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| 1 | CAS FGOALS-f3-L Model Datasets for CMIP6 GMMIP Tier-1 and Tier-3 Experiments显示文摘The Chinese Academy of Sciences(CAS)Flexible Global Ocean Atmosphere Land System(FGOALS-f3-L)model datasets prepared for the sixth phase of the Coupled Model Intercomparison Project(CMIP6)Global Monsoons Model Intercomparison Project(GMMIP)Tier-1 and Tier-3 experiments are introduced in this paper,and the model descriptions,experimental design and model outputs are demonstrated.There are three simulations in Tier-1,with different initial states,and five simulations in Tier-3,with different topographies or surface thermal status.Specifically,Tier-3 contains four orographic perturbation experiments that remove the Tibetan Iranian Plateau,East African and Arabian Peninsula highlands,Sierra Madre,and Andes,and one thermal perturbation experiment that removes the surface sensible heating over the Tibetan Iranian Plateau and surrounding regions at altitudes above 500 m.These datasets will contribute to CMIP6’s value as a benchmark to evaluate the importance of long-term and short-term trends of the sea surface temperature in monsoon circulations and precipitation,and to a better understanding of the orographic impact on the global monsoon system over highlands. | Bian HE Yimin LIU Guoxiong WU Qing BAO Tianjun ZHOU Xiaofei WU Lei WANG Jiandong LI Xiaocong WANG Jinxiao LI Wenting HU Xiaoqi ZHANG Chen SHENG and Yiqiong TANG | 2020 | Advances in Atmospheric Sciences2020，37，1： | 4 |
| 2 | Introduction to the Regional Coupled Model WRF4-LICOM: Performance and Model Intercomparison over the Western North Pacific显示文摘Regional coupled modeling is one of the frontiers of regional climate modeling,but intercomparison has not been well coordinated.In this study,a community regional climate model,WRF4,with a resolution of 15 km,was coupled with a high-resolution(0.1°)North Pacific Ocean model(LICOM_np).The performance of the regional coupled model,WRF4_LICOM,was compared to that of another regional coupled model,RegCM4_LICOM,which was a coupling of version 4 of the Regional Climate Model(RegCM4)with LICOM_np.The analysis focused on the 2005 western North Pacific summer monsoon rainfall.The results showed that the regional coupled models with either RegCM4 or WRF4 as their atmospheric model component simulated the broad features over the WNP reasonably well.Quantitative intercomparison of the regional coupled simulations exhibited different biases for different climate variables.RegCM4_LICOM exhibited smaller biases in its simulation of the averaged June–July–August SST and rainfall,while WRF4_LICOM better captured the tropical cyclone(TC)intensity,the percentage contributions of rainfall induced by TCs to the total rainfall,and the diurnal cycle of rainfall and stratiform percentages,especially over land areas.The different behaviors in rainfall simulated by the two models were partly ascribed to the behaviors in the simulated western North Pacific subtropical high(WNPSH).The stronger(weaker)WNPSH in WRF4_LICOM(RegCM4_LICOM)was driven by overestimated(underestimated)diabatic heating,which peaked at approximately 450 hPa over the region around the Philippines in association with different condensation–radiation processes.Coupling of WRF4 with LIOCM is a crucial step towards the development of the next generation of regional earth system models at the Chinese Academy of Sciences. | Liwei ZOU Tianjun ZHOU Jianping TANG Hailong LIU | 2020 | Advances in Atmospheric Sciences2020，37，8： | 4 |
| 3 | Mechanistic study of copper-catalyzed intramolecular ortho-C-H activation/carbon-nitrogen and carbon-oxygen cyclizations显示文摘Intramolecular ortho-C-H activation and C-N/C-O cyclizations of phenyl amidines and amides have recently been achieved under Cu catalysis. These reactions provide important examples of Cu-catalyzed functionalization of inert C-H bonds, but their mechanisms remain poorly understood. In the present study the several possible mechanisms including electrophilic aromatic substitution, concerted metalation-deprotonation (CMD), Friedel-Crafts mechanism, radical mechanism, and protoncoupled electron transfer have been theoretically examined. Cu(Ⅱ)-assisted CMD mechanism is found to be the most feasible for both C-O and C-N cyclizations. This mechanism includes three steps, i.e. CMD with Cu(Ⅱ), oxidation of the Cu(Ⅱ) intermediate, and reductive elimination from Cu(Ⅲ). Our calculations show that Cu(Ⅱ) mediates the C-H activation through an six-membered ring CMD transition state similar to that proposed for many Pd-catalyzed C-H activation reactions. It is also interesting to find that the rate-limiting steps are different for C-N and C-O cyclizations: for the former it is concerted metalation-deprotonation with Cu(Ⅱ), whereas for the latter it is reductive elimination from Cu(Ⅲ). The above conclusions are consistent with the experimental kinetic isotope effects (1.0 and 2.1 for C-O and C-N cyclizations, respectively), substituent effects, and the reactions under O2 -free conditions. | TANG ShiYa GONG TianJun FU Yao | 2013 | Science China Chemistry2013，56，5： | 2 |
| 4 | Stable PbS colloidal quantum dot inks enable blade‑coating infrared solar cells显示文摘Infrared solar cells are more efective than normal bandgap solar cells at reducing the spectral loss in the near-infrared region,thus also at broadening the absorption spectra and improving power conversion efciency.PbS colloidal quantum dots(QDs)with tunable bandgap are ideal infrared photovoltaic materials.However,QD solar cell production sufers from small-areabased spin-coating fabrication methods and unstable QD ink.Herein,the QD ink stability mechanism was fully investigated according to Lewis acid–base theory and colloid stability theory.We further studied a mixed solvent system using dimethylformamide and butylamine,compatible with the scalable manufacture of method-blade coating.Based on the ink system,100 cm2 of uniform and dense near-infrared PbS QDs(~0.96 eV)flm was successfully prepared by blade coating.The average efciencies of above absorber-based devices reached 11.14%under AM1.5G illumination,and the 800 nm-fltered efciency achieved 4.28%.Both were the top values among blade coating method based devices.The newly developed ink showed excellent stability,and the device performance based on the ink stored for 7 h was similar to that of fresh ink.The matched solvent system for stable PbS QD ink represents a crucial step toward large area blade coating photoelectric devices. | Xinzhao Zhao Mingyu Li Tianjun Ma Jun Yan Gomaa Mohamed Gomaa Khalaf Chao Chen Hsien‑Yi Hsu Haisheng Song Jiang Tang | 2023 | Frontiers of Optoelectronics2023，16，3： | 0 |
| 5 | Ecological Characteristics of Plankton in Shenzhen Bay显示文摘Based on plankton data at two sampling sites of subtidal zone of Shenzhen Bay during 2016-2017,temporal-spatial changes of species composition and quantity,dominant species,diversity index and evenness were analyzed. The results showed that eco-environment quality of plankton in Shenzhen Bay was in general level. | Tang Tianjun Chen Chunxing Xie Linshen | 2019 | Meteorological and Environmental Research2019，10，1： | 0 |
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