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您的检索式：作者名="Shimaa M.ALI"
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| 1 | Removal of organic pollutants by lanthanide-doped MIL-53(Fe) metal-organic frameworks:Effect of dopant type in magnetite precursor显示文摘A series of undoped and lanthanide doped MIL-53(Fe)/Ln-Fe_(3)O_(4)(Ln=La,Nd,or Gd) metal-organic frameworks(MOFs) were prepared by the solvothermal method.All prepared samples were characterized by X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FT-IR),Brunauer-Emmett-Teller(BET) measurements,scanning electron microscopy(SEM),and thermal analysis.XRD and FT-IR results ascertain the successful MOF formation for all prepared samples.MIL-53(Fe)/La-Fe_(3)O_(4) has the smallest particle size of 8.6 nm,the largest BET surface area of 54.2 m^(2)/g,and the highest porosity.Undoped and different lanthanide doped MIL-53(Fe) we re employed as sorbents for the removal of methylene blue(MB)dye from aqueous solutions to examine the doping benefit and the effect of the dopant size on the sorption performance.Doping causes MOFs to act as pH-independent sorbents,which make it applicable at any condition.Adsorption follows pseudo-second-order kinetic model,and doped sorbents attain equilibrium faster.Langmuir isotherms are followed,except for MIL-53(Fe)/La-Fe_(3)O_(4).The adsorption capacity increases with increasing the dopant ion size,100.5 mg/g for La-doped MOF,which is about four times higher than that of undoped MOF.The adsorption mechanism involves chemical interactions between Lewis acid in magnetite MIL-53(Fe) series and Lewis base in MB. | Shimaa M.Ali Khadija M.Emran Fedaa M.M.Alrashedee | 2023 | Journal of Rare Earths2023，41，1： | 1 |
| 2 | 锌在酸性介质中的腐蚀控制:葫芦巴绿色抑制剂(英文)显示文摘利用葫芦巴种子提取物作为绿色腐蚀抑制剂,采用失重法和电化学方法研究锌在2.0 mol/L硫酸和2.0 mol/L盐酸中的腐蚀行为。扫描电子显微镜结果表明添加抑制剂后,锌的表面腐蚀得到减缓。光电子能谱分析表明腐蚀产物为Zn O,验证了抑制剂的吸收机理。当添加200 m L/L葫芦巴提取物时,在硫酸溶液中腐蚀1 h和盐酸溶液中腐蚀0.5 h可得到最大抑制率,分别为90.7%和66.6%。在HCl溶液中添加I-离子时,由于协同作用可大幅度提高葫芦巴种子提取物对锌腐蚀的抑制率。动电位极化和EIS分析表明葫芦巴种子提取物对锌在盐酸中的腐蚀有抑制作用。添加葫芦巴种子提取物可降低腐蚀电流,增加电荷转移电阻。 | Shimaa M.ALI Hamedh A.Al LEHAIBI | 2016 | Transactions of Nonferrous Metals Society of China2016，26，11： | 1 |
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