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| 1 | LaO_(x)(OH)_(y) supported platinum catalysts for CO oxidation:Deactivation by formation of lanthanum carbonate显示文摘Platinum catalyst for CO oxidation has been studied for decades,due to its high activity and good stability.In this work,we prepared three different lantha num oxide or hydroxide supports(LaO_(x)(OH)_(y)),and deposited platinum(Pt) with 0.5 at% via an impregnation approach to synthesize Pt/LaO_(x)(OH)_(y) catalysts.However,we find that these catalysts perform a poor stability for the CO oxidation reaction.The fresh and used samples were comprehensively characterized by multiple techniques including power X-ray diffraction(XRD),X-ray absorption fine structure(XAFS),transmission electron microscopy(TEM),temperature-programmed reduction by carbon monoxide(CO-TPR) and thermogravimetric analysis(TGA),to demonstrate that the oxidized platinum atoms or clusters,without any component of Pt-Pt metallic bond,are highly dispersed on the surface of LaO_(x)(OH)_(y).Furthermore,the as-formed lanthanum carbonate(La_(2)O_(2)CO_(3)) during the exposure to ambient circumstances or in the reaction atmosphere of CO+O_(2),severely impair the reactivity of Pt/LaO_(x)(OH)_(y).On the basis of the obtained experimental results,we have drawn a conclusion that the oxidized P_(t)O_(x) atoms or PtxOy clusters are the active species for CO oxidation,while the formation of lanthanum carbonate is the origin of deactivation on reactivity. | Luozhen Jiang Junxiang Chen Rui Si | 2021 | Journal of Rare Earths2021，39，3： | 2 |
| 2 | A multiunitcata-lystwithsynergisticstabilityandreactivity:apolyoxo-metalate-metalorganicframeworkforaerobicdecontami-nation显示文摘 | SongJie LuoZhen BrittDavidK etal | 2011 | Journalofthe American ChemicalSociety2011，133，16： | 1 |
| 3 | StudiesontheReGlationshipbetweenthecrystalformofTiO2anditsphoGtocatalyzingdegradationefficiency显示文摘 | GaoWei WuFengqing LuoZhen etal | 2001 | ChemicalJournalofChineseUniversities2001，22，4： | 1 |
| 4 | Engineering Pt heterogeneous catalysts for accelerated liquid–solid redox conversion in Li-S batteries显示文摘The shuttle effect caused by soluble lithium polysulfides (LiPSs) deteriorates multiphase transformation reaction kinetics of sulfur species,and gives rise to an unserviceable lithium-sulfur (Li-S) battery.Catalysis,as a process optimization approach,offers an option to eliminate the intrinsic issues.However,exploring and understanding the role of catalysts on electrode reaction remains critical bottlenecks,particularly as they are prone to continuous evolution under complex dynamic environment.Herein,platinum nanoparticles loaded on MXene nanosheets,as sulfur host,and the action of catalysts on the reaction process are investigated via ex-situ monitors upon solid–liquid–solid chemical transformation of sulfur species.These traces confirm that the high performance originates from electron transfer between catalysts and LiPSs,which lowers the nucleation barrier from liquid LiPSs to solid Li_(2)S/Li_(2)S_(2).Further,the accelerated liquid–solid conversion can alleviate the accumulation of LiPSs,and boost the reaction kinetics in Li-S batteries.The findings corroborate the electronic modulation between catalysts and LiPSs,which is a generalizable strategy to optimize energy conversion efficiency of Li-S batteries. | Qinhua Gu Yujie Qi Wuxing Hua Tongxin Shang Junnan Chen Luozhen Jiang Lina Li Ming Lu Yixiao Zhang Xi Liu Ying Wan Bingsen Zhang | 2022 | Journal of Energy Chemistry2022，31，6： | 1 |
| 5 | 显示文摘 | LuoZhen(罗震) XuYankian(徐艳莲) LinJinhuo(林金火) | 2012 | 功能材料2012，，43： | 1 |
| 6 | Unequal salt distribution in zhe rootzone increases growth and yield of cot- ton显示文摘 | DONG He zhong KongXiang-qiang LuoZhen et at | 2010 | Europ J Agron2010，，33： | 1 |
| 7 | Ceria supported platinum catalyst for CO oxidation reaction:Importance of metallic active species——Commemorating the 100th anniversary of the birth of Academician Guangxian Xu显示文摘Ceria supported platinum catalyst has now been widely studied due to its excellent activity for CO oxidatio n.However,the electron state of active metal center is still an open question.In this work,a ce ria nanorod support was prepared and platinum(Pt)with 0.9 at%was deposited using an impregnation method to obtain Pt/CeO_(2)catalyst.With the help of'light-off'experiment and temperatureprogrammed reduction under CO(CO-TPR)test,the conclusion is proposed that the process of hydrogen reduction can enhance the activity of CO oxidation reaction for the generation of optimal active Pt site.An innovative near-situ X-ray absorption fine structure(XAFS)technique was used to investigate the chemical state of central Pt atom during the reaction process,clearly demonstrating that the high oxidized state of Pt does harm to the activity for CO oxidation while the relatively reductive Pt exhibits high activity,and the different oxidized state and chemical environment of Pt during every process has been identified.Furthermore,the activity of our Pt/CeO_(2)catalyst is superior to that of most of the previous reports about CO catalytic oxidation by Pt based catalyst.Moreover,the optimal active species(Pt-O_(4))have been identified after hydrogen reduction,which could be a possible key strategy to control the oxidation of Pt. | Luozhen Jiang Xin Tao Li'na Li Wen Xia Rui Si | 2021 | Journal of Rare Earths2021，39，5： | 0 |
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