|
|
|
题名
|
作者
|
年代
|
出处
|
被引量
|
| 1 | Hydrogen-Bonded Organic Frameworks:A Rising Class of Porous Molecular Materials显示文摘CONSPECTUS:Hydrogen-bonded organic frameworks(HOFs)are a class of porous molecular materials that rely on the assembly of organic building blocks by means of hydrogen-bonding interactions to form two-dimensional(2D)and three-dimensional(3D)crystalline networks.The reversible nature of the hydrogenbond formation endows HOFs with the attributes of solution processability and simple regeneration.High-quality single crystals of HOFs can be grown easily for unambiguous superstructure determination by single-crystal X-ray diffraction,which is crucial for the elucidation of superstructure−property relationships.During the past decade,considerable progress has been achieved in realizing stable HOFs with permanent porosities by focusing on the design of molecular building blocks in order to introduce rigidity,auxiliary[π···π]interactions,and interpenetration of their frameworks to sustain the extended networks.The applications of HOFs are far-reaching,spanning catalysis,energy,and biomedical products as well as the storage and separation of fine chemicals.In this Account,we,first of all,provide an overview of the chronological development of HOFs,starting from the seminal work by Marsh and Duchamp in 1969 on the crystal superstructure of the hydrogen-bonded networks of trimesic acid.We identify the development of novel hydrogen-bonding motifs such as diaminotriazine(DTA),the introduction of the concept of molecular tectonics,and the establishment of permanent porosity in HOFs as being some of the milestones,which incentivized the current burgeoning research endeavors on developing HOFs as multifunctional materials.This Account is focused primarily on surveying the strategies for constructing porous 3D HOFs based on organic building blocks with peripheral carboxyl groups.These strategies are presented in the following categories:(1)the polycatenation of 2D networks by trigonal building blocks to form global 3D frameworks,(2)the utilization of building blocks with 3D geometriestetrahedral and trigonal prismaticthat are predisposed to form 3D networks,and(3)the docking by shape-fitting of geometrically labile building blocks.We emphasize how the molecular geometry of the building blocks plays an important role in modulating the superstructures of extended frameworks so as to address specific applications.Recognizing that the in silico design of HOFs is the ultimate goal of researchers in this field,we also discuss the recent advances in superstructure prediction that lead to the formation of porous supramolecular crystals and assess the complications in implementing computational methods for HOFs with complex superstructures.We hope this Account will inspire the development of new supramolecular designs and creative approaches to crystal engineering that aid and abet the assembly of multifunctional HOFs with customizable properties. | Penghao Li Matthew R.Ryder J.Fraser Stoddart | 2020 | Accounts of Materials Research2020，1，1： | 2 |
| 2 | Large-pore apertures in a series of metal-organic frameworks显示文摘 | Deng H Grunder S Cordova K E Valente C Furukawa H Hmadeh M Gandara F Whalley A C Liu Z Asahina S Kazumori H O'Keeffe M Terasaki O Stoddart J F Yaghi O M | 2012 | Science2012，336，： | 1 |
| 3 | Me tal-containing Dendritic Polymer 显示文摘 | STODDART F J WE LTO N T | 1999 | Polyhedron1999，18，： | 1 |
| 4 | Techniques for the eleetrophoresis of mangrovetissue 显示文摘 | Goodall J A Stoddart J A | 1989 | Aquat Bot1989，35，： | 1 |
| 5 | Genetic algorithms for free-form surface matching显示文摘 | Stoddart A J | 1996 | Pattern Recognition1996，4，4： | 1 |
| 6 | TGFβ3 and loading increases osteocyte survival in human cancellous bone cultured ex vivo显示文摘 | Simpson AE Stoddart MJ Davies CM | 2009 | Cell Biochem Funct2009，27，1： | 1 |
| 7 | Practical liquid chromatographic separation schemes for pyrrolic and pyridinic nitrogen aromatic heterocycle fraction from crude oils suitable for rapid characterization of geochemical samples显示文摘 | Li M Larter S R Stoddart D | 1991 | Analytical Chemistry1991，64，： | 1 |
| 8 | Practical liquid chromatographic separation schemes for pyrrolic and pyridinic nitrogen aromatic heterocycle fractions from crude oils suitable for rapid characterization of geochemical samples 显示文摘 | LI M LARTER S R STODDART D | 1992 | Analytical Chemistry1992，64，： | 1 |
| 9 | Optical Properties of Chi tin: Surface-Enhanced Raman Scattering Substrates Based on An tireflection Structures on Cicada Wings 显示文摘 | Stoddart P Cadusch P Boyce T | 2006 | Nanotechnology2006，17，： | 1 |
| 10 | Second-sphere Cordinadon Adducts of Phosphane-transition Metal Complexes with β-cyclodextrin and Its Methylated Derivative显示文摘 | ALSTON D R SLAWIN D R STODDART J F | 1988 | Angew Chem Int Ed1988，27，： | 1 |
| 11 | Cells and biomaterials in cartilage tissue engineering显示文摘 | Stoddart M J Grad S Eglin D | 2009 | Regen Med2009，4，1： | 1 |
| 12 | Self-Assembly in Natural and Unnatural Systems 显示文摘 | Philp D Stoddart J F | 1996 | Angew Chem Int Ed Engl1996，35，： | 1 |
| 13 | What prevents olderpeople from seeking treatment for urinary incontinence? Aqualitative exploration of barriers to the use of communitycontinence services显示文摘 | Horrocks S Somerset M Stoddart H | 2004 | Fam Pract2004，21，6： | 1 |
| 14 | Chem显示文摘 | Stoddart J F | 1998 | Rev1998，，98： | 1 |
| 15 | Agonism and allosterism: the pharmacology of the free fatty acid receptors FFA2 and FFA3显示文摘 | Milligan G Stoddart L A Smith N J | 2009 | British Journal of Pharmacology2009，158，1： | 1 |
| 16 | Vertical axis resistance type wind turbines for use in buildings显示文摘 | MULLER G JENTSCH M F STODDART E | 2009 | Renewable Energy2009，34，： | 1 |
| 17 | Producing health, consuming health care 显示文摘 | Evans RG Stoddart GL | 1990 | Bull Soc Sci Med Grand Duche Luxemb1990，31，： | 1 |
| 18 | Meslostructured silica supports for functional materials and molecular machines显示文摘 | Angelos S Johansson E Stoddart JF | | 0，，14： | 1 |
| 19 | Mutant analyses define multiple roles for phytochrome C in Arabidopsis photomorphogenesis显示文摘 | Franklin K A Davis S J Stoddart W M | 2003 | Plant Cell2003，15，： | 1 |
| 20 | Geography, education and research显示文摘 | Stoddart DR | 1981 | The Geographical Journal1981，147，3： | 1 |
您所在的机构暂未开通此部分的功能，请联系管理员