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2篇 您的检索式:作者名="Honghui Bi"
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1Interconnected carbon nanocapsules with high N/S co-doping as stable and high-capacity potassium-ion battery anode显示文摘Carbonaceous materials have drawn much attention in potassium-ion batteries (PIBs) due to their low price and superior physicochemical properties. However, the application of carbonaceous materials in PIB anodes is hindered by sluggish kinetics and large volume expansion. Herein, N/S co-doped carbon nanocapsule (NSCN) is constructed for superior K+ storage. The NSCN possesses 3D nanocapsule framework with abundant meso/macropores, which guarantees structural robustness and accelerates ions/electrons transportation. The high-level N/S co-doping in carbon matrix not only generates ample defects and active sites for K+ adsorption, but also expands interlayer distance for facile K+ intercalation/deintercalation. As a result, the NSCN electrode delivers a high reversible capacity (408 mAh g^(−1) at 0.05 A g^(−1)), outstanding rate capability (149 mAh g^(−1) at 5 A g^(−1)) and favorable cycle stability (150m Ah g^(−1) at 2 A g^(−1) after 2000 cycles). Ex situ TEM, Raman and XPS measurements demonstrate the excellent stability and reversibility of NSCN electrode during potassiation/depotassiation process. This work provides inspiration for the optimization of energy storage materials by structure and doping engineering.Honghui Bi Xiaojun He Lei Yang Hongqiang Li Biyu Jin Jieshan Qiu 2022Journal of Energy Chemistry2022,31,3:4
2Interconnected N/P co-doped carbon nanocage as high capacitance electrode material for energy storage devices显示文摘Heteroatom doping carbon materials exhibit a huge application potential for energy storage devices(ESDs).Herein,interconnected N/P co-doped carbon nanocage(NP-CNC)was synthesized from pyrene molecules by using nano-MgO as template and melamine-phytic acid supramolecular aggregate as dopant coupled with KOH activation.The as-prepared NP-CNC possesses interconnected nanocages for electron transportation and abundant micropores for ion adsorption.Moreover,co-doped N/P species in NP-CNC provide active sites and additional pseudocapacitance.Consequently,NP-CNC as electrode material for symmetric supercapacitor exhibits a high gravimetric capacitance of 435 F·g^(-1) at 0.05 A·g^(-1),high volumetric capacitance of 274 F·cm^(-3) at 0.032 A·cm^(-3),and long cycle lifespan with 96.1%capacitance retention after 50,000 cycles.Furthermore,NP-CNC as cathode for zinc-ion hybrid supercapacitor delivers satisfactory energy and power densities of 130.6 Wh·kg^(-1)(82.3 Wh·L^(-1))and 14.4 kW·kg^(-1)(9.1 kWL^(-1)).This work paves a promising approach to the preparation of high capacitance NP-CNC for ESDs.Lei Yang Xiaojun He Yuchen Wei Honghui Bi Feng Wei Hongqiang Li Changzhou Yuan Jieshan Qiu 2022Nano Research2022,15,5:1
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