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1篇 您的检索式:作者名="L.Pihlgren"
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1EXAFS study of cation reordering in NaYF_4:Yb^(3+),Tb^(3+) up-conversion luminescence materials显示文摘The NaYF4:Yb3+,Tb3+(xYb: 0.20, xTb: 0.04) materials were prepared using the co-precipitation method. The as-prepared material was washed either with or without water in addition to ethanol and thereafter annealed for 5 h at 500 °C. This resulted in materials with moderate or very high up-converson luminescence intensity, respectively. The structural study carried out with X-ray powder diffraction revealed microstrains in the rare earth(R) sublattice that were relaxed for the material with very high up-conversion intensity thus decreasing energy losses. The local structural details were investigated with R LIII and Y K edge extended X-ray absorption fine structure(EXAFS) using synchrotron radiation. Around 10 mol.% of the Yb3+ ions were found to occupy the Na site in the material with very high up-conversion intensity. These Yb species formed clusters with the Tb3+ ions occupying the regular Na/R sites. Such clustering enhanced the energy transfer between Yb3+ and Tb3+ thus intensifying the up-conversion emission.H.F.Brito J.Hls T.Laamanen T.Laihinen M.Lastusaari L.Pihlgren L.C.V.Rodrigues T.Soukka 2014Journal of Rare Earths2014,32,3:1
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