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| 1 | Hydrogen production from ammonia decomposition over Ni/CeO_(2) catalyst:Effect of CeO_(2) morphology显示文摘Ammonia(NH_(3)) decomposition to release CO_x-free hydrogen(H_(2)) over non-noble catalysts has gained increasing attention.In this study,three nanostructured CeO_(2) with different morphologies,viz.rod(R).sphere(Sph),and spindle(Spi),were fabricated and served as supports for Ni/CeO_(2) catalyst.The CeO_(2)supports are different in particle sizes,specific surface area and porosity,resulting in the formation of Ni nanoparticles with distinguished sizes and dispersions.The surface properties of the Ni/CeO_(2) catalysts are not only distinct but also influential,affecting the adsorption and desorption of NH_(3),N_(2),and/or H_(2)molecules.The Ni/CeO_(2)-R catalyst shows superior catalytic activity compared to the other two,owing to its smaller Ni crystallite size and larger BET surface area.The most abundant strong basic sites are observed for Ni/CeO_(2)-Spi catalyst based on its exposed CeO_(2)(110) planes,which facilitates the donation of electrons to the Ni particles,benefiting the associative desorption of N atoms.Thus,Ni/CeO_(2)-Spi shows higher catalytic activity than Ni/CeO_(2)-Sph,despite their almost identical Ni crystallite sizes. | Chongqi Chen Xiaoshuang Fan Chen Zhou Li Lin Yu Luo Chaktong Au Guohui Cai Xiuyun Wang Lilong Jiang | 2023 | Journal of Rare Earths2023，41，7： | 3 |
| 2 | Effect of rare earth on the performance of Ru/MgAl-LDO catalysts for ammonia synthesis显示文摘A series of MgAl-layered double oxides(LDO) doped with different rare-earth elements(Y, La, and Ce)were synthesized by the calcination of Mg-Al layered double hydroxides, and Ru, which were used to prepare ammonia synthesis catalysts. The as-obtained oxides and catalysts were characterized by XRD,TEM, TPD, TPR and XPS to understand their catalytic performances in ammonia synthesis. The H_2-TPR and HRTEM studies reveal that Ru/Y-LDO catalyst possesses more active Ru metal and small particle size.The XPS demonstrates that the electronic interaction between Y and Ru metals is stronger, which can be tentatively explained by most of Y inserted into the hydrotalcites structure. CO_2-TPD demonstrates that Ru/Y-LDO catalyst shows stronger basic site densities than catalysts doped with Ce and La. Higher activity of the Ru/Y-LDO catalyst can be attributed to smaller particle size, more active metal(Ru) and strong Ru-support interaction. | Jun Ni Baoqiang Jing Jianxin Lin Bingyu Lin Ziqi Zhao Lilong Jiang | 2018 | Journal of Rare Earths2018，36，2： | 3 |
| 3 | Improving the ammonia synthesis activity of Ru/CeO_(2) through enhancement of the metal–support interaction显示文摘The metal–support interactions induced by high-temperature hydrogen reduction have a strong influence on the catalytic performance of ceria-supported Ru catalysts. However, the appearance of the strong metal–support interaction leads to covering of the Ru species by Ce suboxides, which is detrimental to the ammonia synthesis reaction that requires metallic species as active sites. In the present work, the interaction between Ru and ceria in the Ru/CeO_(2) catalyst was induced by NaBH_(4) treatment. NaBH_(4) treatment enhanced the fraction of metallic Ru, proportion of Ce^(3+), content of exposed Ru species, and amount of surface oxygen species. As a result, a larger amount of hydrogen species would desorb by the H_(2)-formation pathway and the strength of hydrogen adsorption would be weaker, weakening the inhibition effect of the hydrogen species on ammonia synthesis. In addition, the strong electronic metal–support interaction aids in nitrogen dissociation. Consequently, Ru/CeO_(2) with NaBH_(4) treatment showed higher ammonia synthesis rates than that with only hydrogen reduction. | Chunyan Li Yuying Shi Zecheng Zhang Jun Ni Xiuyun Wang Jianxin Lin Bingyu Lin Lilong Jiang | 2021 | Journal of Energy Chemistry2021，30，9： | 2 |
