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1篇 您的检索式:作者名="Shangjun Fu"
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1Ultrasound-assisted co-precipitation synthesis of mesoporous Co_(3)O_(4)–CeO_(2)composite oxides for highly selective catalytic oxidation of cyclohexane显示文摘The one-step highly selective oxidation of cyclohexane into cyclohexanone and cyclohexanol as the essential intermediates of nylon-6 and nylon-66 is considerably challenging.Therefore,an efficient and low-cost catalyst must be urgently developed to improve the efficiency of this process.In this study,a Co_(3)O_(4)–CeO2 composite oxide catalyst was successfully prepared through ultrasound-assisted co-precipitation.This catalyst exhibited a higher selectivity to KA-oil,which was benefited from the synergistic effects between Co^(3+))/Co^(2+))and Ce^(4+)/Ce^(3+)redox pairs,than bulk CeO2 and/or Co_(3)O_(4).Under the optimum reaction conditions,89.6%selectivity to KA-oil with a cyclohexane conversion of 5.8%was achieved over Co_(3)O_(4)–CeO2.Its catalytic performance remained unchanged after five runs.Using the synergistic effects between the redox pairs of different transition metals,this study provides a feasible strategy to design high-performance catalysts for the selective oxidation of alkanes.Shangjun Fu Kuiyi You Zhenpan Chen Taobo Liu Qiong Wang Fangfang Zhao Qiuhong Ai Pingle Liu He’an Luo 2022Frontiers of Chemical Science and Engineering2022,16,8:1
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