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1篇 您的检索式:作者名="Maxim A.Samsonov"
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1Monophthalocyanine complexes of samarium and terbium with axial ligands:synthesis, structure and optoelectronic properties显示文摘The monophthalocyanine complexes of samarium and terbium containing axial 2-mercaptobenzothiazole(Pc Sm(MBT)(1)), 2-(2-benzoxazol-2-yl) phenolate(Pc Tb(OON)(2)) or 2-(2-benzothiazol-2-yl)phenolate(Pc Tb(SON)(3)) ligands were synthesized and identified by elemental, LDI-TOF and X-ray(for 1) analysis.Photoluminescence(PL) and electroluminescence(EL) spectra of the compounds contained only emission bands of phthalocyanine and axial ligands but did not contain the bands of f-f transitions.It was found that among the complexes 1, 2, 3 the latter had highest photoconductivity(~10–7 S/cm) and photovoltaic properties.An organic photovoltaic device(OPV) of configuration of ITO/3/C60/Alq3/Al revealed open-circuit voltage(VOC) of 0.24 V and short current density(ISC) of 0.3 μA/cm2 under illumination by a xenon lamp at 17 m W/cm2.Alexander A.Maleev Anatoly P.Pushkarev Vasily A.Ilichev Mikhail A.Lopatin Maxim A.Samsonov Georgy K.Fukin Georgy L.Pakhomov Vladislav V.Travkin Ivan D.Grishin Mikhail N.Bochkarev 2014Journal of Rare Earths2014,32,12:1
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