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| 1 | Lithospheric structure and faulting characteristics of the Helan Mountains and Yinchuan Basin: Results of deep seismic reflection profiling显示文摘The Helan Mountains and Yinchuan Basin(HM-YB) are located at the northern end of the North-South tectonic belt,and form an intraplate tectonic deformation zone in the western margin of the North China Craton(NCC).The HM-YB has a complicated history of formation and evolution,and is tectonically active at the present day.It has played a dominant role in the complex geological structure and modern earthquake activities of the region.A 135-km-long deep seismic reflection profile across the HM-YB was acquired in early 2014,which provides detailed information of the lithospheric structure and faulting characteristics from near-surface to various depths in the region.The results show that the Moho gradually deepens from east to west in the depth range of 40-48 km along the profile.Significant differences are present in the crustal structure of different tectonic units,including in the distribution of seismic velocities,depths of intra-crustal discontinuities and undulation pattern of the Moho.The deep seismic reflection profile further reveals distinct structural characteristics on the opposite sides of the Helan Mountains.To the east,The Yellow River fault,the eastern piedmont fault of the Helan Mountains,as well as multiple buried faults within the Yinchuan Basin are all normal faults and still active since the Quaternary.These faults have controlled the Cenozoic sedimentation of the basin,and display a 'negative-flower' structure in the profile.To the west,the Bayanhaote fault and the western piedmont fault of the Helan Mountains are east-dipping thrust faults,which caused folding,thrusting,and structural deformation in the Mesozoic stratum of the Helan Mountains uplift zone.A deep-penetrating fault is identified in the western side of the Yinchuan Basin.It has a steep inclination cutting through the middle-lower crust and the Moho,and may be connected to the two groups of faults in the upper crust.This set of deep and shallow fault system consists of both strike-slip,thrust,and normal faults formed over different eras,and provides the key tectonic conditions for the basin-mountains coupling,crustal deformation and crust-mantle interactions in the region.The other important phenomenon revealed from the results of deep seismic reflection profiling is the presence of a strong upper mantle reflection(UMR) at a depth of 82-92 km beneath the HM-YB,indicating the existence of a rapid velocity variation or a velocity discontinuity in that depth range.This is possibly a sign of vertical structural inhomogeneity in the upper mantle of the region.The seismic results presented here provide new clues and observational bases for further study of the deep structure,structural differences among various blocks and the tectonic relationship between deep and shallow processes in the western NCC. | LIU BaoJin FENG ShaoYing JI JiFa WANG ShuaiJun ZHANG JianShi YUAN HongKe YANG GuoJun | 2017 | Science China Earth Sciences2017，60，3： | 11 |
| 2 | Rational Design of Electrocatalyst with Abundant Co/MoN Heterogeneous Domains for Accelerating Hydrogen Evolution Reaction显示文摘Developing efficient and durable electrocatalysts for water splitting, which has long been regarded as one of the most promising patterns to produce green hydrogen, is of great significance but still challenging. Herein,ample Co/MoN heterogeneous domains/nitrogen-doped carbon(Co/MoN/NC) nanosheet arrays as high-performance hydrogen evolution reaction(HER) electrocatalyst via a typical nitriding-carbonization strategy are successfully prepared on nickel foam(NF), which exhibits a low overpotential of 29 m V at 10 m A cm, together with excellent durability at 20 m A cmfor 90 h in alkaline solution. Such excellent catalytic property for HER can be attributed to the generation of abundant Co/Mo N heterogeneous structures. Additionally, the high conductivity of Co/Mo N and NC also increases the charge transfer rate, further helping accelerate the reaction rate of HER. This work presents an efficient method for improving the catalytic hydrogen evolution activity in basic solution. | Yu Qiu Jinzheng Liu Mengxiao Sun Jifa Yang Junzhe Liu Xiaoyan Zhang Xuejun Liu Lixue Zhang | 2022 | Chinese Journal of Structural Chemistry2022，41，7： | 0 |
| 3 | Strong metal–support interaction boosts the electrocatalytic hydrogen evolution capability of Ru nanoparticles supported on titanium nitride显示文摘Ruthenium(Ru)has been regarded as one of the most promising alternatives to substitute Pt for catalyzing alkaline hydrogen evolution reaction(HER),owing to its inherent high activity and being the cheapest platinum-group metal.Herein,based on the idea of strong metal–support interaction(SMSI)regulation,Ru/TiN catalysts with different degrees of TiN overlayer over Ru nanoparticles were fabricated,which were applied to the alkaline electrolytic water.Characterizations reveal that the TiN overlayer would gradually encapsulate the Ru nanoparticles and induce more electron transfer from Ru nanoparticles to TiN support by the Ru–N–Ti bond as the SMSI degree increased.Further study shows that the exposed Ru–TiN interfaces greatly promote the H_(2) desorption capacity.Thus,the Ru/TiN-300 with a moderate SMSI degree exhibits excellent HER performance,with an overpotential of 38 mV at 10 mA cm^(−2).Also,due to the encapsulation role of TiN overlayer on Ru nanoparticles,it displays super long-term stability with a very slight potential change after 24 h.This study provides a deep insight into the influence of the SMSI effect between Ru and TiN on HER and offers a novel approach for preparing efficient and stable HER electrocatalysts through SMSI engineering. | Xin Wang Xiaoli Yang Guangxian Pei Jifa Yang Junzhe Liu Fengwang Zhao Fayi Jin Wei Jiang Haoxi Ben Lixue Zhang | 2024 | Carbon Energy2024，6，1： | 0 |
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