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2篇 您的检索式:作者名="Nitheesha Shaji"
    题名 作者 年代 出处 被引量
1Biomass seaweed-derived n itrogen self-doped porous carb on anodes for sodium-ion batteries:Insights into the structure and electrochemical activity显示文摘Sustainable transformation and efficient utilization of biomasses and their derived materials are environ-mentally as well as economically compliant strategies.Biomass seaweed-derived nitrogen self-doped porous carbon with tailored surface area and pore structures are prepared through carb on izatio n and activation.The in fluence of carb on ization temperature on morphology,surface area,and heteroatom dopants are investigated to optimize sodium-ion storage capability.Seaweed-derived nitrogen selfdoped activated carbon(SAC)as anode materials for sodium-ion batteries exhibits remarkable reversible capacity of 303/192 mAh g^(-1) after 100/500 cycles at current densities of 100/200 mA g^(-1) respectively,and a good rate capability.The interconnected and porous conducting nature along with the heteroatom dopant role in creating defective sites and charge stabilization are favorable for ion storage and diffusion and electron transport,indicating the electrodes can offer improved electrochemical performances.In addition,post-mortem analysis of the cycled carbon electrodes through ex-situ tools demonstrates the sodium-ion storage mechanism.Chenrayan Senthil Jae Woo Park Nitheesha Shaji Gyu Sang Sim Chang Woo Lee 2022Journal of Energy Chemistry2022,31,1:5
2Advancing Li-ion storage performance with hybrid vertical carbon/Ni_(3)S_(2)-based electrodes显示文摘Conversion-reaction induced charge storage mechanisms of transition metal sulphides have received considerable interest in designing high-capacity electrodes for electrochemical energy storage devices.However,their low conductivity and structural degradation during cycling limit their applications as energy storage devices.A combination of different nickel sulphide phases tailored with carbon nanostructures is suggested to address these limitations.Herein,a facile,two-step approach is demonstrated for fabricating a hybrid electrode,consisting of trinickel disulphide(Ni_(3)S_(2))formed on a metallic Ni nanoparticle supported by vertical carbon nanotubes(VCN)backbone in the form Ni_(3)S_(2)/Ni@VCN.Ni_(3)S_(2)/Ni@VCN electrodes were tested as anode for lithium-ion batteries,and the electrode featured outstanding lithiumstorage capabilities with a high reversible capacity(1113 m Ah g^(-1) after 100 cycles at 100 m A g^(-1)),excellent long-term cycling stability(770 m Ah g^(-1) after 500 cycles at 200 m A g^(-1)),and good rate capability.The resulting electrode performance is one of the best Li-ion storage capabilities in the Ni_(3)S_(2)-type anode materials described.A unique “broccoli-like”structure of polycrystalline Ni_(3)S_(2)capped on conductive VCN backbone helps the interface storage process and boosts lithium storage performance.Neelakandan M.Santhosh Nitheesha Shaji d Petra Stražar Gregor Filipič Janez Zavašnik Chang Won Ho Murugan Nanthagopal Chang Woo Lee UrošCvelbar 2022Journal of Energy Chemistry2022,31,4:0
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