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| 1 | Multi-scale processes influencing global carbon storage and land-carbon-climate nexus:A critical review显示文摘Carbon(C)is a key constitutive element in living organisms(plants,microbes,animals,and humans).Carbon is also a basic component of agriculture because it plays a dynamic role in crop growth,development,nutrient cycling,soil fertility,and other agricultural features.The presence of C enhances soil physical,chemical,and biological properties.The C cycle supports all life on the Earth by transferring C between living organisms and the environment.The global climate is changing,and this change is attributable to the release of carbon dioxide and other greenhouse gases from human activities.Owing to the global climate change,agriculture is expected to be majorly affected.Agricultural production is directly linked to the climate.The five main global C pools are the oceanic,geologic,pedologic,atmospheric,and biotic pools,with specific reservoirs and inter-pool fluxes.The soil organic matter has various organic C pools(active,slow,and passive pools),containing various C-based fractions and specific liability pools.Climate,geology,land use,and management techniques are some of the variables that affect organic C and its reservoirs.The dynamics of each of these variables must be understood for a thorough knowledge of how they impact the soil C pools and storage capacity under the changing climate conditions.This review provides a comprehensive overview of the various factors that affect soil C pools/fractions and their C sequestration capacity. | Owais Ali WANI Shamal Shasang KUMAR Nazir HUSSAIN Anas Ibni Ali WANI Subhash BABU Parvej ALAM Megna RASHID Simona Mariana POPESCU Sheikh MANSOOR | 2023 | Pedosphere2023，33，2： | 0 |
| 2 | Chromene-based BioAIEgens:‘in-water’synthesis,regiostructure-dependent fluorescence and ER-specific imaging显示文摘Exploration of artificial aggregation-induced emission luminogens(AIEgens)has garnered extensive interest in the past two decades.In particular,AIEgens possessing natural characteristics(BioAIEgens)have received more attention recently due to the advantages of biocompatibility,sustainability and renewability.However,the extremely limited number of BioAIEgens extracted from natural sources have retarded their development.Herein,a new class of BioAIEgens based on the natural scaffold of chromene have been facilely synthesized via green reactions in a water system.These compounds show regiostructure-,polymorphism-and substituent-dependent fluorescence,which clearly illustrates the close relationship between the macroscopic properties and hierarchical structure of aggregates.Due to the superior biocompatibility of the natural scaffold,chromene-based BioAIEgens can specifically target the endoplasmic reticulum(ER)via the introduction of tosyl amide.This work has provided a new chromene scaffold for functional BioAIEgens on the basis of green and sustainable‘in-water’synthesis,applicable regiostructure-dependent fluorescence,and effective ER-specific imaging. | Xu-Min Cai Yuting Lin Jianyu Zhang Ying Li Zhenguo Tang Xuedan Zhang Ying Jia Wenjin Wang Shenlin Huang Parvej Alam Zheng Zhao Ben Zhong Tang | 2023 | National Science Review2023，10，11： | 0 |
| 3 | Metallophilicity-Induced Clusterization:Single-Component White-Light Clusteroluminescence with Stimulus Response显示文摘Materials showing metallophilic interactions continue to attract considerable theoretical and experimental attention largely because of their unusual and unanticipated photophysical behavior as well as their unique stimuli-responsive behavior in an aggregate or solid state.Metallophilic interactions are mostly found between metals with either identical(d^(10)–d^(10))or different(s^(2)–d^(8),d^(8)–d^(10))configurations.Among various metallophilic interactions,aurophilic interactions(Au⋯Au)are well-known and widely reported.In this study,a new phosphorescent gold(I)complex,[(CF_(3)Ph)_(3)PAuC≡CPh](TPPGPA)was reported. | Xueqian Zhao Parvej Alam Jianyu Zhang Shiyun Lin Qian Peng Jun Zhang Guodong Liang Sijie Chen Jing Zhang Herman HYSung Jacky WYLam Ian DWilliams Xinggui Gu Zheng Zhao Ben Zhong Tang | 2022 | CCS Chemistry2022，4，8： | 0 |
| 4 | A Simple Approach to Achieve Organic Radicals with Unusual Solid-State Emission and Persistent Stability显示文摘Sable organic radicals are promising materials for information storage,molecular magnetism,electronic devices,and biological probes.Many organic radicals have been prepared,but most are non-or weakly emissive and degrade easily upon photoexcitation.It remains challenging to produce stable and efficient luminescent radicals because of the absence of general guidelines for their synthesis.Herein,we present a photoactivation approach to generate a stable luminescent radical from tris(4-chlorophenyl)phosph ine(TCPP)with red emission in the crystal state.The mechanistic study suggests that the molecular symmetry breaking in the crystal causes changes of molecular conformation,redox properties,andmolecular packing that facilitates radical generation and stabilization.This design strategy demonstrates a straightforward approach to develop stable organic luminescent radicals that will open new doors to photoinduced luminescent radical materials. | Xueqian Zhao Junyi Gong Parvej Alam Chao Ma Yanpei Wang Jing Guo Zebin Zeng Zikai He Herman H.Y.Sung Ian D.Williams Kam Sing Wong Sijie Chen Jacky W.Y.Lam Zheng Zhao Ben Zhong Tang | 2022 | CCS Chemistry2022，4，6： | 0 |
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