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1篇 您的检索式:作者名="Maksim Grechko"
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1Controlling the electro-optic response of a semiconducting perovskite coupled to a phonon-resonant cavity显示文摘Optical cavities,resonant with vibrational or electronic transitions of material within the cavity,enable control of light-matter interaction.Previous studies have reported cavity-induced modifications of chemical reactivity,fluorescence,phase behavior,and charge transport.Here,we explore the effect of resonant cavity-phonon coupling on the transient photoconductivity in a hybrid organic-inorganic perovskite.To this end,we measure the ultrafast photoconductivity response of perovskite in a tunable Fabry–Pérot terahertz cavity,designed to be transparent for optical excitation.The terahertz-cavity field-phonon interaction causes apparent Rabi splitting between the perovskite phonon mode and the cavity mode.We explore whether the cavity-phonon interaction affects the material’s electron-phonon interaction by determining the charge-carrier mobility through photoconductivity.Despite the apparent hybridization of cavity and phonon modes,we show that the perovskite properties in both ground(phonon response)and excited(photoconductive response)states remain unaffected by the tunable light-matter interaction.Yet the response of the integral perovskite-terahertz optical cavity system depends critically on the interaction strength of the cavity with the phonon:the transient terahertz response to optical excitation can be increased up to threefold by tuning the cavity-perovskite interaction strength.These results enable tunable switches and frequency-controlled induced transparency devices.Lucia Di Virgilio Jaco J.Geuchies Heejae Kim Keno Krewer Hai Wang Maksim Grechko Mischa Bonn 2023Light(Science & Applications)2023,12,9:0
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