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| 1 | 一种同时分辨识别Zn^(2+)和F^-离子的双功能探针(英文)显示文摘由8-甲酰基-7-羟基香豆素与碳酰肼经一步缩合反应可制得探针1。研究发现,探针1对Zn^(2+)和F-离子均呈现荧光增强和比率比色的高灵敏和高选择性响应,检出限低至10-8 mol·L^(-1)。通过光谱、ITC、1H NMR滴定及质谱分析,详细地研究了探针与离子形成的配合物性质。在不同的介质中,探针不仅同时表现出对金属阳离子Zn^(2+)和对阴离子F-的识别,而且吸收和发射波长均有显著的差异:1-Zn^(2+)配合物的最大吸收波长为360 nm,而1-F-配合物为400 nm;1-Zn^(2+)配合物的荧光激发和发射波长分别为360和454 nm,而1-F-配合物分别为400和475 nm。此外,探针1还能应用于活体PC3细胞中Zn^(2+)的荧光成像。 | 曾莉 赵江林 牟兰 曾晞 卫钢 Redshaw Carl 金宗文 | 2017 | 无机化学学报2017，33，5： | 2 |
| 2 | New Quinoxaline-Based Blue Emitters: Molecular Structures, Aggregation-Induced Enhanced Emission Characteristics and OLED Application显示文摘Three new deep blue light emitters,bearing quinoxaline with different substituents(biphenyl/pyrene)at the 1-or 2-position,were synthesized by a Pd-catalysed coupling reaction in high yields,and were fully characterized by 1H/13C NMR spectroscopy,single crystal X-ray diffraction,and high-resolution mass spectrometry(HRMS). | Xiaoyu Mao Fuli Xie Xiaohui Wang Qingsong Wang Zhipeng Qiu Mark R.J.Elsegood Jie Bai Xing Feng Carl Redshaw Yanping Huo Jian-Yong Hu Qing Chen | 2021 | Chinese Journal of Chemistry2021，39，8： | 1 |
| 3 | Ultralong nitrogen/sulfur Co-doped carbon nano-hollowsphere chains with encapsulated cobalt nanoparticles for highly efficient oxygen electrocatalysis显示文摘The development of simple and effective strategies to prepare electrocatalysts,which possess unique and stable structures comprised of metal/nonmetallic atoms for oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),is currently an urgent issue.Herein,an efficient bifunctional electrocatalyst featured by ultralong N,S-doped carbon nano-hollow-sphere chains about 1300 nm with encapsulated Co nanoparticles(Co-CNHSCs)is developed.The multifunctional catalytic properties of Co together with the heteroatom-induced charge redistribution(i.e.,modulating the electronic structure of the active site)result in superior catalytic activities toward OER and ORR in alkaline media.The optimized catalyst Co-CNHSC-3 displays an outstanding electrocatalytic ability for ORR and OER,a high specific capacity of 1023.6 mAh gZn^(-1),and excellent reversibility after 80 h at 10mA cm^(-2)in a Zn-air battery system.This work presents a new strategy for the design and synthesis of efficient multifunctional carbon-based catalysts for energy storage and conversion devices. | Wei Zhang Xingmei Guo Cong Li Jiang-Yan Xue Wan-Ying Xu Zheng Niu Hongwei Gu Carl Redshaw Jian-Ping Lang | 2023 | Carbon Energy2023，5，8： | 1 |
| 4 | Chromium complexes bearing pyrrolide-imine N, N-chelate ligands: Synthesis, structures and ethylene polymerisation behaviour显示文摘 | Vemon C Gibson Claire Newton Carl Redshaw | 2002 | Journal of the Chemical Society Dalton Transactions2002，21，： | 1 |
