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3篇 您的检索式:作者名="Mangwei Cui"
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1CuS Electrode for All-pH Electrolyte in Aqueous Batteries显示文摘With their excellent safety, affordability, environmental friendliness and high ionic conductivity, aqueous batteries are prospective contenders to replace lithium-ion batteries. However, the pH of aqueous electrolyte might impact the battery’s electrochemical performance and even its normal operation. It is critical to develop an electrode that can work in different pH settings. The hydrothermal method and vulcanization treatment were used to successfully create copper sulfide(CuS) nanosheet in this work. It can store and transport nonmetal and metal ions as well as polyvalent ions with a high charge radius ratio, and function normally under a variety of pH conditions. The CuS electrode has a considerable capacity(900 mA·h/g) and rate performance under alkaline conditions, as well as an ultra-long discharge platform, which contribute to 80% of the total capacity.Liangliang Yang Mangwei Cui Qingjiang Liu Hao Lei Yan Huang 2022Journal of Harbin Institute of Technology(New Series)2022,29,6:0
2Highly uniform Co-Cu bimetallic sulfides for rechargeable alkaline aqueous zinc batteries显示文摘Rechargeable alkaline aqueous zinc batteries(RAZBs)have attracted increasing attention.However,most RAZBs are hindered by the limited availability of cathode materials.The practical electrochemical performance of most cathode materials is lower than the theoretical value due to their poor electrical conductivity and low utilization capacity.In this work,we develop a facile hydrothermal procedure to prepare highly uniform bimetallic sulfides as novel cathode materials for RAZBs.Copper-cobalt binary metallic oxides materials possess higher conductivity and larger capacity compared with their mono-metal oxides compounds due to bimetallic synergistic effects and multiple oxidation states.Furthermore,bimetallic sulfide compounds have smaller bond energy and longer bond length than their oxides,leading to less structural damage,faster kinetics of electrochemical reactions,and better stability.The as-prepared Co-Cu bimetallic sulfides show enhanced electrochemical performance due to various valences of Co and Cu as well as the existence of S.As a result,aqueous Zn/CuCo_(2)S_(4) battery shows a high specific capacity of 117.4 mAh/g at 4 A/g and a good cycle life of over 8000 cycles.Based on PANa hydrogel electrolytes,a flexible Zn/CuCo_(2)S_(4) battery demonstrates excellent cycling stability.This battery can also meet the requirements of electronic devices with different shapes and performs well in extreme environments,such as freezing,drilling,and hammering.This work opens new avenues to obtain high-rate and long-life cathode materials for RAZBs by utilizing the synergistic effects of bimetallic sulfides and provides a new platform for flexible energy storage devices.Xiaofang Bai Yuwei Zhao Mangwei Cui Tianshuo Guo Zijie Tang Chuan Li Heng Gao Shuo Yang Lingzhi Zhao Chunyi Zhi Hongfei Li 2024Chinese Chemical Letters2024,35,2:0
3In-situ oriented oxygen-defect-rich Mn-N-O via nitridation and electrochemical oxidation based on industrial-scale Mn_(2)O_(3) to achieve high-performance aqueous zinc ion battery显示文摘As a general problem in the field of batteries,materials produced on a large industrial scale usually possess unsatisfactory electrochemical performances.Among them,manganese-based aqueous rechargeable zinc-ion batteries(ARZBs)have been emerging as promising large-scale energy storage systems owing to their high energy densities,low manufacturing cost and intrinsic high safety.However,the direct application of industrial-scale Mn2O3(MO)cathode exhibits poor electrochemical performance especially at high current rates.Herein,a highly reversible Mn-based cathode is developed from the industrial-scale MO by nitridation and following electrochemical oxidation,which triples the ion diffusion rate and greatly promotes the charge transfer.Notably,the cathode delivers a capacity of 161 m Ah g^(-1) at a high current density of 10 A g^(-1),nearly-three times the capacity of pristine MO(60 m Ah g^(-1)).Impressive specific capacity(243.4 m Ah g^(-1))is obtained without Mn^(2+) additive added in the electrolyte,much superior to the pristine MO(124.5 m Ah g^(-1)),suggesting its enhanced reaction kinetics and structural stability.In addition,it possesses an outstanding energy output of 368.4 Wh kg^(-1) at 387.8 W kg^(-1),which exceeds many of reported cathodes in ARZBs,providing new opportunities for the large-scale application of highperformance and low-cost ARZBs.Yao Liu Shuailong Guo Wei Ling Mangwei Cui Hao Lei Jiaqi Wang Wenzheng Li Qingjiang Liu Lukuan Cheng Yan Huang 2023Journal of Energy Chemistry2023,,1:0
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