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| 1 | Removal of antibiotics in a parallel-plate thin-film-photocatalytic reactor: Process modeling and evolution of transformation by-products and toxicity显示文摘Photocatalytic degradation of sulfamethoxazole(SMX) antibiotic has been studied under recycling batch and homogeneous flow conditions in a thin-film coated immobilized system namely parallel-plate(PPL) reactor. Experimentally designed, statistically evaluated with a factorial design(FD) approach with intent to provide a mathematical model takes into account the parameters influencing process performance. Initial antibiotic concentration, UV energy level, irradiated surface area, water matrix(ultrapure and secondary treated wastewater) and time, were defined as model parameters. A full of 2~5 experimental design was consisted of 32 random experiments. PPL reactor test experiments were carried out in order to set boundary levels for hydraulic, volumetric and defined defined process parameters. TTIP based thin-film with polyethylene glycol + TiO_2 additives were fabricated according to pre-described methodology. Antibiotic degradation was monitored by High Performance Liquid Chromatography analysis while the degradation products were specified by LC–TOF-MS analysis. Acute toxicity of untreated and treated SMX solutions was tested by standard Daphnia magna method. Based on the obtained mathematical model, the response of the immobilized PC system is described with a polynomial equation. The statistically significant positive effects are initial SMX concentration,process time and the combined effect of both, while combined effect of water matrix and irradiated surface area displays an adverse effect on the rate of antibiotic degradation by photocatalytic oxidation. Process efficiency and the validity of the acquired mathematical model was also verified for levofloxacin and cefaclor antibiotics. Immobilized PC degradation in PPL reactor configuration was found capable of providing reduced effluent toxicity by simultaneous degradation of SMX parent compound and TBPs. | Can Burak?zkal Zacharias Frontistis Maria Antonopoulou Ioannis Konstantinou Dionissios Mantzavinos Süreyya Meric | 2017 | Journal of Environmental Sciences2017，29，10： | 2 |
| 2 | Cotton-supported heterotrophic denitriflcation of nitrate-rich drinking water with a sand filtration posttreatment显示文摘 | DELLA ROCCA C BELGIORNO V MERIC S | 2005 | Water SA2005，31，： | 1 |
| 3 | Heterotrophic/autotrophic deni- trification (HAD) of drinking water: prospective use for permeable reactive barrier 显示文摘 | Rocca C D Belgiorno V Meric S | 2007 | Desalination2007，21，： | 1 |
| 4 | Occurrence patterns of pharmaceuticals in water and wastewater environments 显示文摘 | Nikolski A Meric S Fatta D | 2007 | Anal Bioanal Chem2007，387，4： | 1 |
| 5 | Vegetable and synthetic tannins induce hormesis/toxicity in sea urchin early development and in algal growth 显示文摘 | DE Nicola E MERIC S GALLO M | 2007 | Environmental pollution2007，146，： | 1 |
| 6 | Treatadility of strong wastewaters from polyester manufacturing industry显示文摘 | Meric S Kabdasll I Tttnay O | 1999 | Wat Sci Tech1999，39，1011： | 1 |
| 7 | Local Social Knowledge Man- agement: Community Actors, Institutions and Multilevel Govern- ance in Regional Foresight Exercises 显示文摘 | Meric S Gertler David A Wolfe | 2004 | Futures2004，，36： | 1 |
| 8 | Fenton's oxidation of various- based tanning materials 显示文摘 | Lofrano G Meric S Belgiorno V | 2007 | Desalination2007，2，： | 1 |
| 9 | The primary anomalies of coronary artery origin and course:A coronary angiographic analysis of 16,573patients显示文摘 | Yuksel S Meric M Soylu K | 2013 | Exp Clin Cardiol2013，18，2： | 1 |
| 10 | Investigation of the effect of boronizing on east irons显示文摘 | Sahin S Meric C | 2002 | Mater Res Bull2002，39，： | 1 |
| 11 | The prognostic value of Neuron speci- fic enolase in head trauma patients显示文摘 | Meric E Gunduz A Turedi S | 2010 | J Emerg Med2010，38，3： | 1 |
| 12 | Overview of in-situ applicable nitrate removal processes 显示文摘 | Rocca C D Belgiorno V Meric S | 2007 | Desalination2007，204，： | 1 |
| 13 | Overview of in--situ applicable nitrate removal processes 显示文摘 | Rocca C D Belgiorno V Meric S | 2007 | Desalina- tion2007，204，： | 1 |
| 14 | The prognostic value of neuron-specific enolase in head trauma patients显示文摘 | Meric E Gunduz A Turedi S | 2010 | J Emerg Med2010，38，3： | 1 |
| 15 | Heterotrophic/autotrophic denitrification(HAD)of drinking water:Prospective use for permeable reactive barrier显示文摘 | Rocca C D Belgiorno V Meric S | 2007 | Desalination2007，210，： | 1 |
| 16 | Investigation of the effect of boronizing on cast irons 显示文摘 | SAH1N S MERIC C | 2002 | Materials Research Bulletin2002，37，5： | 1 |
| 17 | Color and COD removal from wastewater containing Reactive Black 5 using Fenton's oxidation process显示文摘 | Meric S Kaptan D Olmez T | | 0，，03： | 1 |
| 18 | Wastewater Toxicity of Tannin-versus Chromium-based Leather Tanncries in Marrakesh,Morocco显示文摘 | Meric S Della Rocca C | 2007 | Archives of Envirortmenttal Contamination and Toxicology2007，53，3： | 1 |
| 19 | Acute toxicity removal in textile finishing wastewater by Fenton's oxidation, ozone and coagula tion-flocculation processes显示文摘 | MERIC S SELCUK H BELGIORNO V | 2005 | Water Research2005，39，： | 1 |
| 20 | The prognostic value of neuron-specific enolase in head trauma patients显示文摘 | Meric E Gunduz A Turedi S | | 0，，03： | 1 |
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