维普期刊资源整合服务平台（V6.5）

维普中文期刊产品整合服务

1篇 您的检索式：作者名="Sunmoon Yu"

选中清除导出查看参考文献查看引证文献引用追踪共1页首页上一页第1页下一页末页 /1 跳转

		题名	作者	年代	出处	被引量
	1	Sulfur-doped graphene anchoring of ultrafine Au25 nanoclusters for electrocatalysis显示文摘The biggest challenge of exploring the catalytic properties of under-coordinated nanoclusters is the issue of stability.We demonstrate herein that chemical dopants on sulfur-doped graphene(S-G)can be utilized to stabilize ultrafine(sub-2 nm)Au_(25)(PET)18 clusters to enable stable nitrogen reduction reaction(NRR)without significant structural degradation.The Au_(25)@S-G exhibits an ammonia yield rate of 27.5μgNH_(3)·mgAu^(-1)·h^(-1)at-0.5 V with faradic efficiency of 2.3%.More importantly,the anchored clusters preserve~80%NRR activity after four days of continuous operation,a significant improvement over the 15%remaining ammonia production rate for clusters loaded on undoped graphene tested under the same conditions.Isotope labeling experiments confirmed the ammonia was a direct reaction product of N2 feeding gas instead of other chemical contaminations.Ex-situ X-ray photoelectron spectroscopy and X-ray absorption near-edge spectroscopy of post-reaction catalysts reveal that the sulfur dopant plays a critical role in stabilizing the chemical state and coordination environment of Au atoms in clusters.Further ReaxFF molecular dynamics(RMD)simulation confirmed the strong interaction between Au nanoclusters(NCs)and S-G.This substrate-anchoring process could serve as an effective strategy to study ultrafine nanoclusters’electrocatalytic behavior while minimizing the destruction of the under-coordinated surface motif under harsh electrochemical reaction conditions.	Mufan Li Bei Zhang Tao Cheng Sunmoon Yu Sheena Louisia Chubai Chen Shouping Chen Stefano Cestellos-Blanco William AGoddard III Peidong Yang	2021	Nano Research2021，14，10：	0

返回顶部每页显示：

共1页首页上一页第1页下一页末页 /1 跳转

goolge学术搜索-维普

网站首页 | 关于我们 | 联系我们 | 产品服务 | 客服中心 | 广告服务 | 版权声明 | 网站联盟 | 友情链接 | 售卡网点

版权所有© 渝B2-20050021-1　渝公网安备 50019002500403号　违法和不良信息举报中心

互联网出版许可证新出网证(渝)字10号全国400电话 - 免长途话费