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您的检索式：作者名="Steven L.Suib"
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| 1 | Fe doped aluminoborate PKU-1 catalysts for the ketalization of glycerol to solketal: Unveiling the effects of iron composition and boron显示文摘An inexpensive Fe doped aluminoborate consisted of 18% Fe in PKU-1 material that exhibits high selectivity of 4-hydroxymethy-2,2-dimethyl^(-1),3-dioxolane (Solketal, 98.3%), considerable activity (TOF 51.7 h-1), and recyclable ability in the ketalization of glycerol to Solketal with acetone at 318 K has been developed. Our study demonstrated that the structure of Fe (less agglomerated iron species vs. FeO clusters) can be tuned by changing Fe loading in the PKU-1 material, which correlated well with experimental observations. Furthermore, the surface boron sites were promoted by iron loading and behaved as Lewis-acid sites to facilitate the reaction process of glycerol ketalization, while the Solketal selectivity was closely related with the structure of iron species in PKU-1, which was proved by kinetic studies, density function theory (DFT) calculations, and a series of spectroscopy studies. This investigation demonstrates that the surface B sites can play important roles in the reaction instead of being spectators. | Weilu Wang Xiangke Zeng Yanliu Dang Ping Ouyang Haidong Zhang Guangming Jiang Fan Dong Tao Yang Steven L.Suib Yang He | 2022 | Chinese Chemical Letters2022，33，3： | 0 |
| 2 | Effects of Zr substitution on soot combustion over cubic fluorite-structured nanoceria:Soot-ceria contact and interfacial oxygen evolution显示文摘Ceria is widely used as a catalyst for soot combustion,but effects of Zr substitution on the reaction mechanism is ambiguous.The present work elucidates effects of Zr substitution on soot combustion over cubic fluorite-structured nanoceria.The nanostructured CeO_(2),Ce_(0.92)Zr_(0.08)O_(2),and Ce_(0.84)Zr_(0.16)O_(2)composed of 5-6 nm crystallites display T_(m-CO2)(the temperature at maximum CO_2 yield)at 383,355,and 375℃under 10 vol.%O_(2)/N_(2),respectively.The size of agglomerate decreases from 165.5 to 51.9-57.3 nm,which is beneficial for the sootceria contact.Moreover,Zr increases the amount of surface oxygen vacancies,generating more active oxygen(O_(2)^-and O^(-))for soot oxidation.Thus,the activities of Ce_(0.92)Zr_(0.08)O_(2)and Ce_(0.84)Zr_(0.16)O_(2)in soot combustion are better than that of CeO_(2).Although oxygen vacancies promote the migration of lattice O~(2-),the enriched surface Zr also inhibits the mobility of lattice O^(2-).Therefore,the T_(m-CO2)of Ce_(0.84)Zr_(0.1)6 O_(2)is higher than that of Ce_(0.92)Zr_(0.08)O_(2).Based on reaction kinetic study,soot in direct contact with ceria preferentially decomposes with low activation energy,while the oxidation of isolated soot occurs through diffusion with high activation energy.The obtained findings provide new understanding on the soot combustion over nanoceria. | Peng Liu Xiaoliang Liang Yanliu Dang Junkai He Alireza Shirazi-Amin Laura A.Achola Shanka Dissanayake Hanlin Chen Mingli Fu Daiqi Ye Steven L.Suib | 2021 | Journal of Environmental Sciences2021，33，3： | 0 |
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