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您的检索式：作者名="M.I.Chebanenko"
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| 1 | Morphology,structure and magnetic behavior of orthorhombic and hexagonal HoFeO_(3)synthesized via solution combustion approach显示文摘Nanostructured HoFeO_(3)powders were obtained by solution combustion method at various glycinenitrate ratios(G/N=0.2,0.4,...,1.4).According to X-ray powder diffractometry data,the presence of two modifications of HoFeO_(3)in the synthesized samples was established:orthorhombic(Pbnm)and hexagonal(P63/mmc).The crystallite size of the obtained compositions varies from 62±6 to 29±3 nm,depending on the G/N ratio.From magnetic structure studies,it is found that HoFeO_(3)obtained with a stoichiometric amount of glycine in the reaction solution is in the magnetically ordered state and is represented by a sextet with quadrupole splitting(QS)=0 mm/s,isomeric shift(IS)=0.36 mm/s and effective field strength(Heff)=497 kOe.According to the results of vibrational magnetometry,it is found that the orthoferrites obtained have a ferromagnetic structure,the main parameters of which(Ms,Mr and Hc)systematically change with a change in the redox ratio of the reaction mixture and,as a consequence,their phase composition,and reach maximum values at a G/N ratio=0.6.In the samples obtained with a significant excess and lack of glycine(G/N=0.2 and 1.4),despite their amorphous nature,hysteresis loops characteristic of the ferromagnetic state of the substance is observed.It is hopeful to obtain a pure hexagonal modification of HoFeO_(3)via heat treatment on amorphous products of glycine-nitrate combustion. | K.D.Martinson I.S.Kondrashkova M.I.Chebanenko A.S.Kiselev T.Yu Kiseleva V.I.Popkov | 2022 | Journal of Rare Earths2022，40，2： | 0 |
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