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| 1 | 硫酸溶液中1,1′-硫代羰基二咪唑在碳钢上的吸附及缓蚀影响和碘离子的增强效应(英文)显示文摘The inhibition effect of 1,1′-thiocarbonyldiimidazole (TCDI) on the corrosion behaviors of mild steel (MS) in 0.5 mol·L-1 H2SO4 solution was studied with the help of potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and linear polarization resistance (LPR) techniques. The effect of immersion time on the inhibition effect of TCDI was also investigated over 72 h. For the long-term tests, hydrogen evolution with immersion time (VH2-t) was measured in addition to the three techniques already mentioned. The thermodynamic parameters, such as adsorption equilibrium constant (Kads) and adsorption free energy (△Gads) values, were calculated and discussed. To clarify inhibition mechanism, the synergistic effect of iodide ion was also investigated. The potential of zero charge (PZC) of the MS was studied by electrochemical impedance spectroscopy method, and a mechanism of adsorption process was proposed. It was demonstrated that inhibition efficiency increased with the increase in TCDI concentration and synergistically increased in the presence of KI. The inhibition efficiency was discussed in terms of adsorption of inhibitor molecules on the metal surface and protective film formation. | SOLMAZ R MERT M. E KARDA■ G YAZICI B ERBL M | 2008 | 物理化学学报2008，24，7： | 4 |
| 2 | Adsorption and corrosion inhibition effect of 2-((5-mercapto-l,3,4-thiadiazol-2-ylimino) methyl) phenol Schiff base on mild steel 显示文摘 | SOLMAZ R ALTUNBAS E KARDAS G | 2011 | Materials Chemistry and Physics2011，125，： | 1 |
| 3 | Adsorption and corrosion inhibition effect of 2-((5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl)phenol Schiffbase on mild steel显示文摘 | SOLMAZ R ALTUNBAS E KARDAS G | | 0，，： | 1 |
| 4 | The corrosion performance of polyaniline on nickel plated mild steel显示文摘 | Ozyllmaz A T Kardas G Erbil M | 2005 | Applide Surface Science2005，242，： | 1 |
| 5 | Effect of deramciclane,a new 5-HT receptor antagonist on cholecystokinin-induced changes in rat gastrointestinal function显示文摘 | Varga G Kardas K Barghardt B | 1999 | Eur J Pharmacol1999，367，23： | 1 |
| 6 | Electrochemical deposition and characterization of NiFe coatings as electrocatalytic materials for alkaline water electrolysis 显示文摘 | SOLMAZ R KARDAS G | 2009 | Electrochimica Acta2009，54，14： | 1 |
| 7 | Investigation of adsorp- tion and inhibitive effect of 2 - mercaptothiazoline on corro- sion of mild steel in hydrochloric acid media 显示文摘 | Solmaz R Kardas G Culha M | 2008 | Electro- chim Acta2008，53，： | 1 |
| 8 | Investigation of adsorption and inhibitive effect of 2-mercaptothiazoline on corrosion of mild steel in hydrochloric acid media 显示文摘 | SOLMAZA R KARDAS G CULHA M YAZICI B ERBIL M | 2008 | ElectrochimicaActa2008，53，： | 1 |
| 9 | Copper/polypyrrole multilayer coating for 7075 aluminum alloy protection显示文摘 | MERT B D SOLMAZ R KARDAS G | 2011 | Progress in Organic Coatings2011，72，4： | 1 |
| 10 | Hydrogen evolution and corrosion performance of NiZn coatings 显示文摘 | SOLMAZ R KARDAS G | 2007 | Energy Conversion and Management2007，48，2： | 1 |
| 11 | Adsorption and corrosion inhibitive properties of 2-amino-5-mercapto-1,3,4-thiadiazole on mild steel in hydrochloric acid media显示文摘 | Solmaz R Karda G | 2008 | Colloids and Surface2008，312，1： | 1 |
| 12 | Copper/Poly- pyrrole Multilayer Coating for 7075 Aluminum Alloy Protec- tion 显示文摘 | MERT B D SOLMAZ R KARDAS G | 2011 | Progress in Organic Coatings2011，72，： | 1 |
| 13 | Electrochemical and Quantum Chemical Studies of 2-amino-4-methyl-thia- zole as Corrosion Inhibitor for Mild Steel in HCl Solution显示文摘 | YUCE A O MERT B D KARDAS G | 2014 | Corrosion Science2014，83，： | 1 |
| 14 | Adsolltion and Cor- rosion Inhibition Effect of 2-( ( 5-mercapto-I , 3,4-thiadi- azol-2-ylimino) methyl) phenol Schiff Base on Mild Steel 显示文摘 | SOLMAZ R ALTUNBA E KARDAS G | 2011 | Materials Chemistry and Physics2011，125，： | 1 |
| 15 | Investigation of Inhi- bition Effect of Rhodanine-N-acetic Acid on Mild Steel Cor- rosion in HCI Solution 显示文摘 | YI3CE A O SOLMAZ R KARDAS G | 2012 | Materials Chemistry and Phys- ics2012，131，3： | 1 |
| 16 | The corrosion performance ofpolyaniline on nickel plated mild steel 显示文摘 | OZYILMAZ A T KARDAS G ERBIL M | 2005 | Applied Surface Science2005，242，12： | 1 |
| 17 | Copper/Poly- pyrrole Multilayer Coating for 7075 Aluminum Alloy Protec- tion 显示文摘 | MERT B D SOLMAZ R KARDAS G | 2011 | Progress in Organic Coatings2011，72，： | 1 |
| 18 | Adsorption and corrosion inhibitive properties of 2-amino-5-mercapto-1,3,4-thiadiazole on mild steel in hydrochloric acid media显示文摘 | Solmaz R Karda G Yaz c B | 2008 | Colloid Surface A-Physicochem Eng Aspects2008，312，1： | 1 |
| 19 | Adsorption properties of barbiturates as green corrosion inhibitors on mild steel in phosphoric acid 显示文摘 | Ozcan M Solmaz R Kardas G | 2008 | Colloid Surf2008，325，2： | 1 |
| 20 | Preparation characterization and application of alkaline leached CuNiZn ternary coatings for long-term electrolysis in alkaline solution显示文摘 | Solmaz R D?ner A Karda? G | 2010 | International Journal of Hydrogen Energy2010，35，10： | 1 |
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