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| 1 | In situsynthesis, photometric and spectroscop- ic studies of chelating system during the 1,4,7,10, 13, 16-hexaoxacyclooctadecane charge transfer reaction with different aeceptors显示文摘 | Aisha S M Hossan Hanaa M Abou-Melha Moamen S Refat | 2011 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy2011，79，： | 1 |
| 2 | Synthesis and Spectroscopic Characterizations on the Complexation of Three Different Metal Ions Ba(Ⅱ),Ni(Ⅱ),and Ce(Ⅲ)with Atenolol Drug Chelate显示文摘Three types of metal ions barium(Ⅱ),nickel(Ⅱ)and cerium(Ⅲ)complexity of ATN drug have been prepared and characterized using molar conductance method,FT-IR,electronic,and 1H-NMR analysis measurements.The chemical and physical results for all atenolol complexes are agreement with the speculated structures.For the divalent(Ba&Ni)and trivalent(Ce)metal atenolol a molar ratio 1∶2 was established.Qualitative chemical analysis showed that for the divalent metal complexes,the chloride ions are not involved in the complexes,suggesting that all of these complexes,[Ba(ATN)2]·2 H2O and[Ni(ATN)2(H2O)2]·4 H2O are neutral.However,for the cerium(Ⅲ)complex,[Ce(ATN)2(NO3)]·3 H2O,the nitrate group is existed inside the coordination sphere.ATN make astable metal complexity with barium(Ⅱ),nickel(Ⅱ)and cerium(Ⅲ)ions.Electronic absorption analysis of Atenolol give two fundamental peaks at 225 nm and 274 nm refers to variation in transition electrons of ligand,UV spectral analysis of the three complexity obtained give asymmetric broad band in the range 200~400 nm,the reults are convenient with the suggestion of metal-nitrogen and metal-oxygen bonds.The infrared analysis data proved that ATN act as bidentate ligand through the N atom of the-NH group and O atom of the deprotonated alcoholic OH group.Nickel(Ⅱ)and cerium(Ⅲ)complexity make six-coordinate geometry,whereas the barium(Ⅱ)complex exhibit four-coordinate geometry.Ni(Ⅱ)-ATN complex has an effective magnetic moment equal 3.12 B.M,that is assigned to octahedral structure.The 1H-NMR spectral results of Ba(Ⅱ)-ATN complexity give strong signal at^4.00 ppm due to protons of-CH2 that influenced by low degree due to complexity.These results confirm the position of chelation through the N atom of the-NH group and O atom of the deprotonated alcoholic OH group. | Samy M El-Megharbel Tariq Altalhi Abdullah Ayad Salem Alruqi Moamen S Refat | 2020 | 光谱学与光谱分析2020，40，6： | 0 |
| 3 | Synthesis and Spectroscopic Characterizations of the Mono-and Bimolecular Iron(Ⅲ)Complexes by the Interaction With Tris Buffer in Neutralized Media:Biological and Morphological Investigations显示文摘The reaction of iron(Ⅲ)anions,FeCl 3 and Fe 2(SO 4)3 with tris(hydroxymethyl)aminomethane(Tris)in a 1∶2 molar ratio affords the new coordination compounds NH 4[Fe 2(Tris)2(H 2O)4(SO 4)](Ⅰ)and NH 4[Fe(Tris)2(H 2O)2](Ⅱ).These compounds were characterized by elemental analysis,and their molecular structures were determined by spectroscopic methods(infrared and electronic spectra),magnetic susceptibility,and molar conductivity measurements,and further corroborated by thermo gravimetric analysis and its differential(TGA/DrTGA).According to the experimental data,the complexes can be characterized in the solid state as mono-and binuclear,with a distorted octahedral stereochemistry.The distorted octahedral stereochemistry adopted by the complexes was confirmed by the magnetic susceptibility measurement of NH 4[Fe 2(Tris)2(H 2O)4(SO 4)],which consists of a six-coordinate iron atoms in a distorted octahedral environment constructed from four O atoms(two Tris molecules),two O atoms from the loosely associated SO 4 coordinated ligand,and O,N of second Tris molecule with occupying by four oxygen atoms of coordinated water molecules.Regarding,NH 4[Fe(Tris)2(H 2O)2]complex the mono iron atom is surrounded by six oxygen atoms as four by two Tris molecules and two coordinated water molecules in axial form.Antibacterial and anticancer activities of the complexes were studied and the complexes were screened against bacteria,colorectal adenocarcinoma(Caco-2)and breast cancer(Mcf-7)cell lines. | Jehan Y Al-Humaidi Foziah A Al-Saif Dalal N Binj awhar Salha E Alotaibi Moamen S Refat | 2020 | 光谱学与光谱分析2020，40，10： | 0 |
