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1篇 您的检索式:作者名="Manchi Nagaraju"
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1In situ deposited cobalt-magnesium selenates as an advanced electrode for electrochemical energy storage显示文摘Currently,bimetallic selenates have attracted much attention as a prominent electrode composite material for supercapacitors owing to their higher redox chemistry and superior electrical conductivity.Herein,we synthesized cobalt-magnesium selenates (CoSeO3-Mg Se O4,CMS) via a facile hydrothermal process,followed by selenization.At first,cobalt-magnesium oxide (Co2.32Mg0.68O4,CMO) was in situ prepared by a one-pot hydrothermal method.An investigation on the morphological change was performed by synthesizing the same CMO samples at different growth times by keeping the temperature constant.The CMO electrode designed for 8 h of growth time (CMO-8 h)with an attractive morphology showed a higher areal capacity of 101.7μAh cm-2(at 3 m A cm-2) than the other CMO electrodes prepared for 6 and 10 h.Further exalted performance was achieved by the selenization of the CMO-8 h sample to form the CMS material.At 3 m A cm-2,the resulted CMS exhibited nearly three times higher capacity,i.e.,385.4μAh cm-2,than the CMO-8 h electrode.Additionally,an asymmetric cell fabricated with CMS as a positive electrode also revealed good energy storage performance.Within the applied voltage between 0 and 1.5 V,the asymmetric cell demonstrated maximum energy density of 0.159 m Wh cm-2(18.6 Wh kg-1) and maximum power density of 18.47 m W cm-2(1938 W kg-1),respectively.Thus,novel magnesium-based metal selenates can act as an efficient electrode for energy storage.Manchi Nagaraju S.Chandra Sekhar Bhimanaboina Ramulu Shaik Junied Arbaz Jae Su Yu 2022Journal of Magnesium and Alloys2022,10,12:0
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