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7篇 您的检索式:作者名="Luca Basile"
    题名 作者 年代 出处 被引量
1Electrical conductivity of wood biochar monoliths and its dependence on pyrolysis temperature显示文摘Biochar is traditionally used as solid fuel and for soil amendment where its electrical conductivity is largely irrelevant and unexplored.However,electrical conductivity is critical to biochar’s performance in new applications such as supercapacitor energy storage and capacitive deionization of water.In this study,sugar maple and white pine were carbonized via a slow pyrolysis process at 600,800 and 1000°C and conductivities of monolithic biochar samples along the radial direction were measured using the 4-probe method.Biochars were characterized using an elemental analyzer,scanning electron microscopy,X-ray diffraction and Raman spectroscopy.The solid carbon in biochar samples was found to consist primarily of disordered carbon atoms with small graphitic nanocrystallites that grow with increasing temperature.The bulk conductivity of biochar was found to increase with pyrolysis temperature-1 to~1000 S/m for maple and 1 to~350 S/m for pine,which was accompanied by an increase in carbon content-91 to 97 wt%and 90 to 96 wt%for maple and pine,respectively.The skeletal conductivity of biochar samples carbonized at 1000°C is about 3300 S/m and 2300 S/m for maple and pine,respectively(assuming solid carbon is amorphous);both values are above that of amorphous carbon(1250-2000 S/m).This work demonstrated the importance of carbonization and graphitization to electrical conductivity and suggested electron hopping as a likely mechanism for electric conduction in biochar-an amorphous carbon matrix embedded with graphitic nanocrystallites.Randeep Gabhi Luca Basile Donald W.Kirk Mauro Giorcelli Alberto Tagliaferro Charles Q.Jia 2020Biochar2020,2,3:4
2An Ru-based catalytic membrane reactor for dry reforming of methane its catalytic performance compared with tubular packed bed reactors 显示文摘Luca Paturzo Fausto Gallucci Angelo Basile 2003Catalysis Today2003,82,14:1
3759C/T genetic variation of SHT(2C) receptor and elozapine-induced weight gain 显示文摘BASILE VS MASELLIS M DE LUCA V 2002Lancet2002,360,9347:1
4An experimental study of multi-layered composite palladium membrane reactors for partialoxidation of methane to syngas 显示文摘Angelo Basile Luca Paturzo 2001Catalysis Today2001,67,13:1
5759C/T genetic variation of 5HT(2C) receptor and clozapine-induced weight gain显示文摘BASILE VS MASELLIS M DE LUCA V 2002Lancet2002,360,9347:1
6An experimental study of multilayered composite palladium membrane reactors for partial oxidation of methane to syngas显示文摘Angelo Basile Luca Paturzo 2001Catal Today2001,67,:1
7An Ru-based catalytic membrane reactor for dry reforming of methane: Its catalytic performance compared with tubular packed bed reactors 显示文摘Luca Paturzo Fausto Gallucci Angelo Basile 2003Catalysis Today2003,82,1234:1
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