letters1996，391，12： | 1 |
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