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4篇 您的检索式:作者名="Mingde QIN"
    题名 作者 年代 出处 被引量
1Single-phase high-entropy intermetallic compounds(HEICs): bridging high-entropy alloys and ceramics显示文摘High-entropy intermetallic compounds(HEICs)were fabricated by mechanical alloying and spark plasma sintering to fill a knowledge gap between the traditional high-entropy alloys(HEAs)and emerging highentropy ceramics(HECs).Notably,several four-or five-component equimolar aluminides,such as the B2-phase(Fe1/5 Co1/5 Ni1/5 Mn1/5 Cu1/5)Al,have been made into single-phase HEICs for the first time.Thermodynamic modeling and a reversible,temperature-dependent,phase-stability experiment suggest that such B2-phase HEICs are entropy-stabilized phases.The structure of these HEICs resembles that of HECs with high-entropy mixing of fo ur or five elements of nearly equal fractions in one and only one sublattice,but with significant(10%)anti-site defects(differing from typical HECs).A new phase stability rule for forming single B2-phase HEICs is proposed.Five additional HEICs of predominantly D022 phases have also been made.This study broadens the families of equimola r,single-phase,high-entropy materials that have been successfully fabricated.Naixie Zhou Sicong Jiang Timothy Huang Mingde Qin Tao Hu Jian Luo 2019Science Bulletin2019,64,12:8
2A new class of high-entropy M_(3)B_(4) borides显示文摘A new class of high-entropy M3B4 borides of the Ta_(3)B_(4)-prototyped orthorhombic structure has been synthesized in the bulk form for the first time.Specimens with compositions of(V0.2Cr0.2Nb0.2Mo0.2Ta0.2)3B4 and(V0.2Cr0.2Nb0.2Ta0.2W0.2)_(3)B_(4) were fabricated via reactive spark plasma sintering of high-energy-ball-milled elemental boron and metal precursors.The sintered specimens were〜98.7%in relative densities with virtually no oxide contamination,albeit the presence of minor(4-5 vol%)secondary high-entropy M5B6 phases.Despite that Mo_(3)B_(4) or W_(3)B_(4) are not stable phase,20%of M03B4 and W3B4 can be stabilized into the high-entropy M3B4 borides.Vickers hardness was measured to be 18.6 and 19.8 GPa at a standard load of 9.8 N.This work has further expanded the family of different structures of high-entropy ceramics reported to date.Mingde QIN Qizhang YAN Yi LIU Jian LUO 2021Journal of Advanced Ceramics2021,10,1:4
3Decolorization of methylene blue by heterogeneous Fenton reaction using Fe 3? x Ti x O 4 (0<ce:hsp sp='0.25'/>≤<ce:hsp sp='0.25'/> x <ce:hsp sp='0.25'/>≤<ce:hsp sp='0.25'/>0.78) at neutral pH values显示文摘Shijian Yang Hongping He Daqing Wu Dong Chen Xiaoliang Liang Zonghua Qin Mingde Fan Jianxi Zhu Peng Yuan 2009Applied Catalysis B Environmental2009,,3:1
421-Component compositionally complex ceramics: Discovery of ultrahigh-entropy weberite and fergusonite phases and a pyrochlore–weberite transition显示文摘Two new high-entropy ceramics(HECs)in the weberite and fergusonite structures,along with the unexpected formation of ordered pyrochlore phases with ultrahigh-entropy compositions and an abrupt pyrochlore–weberite transition,are discovered in a 21-component oxide system.While the Gibbs phase rule allows 21 equilibrium phases,9 out of the 13 compositions examined possess single HEC phases(with ultrahigh ideal configurational entropies:~2.7kB per cation or higher on one sublattice in most cases).Notably,(15RE_(1/15))(Nb_(1/2)Ta_(1/2))O_(4) possess a single monoclinic fergusonite(C2/c)phase,and(15RE_(1/15))_(3)(Nb_(1/2)Ta_(1/2))_(1)O_(7) form a single orthorhombic(C222_(1))weberite phase,where 15RE_(1/15) represents Sc_(1/15)Y_(1/15)La_(1/15)Pr_(1/15)Nd_(1/15)Sm_(1/15)Eu_(1/15)Gd_(1/15)Tb_(1/15)Dy_(1/15)Ho_(1/15)Er_(1/15)Tm_(1/15) Yb_(1/15)Lu_(1/15).Moreover,a series of eight(15RE_(1/15))_(2+x)(Ti_(1/4)Zr_(1/4)Ce_(1/4)Hf_(1/4))_(2−2x)(Nb_(1/2)Ta_(1/2))_(x)O_(7) specimens all exhibit single phases,where a pyrochlore–weberite transition occurs within 0.75Mingde QIN Heidy VEGA Dawei ZHANG Sarath ADAPA Andrew J.WRIGHT Renkun CHEN Jian LUO 2022Journal of Advanced Ceramics2022,11,4:1
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