| 4 | Boosting Efficient Ammonia Synthesis over Atomically Dispersed Co-Based Catalyst via the Modulation of Geometric and Electronic Structures显示文摘Ammonia(NH_(3))synthesis at mild conditions is of great significance,while the significant bottleneck of this process is the activation of N_(2) to realize the desired NH_(3) synthesis performance,which requires deep insight and rational design of active sites at the atomic level.Here,were synthesized atomically dispersed Co-based catalysts with different Co-N coordination numbers(CNs)to explore the coordination-sensitive NH_(3) synthesis reaction for the first time.Our studies showed that Co-based catalysts increased the NH_(3) synthesis rate gradually with a decrease in CN.The Co-N_(2) catalyst exhibited the highest NH_(3) synthesis rate of 85.3 mmol gCo^(−1) h^(−1) at 300℃ and 1 MPa,which outperformed most of the previously reported Co-based catalysts.Various characterizations and theoretical calculations demonstrated that atomically dispersed Co catalyst with low CN could generate more unoccupied Co 3d charges and tetrahedral cobalt(Ⅱ)sites.The unoccupied Co 3d charge,in turn,promoted the electron donation from the Co active center to the antibonding π-orbital(π*)of N_(2) and expedites N_(2) hydrogenation.Furthermore,the Co-N_(2) catalyst with more tetrahedral cobalt(II)sites could effectively facilitate the desorption of N-containing intermediate species(such as*NH_(3) and*N_(2)H_(4))to obtain a high NH_(3) synthesis rate. | Yanliang Zhou Congying Wang Xuanbei Peng Tianhua Zhang Xiuyun Wang Yafei Jiang Haifeng Qi Lirong Zheng Jianxin Lin Lilong Jiang | 2022 | CCS Chemistry2022，4，5： | 1 |
| 5 | Effect of pore-size distribution on Ru/ZSM-5 catalyst for enhanced N2 activation to ammonia via dissociative mechanism显示文摘In the present study,a series of Ru/ZSM-5 catalysts with different pore-size distributions were prepared and investigated for NH3 synthesis.Our studies indicate that Ru/ZSM-5-Mic with micropore structure exhibits superior NH3 synthesis rate,which is much higher than those of Ru/ZSM-5-Mac(with macroporous structure)and Ru/ZSM-5-Mes(with mesoporous structure)catalysts.A series of TPD experiments demonstrate that pore-size distributions play an important role in N2 adsorption and activation over Ru/ZSM-5.Moreover,the addition of La significantly promotes the NH3 synthesis performance over Ru/ZSM-5-Mic.Additionally,in situ DRIFTS studies indicate that the main intermediate species over Ru/ZSM-5-Mic are-NH2,and most of the surface hydrogen species desorb following the H2O-formation pathway. | Jihui Cai Congying Wang Yi Liu Jun Ni Bingyu Lin Xiuyun Wang Jianxin Lin Lilong Jiang | 2020 | Journal of Rare Earths2020，38，8： | 1 |
| 6 | Effect of barium and potassium promoter on Co/CeO_2 catalysts in ammonia synthesis显示文摘The Co/CeO_2 catalysts promoted with Ba or K were prepared to study the effect of promoter on the catalytic performance of ammonia synthesis. The results show that the presence of Ba or K promoter changes the properties of CeO_2-supported Co catalysts including the surface area, the crystallite size and the morphology of CeO_2, the reduction degree of cobalt species and the adsorption performance of hydrogen and nitrogen. As a consequence, the samples promoted with an appropriate amount of Ba show higher ammonia synthesis rates, while the catalysts with high Ba loading or K promoter all exhibit low catalytic activities. | Bingyu Lin Yi Liu Lan Heng Jun Ni Jianxin Lin Lilong Jiang | 2018 | Journal of Rare Earths2018，36，7： | 1 |
| 7 | Target-oriented confinement of Ru-Co nanoparticles inside N-doped carbon spheres via a benzoic acid guided process for high-efficient low-temperature ammonia synthesis显示文摘Ru-based heterogeneous catalysts have been used in a wide range of important reactions.However,due to the sintering of Ru nanoparticles their practical applications are somewhat restricted.Herein,for the first time we report a new and facile strategy to confine Ru and/or Co nanoparticles(NPs) in the channels of N-doped carbon using benzoic acid to guide the deposition location of Ru.The developed catalyst with confined RuCo alloy particles exhibits high resistance against Ru sintering and displays excellent activity and long term stability for NH3 synthesis,achieving an NH3 synthesis rate of up to 18.9 mmol NH_(3) gcat^(-1)h^(-1)at 400℃,which is ca.2.25 times that of the catalyst prepared without confinement(with metal deposited on the support surface).In the latter case,there is an increase of nanoparticle size from 2.52 to 4.25 nm together with ca.48% decrease of NH_(3) synthesis rate after 68 h at 400℃.This study provides a new avenue for simple fabrication of precious-metal-based catalysts that are highly resistant against sintering,specifically suitable for low-temperature synthesis of ammonia with outstanding efficiency. | Jun Ni Zhenni Tan Qianjin Sai Jie Zhu Xiuyun Wang Bingyu Lin Jianxin Lin Chak-tong Au Lilong Jiang | 2021 | Journal of Energy Chemistry2021，30，6： | 0 |
