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3篇 您的检索式:作者名="Jinhang Fan"
    题名 作者 年代 出处 被引量
1Hydrothermal preparation and electrochemical sensing properties of TiO2-graphene nanocomposite 显示文摘FAN Yang LU Halting LIU Jinhang 2011Colloids and Surfaces B : Biointerfaces2011,83,1:1
2Metallic phase W_(0.9)Mo_(0.1)S_(2)for high-performance anode of sodium ion batteries through suppressing the dissolution of polysulfides显示文摘WS_(2)with layered graphite-like structure as anode for sodium ion batteries has high specific capacity.However,the poor cycling performance and rate capability of WS_(2)caused by the low electronic conductivity and structure changes during cycles inhibit its practical application.Herein,metallic phase(1T)W_(x)Mo_(1−x)S2(x=1,0.9,0.8 and 0.6)with high electronic conductivity and expanded interlayer spacing of 0.95 nm was directly prepared via a simple hydrothermal method.Specially,1T W_(0.9)Mo_(0.1)S_(2)as anode for sodium ion batteries displays high capacities of 411 mAh g^(-1)at 0.1 A g^(-1)after 180 cycles and 262 mAh g^(-1)at 1 A g^(-1)after 280 cycles and excellent rate capability(245 mAh g^(-1)at 5 A g^(-1)).The full cell based on Na_(3)V_(2)(PO_(4))_(2)O_(2)F/C cathode and 1T W_(0.9)Mo_(0.1)S_(2)anode also exhibits high capacity and good cycling performance.The irreversible electrochemical reaction of 1T W_(0.9)Mo_(0.1)S_(2)with Na ions during first few cycles results in the main products of W-Mo alloy and S.The strong adsorption of W-Mo alloy with polysulfides can effectively suppress the dissolution and shuttle effect of polysulfides,which ensures the excellent cycling performance of 1T W_(0.9)Mo_(0.1)S_(2).Huachao Tao Jing Li Jinhang Li Zhenhua Hou Xuelin Yang Li-Zhen Fan 2022Journal of Energy Chemistry2022,31,3:1
3Eliminating carbon contamination with improved one-step electrochemical preparation of refractory high-entropy alloy TiZrHfNbTa显示文摘Creating refractory high-entropy alloys(RHEAs)effectively without impurities is a momentous challenge.Conventional methods for the preparation of RHEAs have exacting requirements for raw material purity and energy consumption.Molten salt electrolytic oxides are applied to the preparation of HEAs by virtue of their low cost and high efficiency.However,the use of graphite anodes in electrolysis will result in the carbon contamination of the products due to the deposition of CO_(3)^(2−)at the cathode.Increasing the reaction temperature accelerates the deoxidation of the oxide,thus reducing the amount of carbide but not eliminating it.Switching HfH_(2)instead of HfO_(2)and using Nb_(2)O_(5)to shield the precursor can effectively remove carbon contamination.However,this leads to a complicated preparation process and energy waste.Herein,we use the solid oxygen ion-conducting membrane(SOM)containing graphite and Sn(named as SOM@C/Sn)anode to separate the carbon from the molten salt and prevent the circulation of CO_(3)^(2−).The pure single-phase TiZrHfNbTa RHEA can be produced in only one-step with the SOM@C/Sn anode,which completely solves the problem of carbon contamination in the molten salt electrolysis preparation of HEAs.This work provides a feasible solution for the preparation of novel complex alloys such as carbon-free RHEAs in a low-cost short process.Peng Li Jinhang Fan Kaifa Du Peilin Wang Ao Liu Huayi Yin Dihua Wang 2023Journal of Materials Science & Technology2023,,32:0
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