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| 1 | Efficient catalytic conversion of jatropha oil to high grade biofuel on Ni-Mo_(2)C/MCM-41 catalysts with tuned surface properties显示文摘The activity of Mo_(2) C-based catalyst on vegetable oil conversion into biofuel could be greatedly promoted by tuning the carbon content,while its modification mechanism on the surface properties remained elusive.Herein,the exposed active sites,the particle size and Lewis acid amount of Ni-Mo_(2) C/MCM-41 catalysts were regulated by varying CH_(4) content in carbonization gas.The activity of Ni-Mo_(2) C/MCM-41 catalysts in jatropha oil(JO)conversion showed a volcano-like trend over the catalysts with increasing CH_(4) content from 15%to 50%in the preparation process.The one prepared by 25%CH_(4) content(NiMo_(2) C(25)/MCM-41)exhibited the outstanding catalytic performance with 83.9 wt%biofuel yield and95.2%C_(15)-C_(18) selectivity.Such a variation of activity was ascribed to the most exposed active sites,the smallest particle size,and the lowest Lewis acid amount from Ni^(0) on the Ni-Mo_(2) C(25)/MCM-41 catalyst surface.Moreover,the Ni-Mo_(2) C(25)/MCM-41 catalyst could also effectively catalyze the conversion of crude waste cooking oil(WCO)into green diesel.This study offers an effective strategy to improve catalytic performance of molybdenum carbide catalyst on vegetable oil conversion. | Xiangze Du Keyao Zhou Linyuan Zhou Xiaomei Lei Huiru Yang Dan Li Changwei Hu | 2021 | Journal of Energy Chemistry2021，30，10： | 2 |
| 2 | Recent progress in the thermal treatment of oilseeds and oil oxidative stability:A review显示文摘Oxidative deterioration of vegetable oils is of great importance in the food industry.In China,vegetable oils produced via thermal pretreatment are popular owing to their strong oil flavor and enhanced yield.Here,we review:(i)the currently employed thermal treatment methods of oilseeds before oil extraction;(ii)effects of thermal treatments on the physicochemical properties,contents of minor lipid components,and oxidative stability of vegetable oils;and(iii)Maillard model systems that are related to oil and oilseed chemistry.Among the thermal pretreatment technologies,microwave and infrared radiations are promising,but these are not performed on the same large production scales as roasting.For most oilseeds,thermal treatments increase the yield of extracted oil and content of minor lipid compounds in the oil,such as polyphenols,tocopherols,and phytosterols.In addition,some Maillard reaction products(MRPs)generated by heating oilseeds have been extracted.The presence of both minor lipids and MRPs in the oil confers improved oxidative stability.However,the mechanism or relationship between thermal treatment and oxidative stability is yet to be clearly elucidated because vegetable oil oxidation is dependent on variables such as unsaturation,concentration and types of minor lipid components,MRPs,and the potential synergistic effects of these components.Recently,several Maillard reaction models related to thermally treated oilseeds have been established,suggesting that MRPs play a critical role during oxidation.However,comprehensive identification of antioxidants and the mechanism by which they inhibit oxidation are lacking.Future research can be performed to establish models that would help elucidate the antioxidative mechanisms of MRPs for more oilseeds.Using these models,it will be possible to predict the oil quality after processing,based on the presence of MRPs and oil chemistry. | Zizhe Cai Keyao Li Wan Jun Lee Martin T J Reaney Ning Zhang Yong Wang | 2021 | Fundamental Research2021，1，6： | 1 |
| 3 | Multi-dimensional multiplexing optical secret sharing framework with cascaded liquid crystal holograms显示文摘Secret sharing is a promising technology for information encryption by splitting the secret information into different shares.However,the traditional scheme suffers from information leakage in decryption process since the amount of available information channels is limited.Herein,we propose and demonstrate an optical secret sharing framework based on the multi-dimensional multiplexing liquid crystal(LC)holograms.The LC holograms are used as spatially separated shares to carry secret images.The polarization of the incident light and the distance between different shares are served as secret keys,which can significantly improve the information security and capacity.Besides,the decryption condition is also restricted by the applied external voltage due to the variant diffraction efficiency,which further increases the information security.In implementation,an artificial neural network(ANN)model is developed to carefully design the phase distribution of each LC hologram.With the advantage of high security,high capacity and simple configuration,our optical secret sharing framework has great potentials in optical encryption and dynamic holographic display. | Keyao Li Yiming Wang Dapu Pi Baoli Li Haitao Luan Xinyuan Fang Peng Chen Yanqing Lu Min Gu | 2024 | Opto-Electronic Advances2024，7，1： | 0 |
| 4 | Climate Services for Water Resource Management in China: The Case Study of Danjiangkou Reservoir显示文摘The efficiencies and effectiveness of water resource management are inextricably linked to climate services. This study demonstrates a climate information service for Danjiangkou Reservoir, which is the largest artificial lake in Asia, facing mounting challenges for flood control, water storage, and water diversion. Unlike traditional water resource management on the basis of short-term weather forecast and runoff monitoring, subseasonal to seasonal(S2S)and annual climate predictions as well as long-term climate change projections were well used to support the decision makers in Danjiangkou Reservoir. The National Climate Center(NCC) has projected the changes of future climate and extreme events by dynamically downscaling the Coupled Model Intercomparison Project phase 5(CMIP5)projections to 25-km resolution for the long-term planning of water resource management in Danjiangkou Reservoir.Real-time climate predictions based on climate models and downscaling interpretation and application methods at different timescales were also provided to meet the specific needs of earlier predictions and spatial refinement for the short-term diversion of the reservoir. Our results show that such climate services facilitated the Diversion Center of Danjiangkou Reservoir(DCDR) to reasonably control the operational water level, increased the ecological water supply to the northern portion of China by 844 million m^(3), and reduced as much as 1.67 billion m^(3) of abandoned water in 2019. In the future, it is necessary to develop climate prediction methods to increase spatial and temporal resolutions and prediction skills, and enhance interactions between providers and users. | Yujie WANG Xiang LI Song LIU Zhenyu HAN Lianchun SONG Zongjian KE Keyao CHEN | 2021 | Journal of Meteorological Research2021，35，1： | 0 |
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