| 8 | Reprogramming somatic cells to cells with neuronal characteristics by defined medium both in vitro and in vivo显示文摘Background:Currently,direct conversion from somatic cells to neurons requires virus-mediated delivery of at least one transcriptional factor or a combination of several small-molecule compounds.Delivery of transcriptional factors may affect genome stability,while small-molecule compounds may require more evaluations when applied in vivo.Thus,a defined medium with only conventional growth factors or additives for cell culture is desirable for inducing neuronal trans-differentiation.Results:Here,we report that a defined medium(5C)consisting of basic fibroblast growth factor(bFGF),N2 supplement,leukemia inhibitory factor,vitamin C(Vc),andβ-mercaptoethanol(βMe)induces the direct conversion of somatic cells to cells with neuronal characteristics.Application of 5C medium converted mouse embryonic fibroblasts(MEFs)into TuJ+neuronal-like cells,which were capable of survival after being transplanted into the mouse brain.The same 5C medium could convert primary rat astrocytes into neuronal-like cells with mature electrophysiology characteristics in vitro and facilitated the recovery of brain injury,possibly by inducing similar conversions,when infused into the mouse brain in vivo.Crucially,5C medium could also induce neuronal characteristics in several human cell types.Conclusions:In summary,this 5C medium not only provides a means to derive cells with neuronal characteristics without viral transfection in vitro but might also be useful to produce neurons in vivo for neurodegenerative disease treatment. | Songwei He Yiping Guo Yixin Zhang Yuan Li Chengqian Feng Xiang Li Lilong Lin Lin Guo Haitao Wang Chunhua Liu Yi Zheng Chuanming Luo Qiang Liu Fuhui Wang Hao Sun Lining Liang Lingyu Li Huanxing Su Jiekai Chen Duanqing Pei Hui Zheng | 2015 | Cell Regeneration2015，4，1： | 0 |
| 9 | Facile Synthesis and High-Value Utilization of Ammonia显示文摘Ammonia is a key component in fertilizer and the carbon-free hydrogen carrier.Catalytic ammonia synthesis and utilization have played a central role in the development of chemical engineering.The industrial production of ammonia remains dependent on the energy-and carbon-intensive Haber-Bosch process.A major effort has been devoted to developing robust and efficient catalysts,as well as alternative benign processes.Herein,we detail our endeavors that develop the ammonia synthesis and decomposition catalysts,and utilize the ammonia energy.We firstly discuss the catalysts for ammonia synthesis via dissociative and associative process,and the regulation of catalysts'properties.Then,we review the burgeoning electrocata-lytic nitrogen reduction process,focusing on the enhanced catalytic performances by the regulation of the catalysts and the electrode.Additionally,we provide a novel high-value utilization of ammonia to achieve the'zero-carbon'circular economy.The promising catalysts,reactors,and ammonia energy systems have been discussed in detail.We end this Account that offers future research directions and prospects of ammonia. | Yu Luo Shijing Liang Xiuyun Wang Bingyu Lin Chongqi Chen Lilong Jiang | 2022 | Chinese Journal of Chemistry2022，40，8： | 0 |
| 10 | DEVELOPMENT OF AN AUTOMATIC WEIGHING PLATFORM FOR MONITORING BODYWEIGHT OF BROILER CHICKENS IN COMMERCIAL PRODUCTION显示文摘Bodyweight is a key indicator of broiler production as it measures the production efficiency and indicates the health of a flock.Currently,broiler weight(i.e.,bodyweight)is primarily weighed manually,which is timeconsuming and labor-intensive,and tends to create stress in birds.This study aimed to develop an automatic and stress-free weighing platform for monitoring the weight of floor-reared broiler chickens in commercial production.The developed system consists of a weighing platform,a real-time communication terminal,computer software and a smart phone applet userinterface.The system collected weight data of chickens on the weighing platform at intervals of 6 s,followed by filtering of outliers and repeating readings.The performance and stability of this system was systematically evaluated under commercial production conditions.With the adoption of data preprocessing protocol,the average error of the new automatic weighing system was only 10.3 g,with an average accuracy 99.5%with the standard deviation of 2.3%.Further regression analysis showed a strong agreement between estimated weight and the standard weight obtained by the established live-bird sales system.The variance(an indicator of flock uniformity)of broiler weight estimated using automatic weighing platforms was in accordance with the standard weight.The weighing system demonstrated superior stability for different growth stages,rearing seasons,growth rate types(medium-and slow-growing chickens)and sexes.The system is applicable for daily weight monitoring in floor-reared broiler houses to improve feeding management,growth monitoring and finishing day prediction.Its application in commercial farms would improve the sustainability of poultry industry. | Danni ZHOU Yi ZHOU Pengguang HE Lin YU Jinming PAN Lilong CHAI Hongjian LIN | 2023 | Frontiers of Agricultural Science and Engineering2023，10，3： | 0 |