| 5 | HALONICKEL 2,4-DI-t-BUTYL-6-(QUINOLIN-8-YLIMINOMETHYL)PHENOLATES:SYNTHESIS,CHARACTERIZATION AND ETHYLENE REACTIVITY显示文摘A series of nickel halides bearing 2,4-di-t-butyl-6-(quinolin-8-yliminomethyl) phenolate ligands was synthesized and characterized by IR spectroscopy and elemental analysis.Molecular structures of C1(R = H,X = Br) and C2(R = H,X = Cl) were further confirmed by single-crystal X-ray crystallographic studies,and revealed a distorted square planar geometry at nickel.Upon activation with diethylaluminum chloride(Et 2 AlCl),all nickel pre-catalysts displayed good catalytic activity [up to 9.3 × 10 5 g mol 1(Ni) h 1 ] for ethylene oligomerization with major dimerization.In the presence of methylaluminoxane(MAO),the nickel complex C1 was capable of ethylene polymerization under 3 MPa,and produced polyethylene products with narrow polydispersity(1.16 1.73) and molecular weights in the range of 2.6 4.95 kg/mol. | Qi-song Shi Xiang Hao Carl Redshaw 孙文华 | 2013 | Chinese Journal of Polymer Science2013，31，5： | 1 |
| 6 | 一种用于水中次氯酸根检测的高选择性裸眼比色探针显示文摘实时检测和监测水中的次氯酸根离子(ClO-)是极富挑战性的研究工作。报道了一种光学性能优异、“裸眼”可分辨的比色型探针分子(PAH)。首先利用高分辨质谱,核磁共振氢谱和核磁共振碳谱等方法对目标探针分子(PAH)的结构进行表征。随后,利用紫外-可见吸收光谱考察了不同pH缓冲溶液条件下探针PAH与次氯酸根离子的相互作用。结果显示,水溶性的探针分子PAH在pH值为2.0~5.0的磷酸盐缓冲液中为黄色溶液,其最大吸收峰在424 nm处;在pH值为6.0~12.0的磷酸盐缓冲液中PAH为紫色溶液,最大吸收峰在532 nm处;在不同pH缓冲液体系中分别加入次氯酸根离子,肉眼可观察PAH溶液颜色褪去,紫外-可见吸收光谱显示在424 nm处的特征吸收峰逐渐降低并在532 nm处出现新的吸收峰,溶液颜色从黄色到紫色然后到无色,特征峰明显消失。进一步优化了实验条件,发现在pH 5.0的磷酸盐缓冲液中,探针分子PAH对ClO-离子具有特定的选择性和灵敏度,并且具有较低检出限等优点;在优化的条件下,探究了常见的金属离子、阴离子等共存条件下,对探针分子PAH检测次氯酸根离子的干扰影响。实验发现,常见的金属离子(Li^(+),Co 2^(+),Cr 3^(+),K^(+),Cd 2^(+),Pb 2^(+),Ca 2^(+),Hg 2^(+),Ba 2^(+),Cu 2^(+),Mg 2^(+),Ni 2^(+),Zn^(2^(+)),Al 3^(+)和Fe 3^(+)),阴离子(NO-2,I-,AcO-,ClO-4,SO_(2)-4,CN-,Br-,CO_(2)-3和F-),活性氧(ROO·,·OH,H_(2)O_(2),·O-2,tBuOOH,tBuO·和^(1)O_(2)),和活性氮(ONOO-和NO·)等33种物质对探针分子检测ClO-离子的干扰较小。同时,探针PAH可以定量检测次氯酸根离子(y=1.58678-0.52451x,R^(2)=0.99852),检出限为5.39μmol·L^(-1)。此外,对水体系(84消毒剂和自来水)中的次氯酸根离子浓度进行分析,三次平行试验测得自来水中次氯酸根离子的平均浓度为7.96μmol·L^(-1),平均加标回收率高,表明探针PAH还可用于定量检测实际水体系中的次氯酸根离子。 | 余青 陈晓丽 张奇龙 刘华 杨先炯 徐红 黄亚励 冯星 REDSHAW Carl | 2022 | 光谱学与光谱分析2022，42，1： | 0 |
| 7 | Supramolecular Self-assembly Formed from Cucurbit[8]uril and p-Hydroxybenzoic Acid显示文摘The binding behavior of cucurbit[8]uril(Q[8])and p-hydroxybenzoic acid(p-HBA)has been investigated using ^(1)H NMR titration experiments,UV-Vis absorption,isothermal titration calorimetry(ITC),and X-ray crystallography.Results revealed that the Q[8]can accommodate two p-HBA molecules to form a 1:2 host-guest inclusion complex in solution,namely(p-HBA)2@Q[8].From a poorly scattering crystal,we were able to identify two symmetry unique Q[8]rings,but with different p-HBA fillings.The structure can be represented as Q[8]+1.5 p-HBA,which gives Q[8]@(p-HBA)2∙Q[8]@p-HBA as the structural formula.This supramolecular structure was screened for its ability to capture iodine.The experimental results showed that the adsorption efficiency of the supramolecular organic framework material for iodine capture was 43.8%,with an equilibrium adsorption capacity of 223.3 mg/g. | WANG Chenghui YU Zhichao BAI Qinghong PAN Dingwu PRIOR Timothy J TAO Zhu REDSHAW Carl XIAO Xin | 2023 | Chemical Research in Chinese Universities2023，39，6： | 0 |
