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| 1 | Interface-directed epitaxially growing nickle ensembles as efficient catalysts in dry reforming of methane显示文摘Supported nickel catalysts are promising candidates for dry reforming of methane, but agglomeration of Ni^(0) and coke deposition hinder the industrial applications. Herein, we report a novel interface-directed synthetic approach to construct distinct metal ensembles by carefully tuning the compositions of the carriers. A Zr-Mn-Zn ternary oxide-supported Ni catalyst, together with the respective binary oxide-supported analogues, was synthesized by adopting a sequential co-precipitation and wetness impregnation method. Combined characterization techniques identify distinct catalyst models, including (i) conventional NiO nanoparticles with different sizes on Zr-Mn and Zr-Zn, and (ii) epitaxially growing NiO ensembles of a few nanometers thickness at the periphery of ZnO_(x) particles. These catalysts exhibit divergent responses in the catalytic testing, with the ternary oxide system significantly outperforming the binary analogues. The strong electronic interactions between Mn-Ni increase Ni dispersion and the activity while the stability is strengthened upon Zn addition. Both high activity, high selectivity, and remarkable stability are attained upon co-adding Mn and Zn. The interfaces between Ni and Zr-Mn-Zn rather than the physical contacts of individual oxide-supported analogues through mechanical mixing are keys for the outstanding performance. | Ping Wang Song Wei Shiyi Wang Ronghe Lin Xiaoling Mou Yunjie Ding | 2022 | Journal of Energy Chemistry2022，31，3： | 1 |
| 2 | Full Metal Species Quantification of Metal Supported Catalysts Through Massive TEM Images Recognition显示文摘For a practical high-loading single-atom catalyst,it is prone to forming diverse metal species owing to either the synthesis inhomogeneity or the reaction induced aggregation.The diversity of this metal species challenges the discerning about the contributions of specific metal species to the catalytic performance,and thus hampers the rational catalyst design.In this paper,a distinct solution of dispersion analysis based on transmission electron microscopy imaging specialized for metal-supported catalysts has been proposed in the capability of full-metal-species quantification(FMSQ)from single atoms to nanoparticles,including dispersion densities,shape geometry,and crystallographic surface exposure.This solution integrates two image-recognition algorithms including the electron microscopy-based atom recognition statistics(EMARS)for single atoms and U-Net type deep learning network for nanoparticles in different shapes.When applied to the C_(3)N_(4)-and nitrogen-doped carbon-supported catalysts,the FMSQ method successfully identifies the specific activity contributions of Au single atoms and particles in butadiene hydrogenation,which presents remarkable variation with the metal species constitution.This work demonstrates a promising value of our FMSQ strategy for identifying the activity origin of heterogeneous catalysis. | LIU Shuhui ZHANG Fan LIN Ronghe LIU Wei | 2022 | Chemical Research in Chinese Universities2022，38，5： | 0 |
| 3 | Comparative study on stability and coke deposition over supported Rh and FePO_4 catalysts for oxy-bromination of methane显示文摘Rhodium- and iron phosphate-based catalysts are by far the most promising catalysts for oxy-bromination of methane(OBM) reaction. However, most literature reported either Rh- or FePO4-based catalysts, and the results were rarely studied in a uniform environmental condition. In this report, comparative study was conducted on silica- and silicon carbide-supported rhodium and iron phosphate catalysts with the main focuses on stability performance and coke deposition. The catalytic results demonstrated that the stability of both Rh- and FePO4-based catalysts was greatly influenced by the supports used, and silicon carbide-supported catalysts showed much better anti-coking ability as compared with silica-supported ones. Temperature-programmed oxidation over the used catalysts further indicated that the coke formation mechanisms were completely different between silica-supported rhodium and iron phosphate catalysts. While cokes might be caused by condensation of CH2Br2over supported iron phosphate, methane decomposition might be the reason for coke formation over silica-supported rhodium catalyst. These findings might pave the way for designing highly efficient and stable catalysts of the OBM reaction. | Ronghe Lin Yunjie Ding Runqin Wang | 2014 | Journal of Energy Chemistry2014，23，1： | 0 |
| 4 | Selective hydrogenation of 1,3-butadiene on iridium nanostructures:Structure sensitivity, host effect, and deactivation mechanism显示文摘A systematic study on the structure sensitivity,host effect,and the deactivation mechanism of Ircatalyzed selective hydrogenation of 1,3-butadiene,a key process in the purification of alkadiene for the upgrading of C4 cut,is presented by coupling steady-state catalytic testing,in-depth characterization,kinetic evaluation,and density functional theory calculations.We reveal that:(i) 1,3-Butadiene hydrogenation on iridium is structure-sensitive with the optimal particle size of about 2 nm,and the H_(2) dissociation energy is a reliable activity descriptor;(ii) The nature of the NC hosts exerts a critical impact on the catalytic performance,and balanced nitrogen content and speciation seem key for the optimized performance;and (iii) Different deactivation mechanisms occur:fouling by coke deposition on the catalysts with a high N:C ratio (>1),and site blockage due to the competitive adsorption between 1-butene/cis-2-butene and 1,3-butadiene.These molecular insights provide valuable guidelines for the catalyst design in selective hydrogenations. | Mengru Wang Yuxue Yue Yi Wang Xiaoling Mou Renqin Chang Zupeng Chen Ronghe Lin Jia Zhao Yunjie Ding | 2022 | Journal of Energy Chemistry2022，31，6： | 0 |
| 5 | Assembly of N-and P-functionalized carbon nanostructures derived from precursor-defined ternary copolymers for high-capacity lithiumion batteries显示文摘Synthesis of new carbon nanostructures with tunable properties is vital for precisely regulating electrochemical performance in the wide applications.Herein,we report a novel approach for the oxidative polymerization of N-and P-bearing copolymers from the self-assembly of three different monomers(aniline,pyrrole,and phytic acid),and further prepare the respective carbon nanostructures with relatively consistent N dopant(6.2%–8.0%,atom)and varying P concentrations(0.4%–2.8%,atom)via controllable pyrolysis.The impacts of phytic acid addition on the compositional,structural,and morphological evolution of the copolymers and the resulting nanocarbons are well studied through a spectrum of characterizations including N2 sorption,Fourier transform infrared spectroscopy,gel permeation chromatograph,scanning/transmission electron microscopy,and X-ray photoelectron spectroscopy.Gradual fragmentation of the nanosphere structures is evidenced with increasing addition of phytic acid,leading to different nanostructures from hollow nanospheres to 3D aggregates.Nanocarbons decorated with N and P dopants from pyrolysis are further utilized as anode materials in lithium-ion batteries,demonstrating enhanced electrochemical performance,i.e.,a reversible capacity of 380 mAhg^(-1)at 2 Ag^(-1)for NPC-0.5 during 200 cycles.The superior performance originates from the balanced porosity,and appropriate concentrations of P and pyrrolic N,thus pointing the direction for designing high-performance anode materials. | Luyao Guo Mengru Wang Ronghe Lin Jiaxin Ma Shuanghao Zheng Xiaoling Mou Jun Zhang Zhong-Shuai Wu Yunjie Ding | 2023 | Chinese Journal of Chemical Engineering2023，53，1： | 0 |
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