| 4 | Complexity of Gold(Ⅲ)Ion With Cefotaxime and Cefepime Drugs:Spectroscopic,Antimicrobial and Antitumor Discussions显示文摘The availability of chemical and biological data presented in this paper is the basis for understanding not only the current state of anti-cancer drugs based on gold(Ⅲ),but also the rationale for strategies for future drug design.New Au(Ⅲ)nanosized complexes of cefotaxime(ceph-3)and cefepime(ceph-4)ligands as a 3rd and 4th of cephalosporin generation drugs were synthesized.Gold(Ⅲ)complexes were discussed based on the elemental,molar conductance,thermal and magnetic moment measurements as well as spectral(FTIR,1HNMR,UV-Vis,and XRD)techniques.FT-IR spectra revealed that the ceph-3 and ceph-4 ligands reacted as a bidentate ligands through carboxylate oxygen andβ-lactam oxygen groups.The analytical analysis confirm that the molar ratio is 1∶1(Au 3+/ceph)with general formula[Au(L)(Cl)2]where L=ceph-3 or ceph-4.The structures of Au(Ⅲ)complexes were presence as a square planar geometry.X-ray diffraction patterns referred to a crystalline nature for all synthesized complexes.TEM analyses confirmed that the synthetic gold(Ⅲ)complexes have a nanosized particles.In vitro antimicrobial activities of Au(Ⅲ)complexes were evaluated towards two types of bacteria(G+&G-).The antitumor activities of gold(Ⅲ)complexes are appraised against breast(MCF-7)and colorectal adenocarcinoma(Caco-2)cell lines,which means that the two complexes may consider promising anticancer drugs. | Lamia A Albedair Samar O Aljazzar Mohamed I Kobeasy Moamen S Refat | 2020 | 光谱学与光谱分析2020，40，10： | 0 |
| 5 | Spectrophotometric Determination of Albendazole Drug in Tablets: Spectroscopic Characterization of the Chargetransfer Solid Complexes显示文摘为 albendazole (ABZ ) 的决心的简单、快速、可靠的方法被描述。这为 ABZ 药的评价包括象 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ ) 和 3,6-dichloro-2,5-dihy- droxy-p-benzoquinone (p-CLA ) 那样的一些领受人的用途(是行动施主) 。试验性的条件被优化,系统为 7.5080 和 10.0085.00 g 遵守啤酒的法律吗? | Refat Moamen S Mohamed Gehad G. Fathi Ahmed | 2011 | Chinese Journal of Chemistry2011，29，2： | 0 |
| 6 | Investigation of charge transfer complexes formed between 3,3′-dimethylbenzidine (o-toluidine) donor and DDQ, p-chloranil and TCNQ as π-acceptors显示文摘Charge-transfer (CT) complex of o-toluidine (o-tol) with the π-acceptor tetrachloro-p-benzoquinone (p-chloranil; CHL) has been synthesized and characterized, along with the products of the elimination reaction of o-toluidine (o-tol) with 2,3-dichloro-5,6dicyano-p-benzoquinone (DDQ) and 7,7,8,8-tetracyanoquinodimethane (TCNQ). Their properties and structures have been investigated using electronic absorption and IR spectroscopy as well as elemental analyses of the isolated compounds. The o-tol/p-CHL CT complex is shown to consist of a CHL radical anion and o-tol + radical cation. The formations of all three compounds result in the appearance of new UV-Vis spectral bands that peaked in intensity at a stoichiometric ratio of 1 : 1. 1 H-NMR and mass spectra were used to confirm the formation of the o-tol/DDQ and o-tol/TCNQ products. The new 7,8-dicyano-7′,8′-o-toluidilequinodimethane and 2,3-dichloro-5-cyano-6-o-toluidil-p-benzoquinone products resulted from the rapid reaction of o-tol with TCNQ and DDQ, respectively. Thermogravimetric studies showed that the CT-complex decomposes in three steps whereas the new compounds decompose in a single step. Thermodynamic parameters were computed from the thermal decomposition data. | REFAT Moamen S El-METWALLY Nashwa M | 2011 | Chinese Science Bulletin2011，56，19： | 0 |
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