| 11 | Highly efficient subnanometer Ru-based catalyst for ammonia synthesis via an associative mechanism显示文摘The industrial manufacture of ammonia(NH_(3))using Fe-based catalyst works under rigorous conditions.For the goal of carbon-neutrality,it is highly desired to develop advanced catalyst for NH_(3)synthesis at mild conditions to reduce energy consumption and CO_(2)emissions.However,the main challenge of NH_(3)synthesis at mild conditions lies in the dissociation of steady N≡N triple bond.In this work,we report the design of subnanometer Ru clusters(0.8 nm)anchored on the hollow N-doped carbon spheres catalyst(Ru-SNCs),which effectively promotes the NH_(3)synthesis at mild conditions via an associative route.The NH_(3)synthesis rate over Ru-SNCs(0.49%(mass)Ru)reaches up to 11.7 mmol NH_(3)·(g cat)^(-1)·h^(-1) at 400℃ and 3 MPa,which is superior to that of 8.3 mmol NH_(3)·(g cat)^(-1)·h^(-1) over Ru nanoparticle catalyst(1.20%(mass)Ru).Various characterizations show that the N_(2)H_(4)species are the main intermediates for NH_(3)synthesis on Ru-SNCs catalyst.It demonstrates that Ru-SNCs catalyst can follow an associative route for N_(2)activation,which circumvents the direct dissociation of N_(2)and results in highly efficient NH_(3)synthesis at mild conditions. | Yanliang Zhou Qianjin Sai Zhenni Tan Congying Wang Xiuyun Wang Bingyu Lin Jun Ni Jianxin Lin Lilong Jiang | 2022 | Chinese Journal of Chemical Engineering2022，35，3： | 0 |
| 12 | Zirconia prepared from UIO-66 as a support of Ru catalyst for ammonia synthesis显示文摘The development of effective Ru catalyst for ammonia synthesis is of important practical value and scientific significance because of the wide application of ammonia as a fertilizer and its promising applications in the renewable energy.Generally,ZrO_(2) was regarded as an inferior support for Ru catalyst used in ammonia synthesis.Here we prepare ZrO_(2) with monoclinic phase and carbon species from ZrCl_(4) following the preparation route of UiO-66 as well as ammonia treatment.Owing to the presence of a larger amount of hydrogen adsorption as well as the easier desorption of hydrogen species,the ill effect of hydrogen species on the nitrogen adsorption-desorption and ammonia synthesis can be effectively alleviated.The resulting ZrO_(2)-supported Ru catalyst showed 4 times higher ammonia synthesis activity than the conventional Ru/ZrO_(2) obtained from zirconium nitrate. | Chuanfeng Zhang Siyu Shi Biyun Fang Jun Ni Jianxin Lin Xiuyun Wang Bingyu Lin Lilong Jiang | 2023 | Chinese Chemical Letters2023，34，1： | 0 |
| 13 | GraphCWGAN-GP:A Novel Data Augmenting Approach for Imbalanced Encrypted Traffic Classification显示文摘Encrypted traffic classification has become a hot issue in network security research.The class imbalance problem of traffic samples often causes the deterioration of Machine Learning based classifier performance.Although the Generative Adversarial Network(GAN)method can generate new samples by learning the feature distribution of the original samples,it is confronted with the problems of unstable training andmode collapse.To this end,a novel data augmenting approach called Graph CWGAN-GP is proposed in this paper.The traffic data is first converted into grayscale images as the input for the proposed model.Then,the minority class data is augmented with our proposed model,which is built by introducing conditional constraints and a new distance metric in typical GAN.Finally,the classical deep learning model is adopted as a classifier to classify datasets augmented by the Condition GAN(CGAN),Wasserstein GAN-Gradient Penalty(WGAN-GP)and Graph CWGAN-GP,respectively.Compared with the state-of-the-art GAN methods,the Graph CWGAN-GP cannot only control the modes of the data to be generated,but also overcome the problem of unstable training and generate more realistic and diverse samples.The experimental results show that the classification precision,recall and F1-Score of theminority class in the balanced dataset augmented in this paper have improved by more than 2.37%,3.39% and 4.57%,respectively. | Jiangtao Zhai Peng Lin Yongfu Cui Lilong Xu Ming Liu | 2023 | Computer Modeling in Engineering & Sciences2023，，8： | 0 |
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