| 8 | A novel pillar[5]arene-cucurbit[10]uril based host-guest complex: Synthesis, characterization and detection of paraquat显示文摘The macrocyclic family comprising pillar[n]arenes and cucurbit[n]urils have received much attention recently. However, studies on the construction of supramolecular complexes formed directly with derivatized pillar[n]arenes and cucurbit[n]urils are scant. Given the interest in such systems, herein we have synthesized a new type of naphthalene-derivatized pillar[n]arene NTP5 and selected Q[10] as the host molecule. The 4-[2-(1-naphthalenyl)ethenyl]pyridine of NTP5 is encapsulated by Q[10] and formed a hostguest complex in water-acetic acid(1:1) solution accompanied by enhanced fluorescence, which changed the morphology of NTP5 from a sphere to a porous form. In addition, the fluorescence of Q[10]-NTP5 can be quenched by the addition of the highly toxic pesticide paraquat(PQ), and the mechanism was shown to be the formation of a new charge transfer ternary system of Q[10]-NTP5-PQ. This work provides new ideas for the contribution of supramolecular assemblies based on derivatized pillar[n]arenes and their combination with cucurbit[n]urils and reveals their potential applications. | Yang Luo Wei Zhang Jie Zhao Mao-Xia Yang Qian Ren Carl Redshaw Zhu Tao Xin Xiao | 2023 | Chinese Chemical Letters2023，34，3： | 0 |
| 9 | Supramolecular assemblies of cucurbit[n]urils and 4-aminopyridine controlled by cucurbit[n]uril size(n=5,6,7 and 8)显示文摘The binding interactions between 4-aminopyridine(4-AP) and a series of cucurbit[n]urils(Q[5], Q[6],TMe Q[6], Q[7], Q[8]) have been studied using1H NMR spectroscopy, UV–vis absorption spectroscopy,isothermal titration calorimetry(ITC) and X-ray crystallography. The data indicates that the Q[5]@4-AP complex exhibits exo binding, which is not observed in the other four host-guest complexes. Furthermore,X-ray crystallography clearly reveals how the Q[n]s bind with 4-AP to form complexes, for example Q[5]forms an outer-surface complex, whilst Q[6], TMe Q[6] and Q[7] formed 1:1 host and guest type complexes, and Q[8] formed a stable 1:2 ternary complex due to its large cavity, which can accommodate two 4-AP molecules. | Yun Lu Zhichao Yu Xinan Yang Jingjing Dai Peihui Shan Xianhao Feng Zhu Tao Carl Redshaw Xin Xiao | 2023 | Chinese Chemical Letters2023，34，7： | 0 |
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