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| 1 | 微孔和介孔材料中的热化学(英文)显示文摘这篇论文综述了美国加州大学戴维斯分校科学院院士Navrotsky课题组多年来在多孔材料上取得的一系列热化学研究结果。讨论了热化学对微孔、介孔材料的结构稳定性和合成过程的影响。借助多种测热手段对影响骨架结构的热焓、热熵和自由能进行了系统的测量和计算。研究数据表明一系列纯硅分子筛、介孔材料和磷酸铝多孔材料同相应的石英相和块磷铝矿相相比能量上最多只高出15 kJ.mol-1。一系列纯硅分子筛的熵值比石英相高出3.2—4.2 J.K-1.mol-1;在0—12.6 J.K-1.mol-1范围内相对应的自由能几乎没有差别。因此,对不同微孔、介孔材料,其骨架结构在能量上是几乎没有区别的。另外,本文通过介绍一种新型测热方法———原位测热,揭示了分子筛合成过程中的动力学和成核/结晶机理。 | 李庆华 王景伟 袁昊 解丽丽 王立军 Alexandra Navrotsky | 2006 | 化学进展2006，18，5： | 3 |
| 2 | New Developments in the Calorimetry of High-Temperature Materials显示文摘1. Introduction Thermodynamics forms the fundamental underpinning of reactivity, transformation, and stability, and controls processes such as synthesis, corrosion and degradation, environmental transport, catalysis, and biological reactivity. In the materials field, the wealth of new compounds, polymorphs, hybrid organic–inorganic hybrid materials and metal organic frameworks, high-entropy alloys, and multiphase and nanophase materials attained by a variety of non-equilibrium synthesis and processing methodologies has outrun the available thermodynamic data, hampering current understanding of synthetic pathways, materials compatibility, and longevity during use, degradation, corrosion, and dissolution, and limiting our understanding of environmental contamination and transport for new materials. | Alexandra Navrotsky | 2019 | Engineering2019，5，3： | 2 |
| 3 | Enthalpy of formation of LiNiO2,LiCoO2 and their solid solution LiNil - x Cox O2 显示文摘 | Miaojun Wang Alexandra Navrotsky | 2004 | Solid State Ionics2004，166，： | 1 |
| 4 | Mantle geochemistry-A lesson from ceramics 显示文摘 | Navrotsky A | 1999 | Science1999，284，： | 1 |
| 5 | Enthalpy of Water Adsorption and Surface Enthalpy of Lepidocrocite,(γ-FeOOH)显示文摘 | Majzlan J Mazeina L Navrotsky A | | 0，，71： | 1 |
| 6 | Enthalpy of formation of LiNiO2, LiCoO2 and their solid solution LiNi1-x Cox O2 显示文摘 | WANG Miaojun NAVROTSKY A | 2004 | Solid State Ionics2004，166，： | 1 |
| 7 | Energetics of compounds(A2+B4+O3) with the perovskite structure显示文摘 | MUROMACHI E T NAVROTSKY A | 1988 | J Solid State Chem1988，72，： | 1 |
| 8 | Thermo-chemistry of microporous and mesoporous materials 显示文摘 | NAVROTSKY A TROFYMLUK O LEVCHENKO A A | 2009 | Chem Rev2009，109，9： | 1 |
| 9 | Thermochemistry of microporous and mesoporous materials 显示文摘 | Navrotsky A Trofymluk O Levchenko A A | 2009 | Chem Rev2009，109，9： | 1 |
| 10 | Thermodynamics of Solid Phases Containing Rare Earth Oxides显示文摘 | Navrotsky A Lee W Mielewczyk-Gryn A | 2015 | The Journal of Chemical Thermodynamics2015，88，： | 1 |
| 11 | Energetics in browmnillerite - perovskite pseudobinary Ca2Fe2O5 - CaTiO3 显示文摘 | PRASANNA T R S NAVROTSKY A | 1994 | Journal of Materials Research1994，9，12： | 1 |
| 12 | Enthalpy of formation of LiNiO2, LiCoO2 and their solid solution, LiNi1-xCoxO2显示文摘 | Wang M J Navrotsky A | 2004 | Solid State Ionics2004，166，12： | 1 |
| 13 | Simple spinels; crystallographic parameters, cation radii, lattice energies, and cationdistribution显示文摘 | O'NEILL H S C NAVROTSKY A | 1983 | American Mineralogist1983，68，12： | 1 |
| 14 | Enthalpy of water adsorption and surface enthalpy of goethite (α-FeOOH) and Hematite (α-Fe2O3) 显示文摘 | MAZEINA L NAVROTSKY A | 2007 | Chem Mater2007，19，： | 1 |
| 15 | Calorimetric study of maghemite nanoparticles synthesized by laser-induced pyrolysis 显示文摘 | BOMATI MIGUEL O MAZEINA L NAVROTSKY A | 2008 | Chem Mater2008，20，2： | 1 |
| 16 | Thermodynamics of glass formation and metastable solidifacation of molten Y3Al5O12显示文摘 | LIN I Ching ALEXANDRA Navrotsky Richard Weber J K | 1999 | J Non-Cryst Solids1999，243，23： | 1 |
| 17 | Olivine-modified spinel-spinel transitions in the system Mg2SiO4-Fe2SiO4: Calorimetric measurements, thermochemical calculation, and geophysical application 显示文摘 | Akaogi M Ito E Navrotsky A | 1989 | Journal of Geophysical Research1989，94，15： | 1 |
| 18 | Energetics of nanoparticle oxides:interplay between surface energy and polymorphism显示文摘 | Navrotsky A | 2003 | Geochemical Transactions2003，4，6： | 1 |
| 19 | Synthesis of nitrate sodalite: An in situ scanning calorimetric Study 显示文摘 | LIU Q Y NAVROTSKY A | 2007 | Geochimi Cosmochim Acta2007，71，： | 1 |
| 20 | Structural investigation and energetics of mullite formation from sol-gel precursors显示文摘 | Gerardin C Benziger J Sundaresan S Navrotsky A | | 0，，02： | 1 |
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